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5
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0036739952
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For more on atom-economy, see
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For more on atom-economy, see: B. M. Trost Acc. Chem. Res. 2002 35 695-705.
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Trost, B.M.1
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7
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C.-J. Li Chem. Rev. 2005 105 3095-3165.
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Chem. Rev.
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Li, C.-J.1
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14
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0037239704
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For reviews on isomerisation of allylic alcohols, see
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For reviews on isomerisation of allylic alcohols, see: R. Uma C. Crévisy R. Grée Chem. Rev. 2003 103 27-51.
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Chem. Rev.
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, pp. 27-51
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Uma, R.1
Crévisy, C.2
Grée, R.3
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0034859403
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For highly efficient recent examples using organic solvents, see
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For highly efficient recent examples using organic solvents, see: R. Uma M. K. Davies C. Crévisy R. Grée Eur. J. Org. Chem. 2001 3141-3146.
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(2001)
Eur. J. Org. Chem.
, pp. 3141-3146
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Uma, R.1
Davies, M.K.2
Crévisy, C.3
Grée, R.4
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43
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57649243236
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For formation of metal hydrides and hydroxides via oxidative addition of water, see
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For formation of metal hydrides and hydroxides via oxidative addition of water, see: O. V. Ozerov Chem. Soc. Rev. 2009 38 83-88.
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Chem. Soc. Rev.
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, pp. 83-88
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Ozerov, O.V.1
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45
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9144265784
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Joó et al. observed formation of Ru-aqua and hydroxide species with a water soluble Ru–NHC complex
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Joó et al. observed formation of Ru-aqua and hydroxide species with a water soluble Ru–NHC complex: P. Csabai F. Joó Organometallics 2004 23 5640-5643.
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(2004)
Organometallics
, vol.23
, pp. 5640-5643
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Csabai, P.1
Joó, F.2
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46
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85032773524
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We attribute this partially to the poor solubility of the catalyst in THF
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We attribute this partially to the poor solubility of the catalyst in THF.
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47
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85032776570
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−1, according to supplier
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−1, according to supplier.
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48
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85032775651
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TOF = mol product/mol Rh/time
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TOF = mol product/mol Rh/time.
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52
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85032781013
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1 takes place at approximately the same rate as that of 5a
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1 takes place at approximately the same rate as that of 5a.
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53
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65249164233
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We have observed before that under certain reaction conditions, metal hydrides formed in situ react with the allylic alcohols via an insertion/β-hydride elimination sequence
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We have observed before that under certain reaction conditions, metal hydrides formed in situ react with the allylic alcohols via an insertion/β-hydride elimination sequence: A. Bartoszewicz B. Martín-Matute Org. Lett. 2009 11 1749-1752.
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(2009)
Org. Lett.
, vol.11
, pp. 1749-1752
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Bartoszewicz, A.1
Martín-Matute, B.2
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55
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85032764764
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3-oxo-allyl intermediates as proposed by Trost and Gimeno may be involved. See references 6a and 23
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3-oxo-allyl intermediates as proposed by Trost and Gimeno may be involved. See references 6a and 23.
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