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Volumn 12, Issue 1, 2010, Pages 135-14

Ruthenium-catalyzed synthesis of β-oxo esters in aqueous medium: Scope and limitations

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EID: 77149153412     PISSN: 14639262     EISSN: 14639270     Source Type: Journal    
DOI: 10.1039/b914774h     Document Type: Article
Times cited : (40)

References (90)
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    • For references on the use of esters units as protecting groups of alcohols, see, Thieme Verlag, Stuttgart, 3rd edn
    • For references on the use of esters units as protecting groups of alcohols, see: P. J. Kocienski, Protecting Groups, Thieme Verlag, Stuttgart, 3rd edn, 2003.
    • (2003) Protecting Groups
    • Kocienski, P.J.1
  • 13
    • 15744379429 scopus 로고    scopus 로고
    • Ruthenium complexes have emerged in recent years as powerful tools in catalytic organic synthesis, with significant applications in atom-economic transformations, C. Bruneau and P. H. Dixneuf, Springer-Verlag, Berlin
    • Ruthenium complexes have emerged in recent years as powerful tools in catalytic organic synthesis, with significant applications in atom-economic transformations. See, for example: Ruthenium Catalysts and Fine Chemistry, ed. C. Bruneau and P. H. Dixneuf, Springer-Verlag, Berlin, 2004.
    • (2004) Ruthenium Catalysts and Fine Chemistry
  • 14
    • 17844369291 scopus 로고    scopus 로고
    • S.-I. Murahashi, Wiley-VCH, Weinheim
    • Ruthenium in Organic Synthesis, ed. S.-I. Murahashi, Wiley-VCH, Weinheim, 2004.
    • (2004) Ruthenium in Organic Synthesis
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    • 4444376920 scopus 로고    scopus 로고
    • For general reviews on metal-catalyzed addition of heteroatom-hydrogen bonds to alkynes, see
    • For general reviews on metal-catalyzed addition of heteroatom-hydrogen bonds to alkynes, see: F. Alonso I. P. Beletskaya M. Yus Chem. Rev. 2004 104 3079.
    • (2004) Chem. Rev. , vol.104 , pp. 3079
    • Alonso, F.1    Beletskaya, I.P.2    Yus, M.3
  • 24
    • 84919323071 scopus 로고
    • For specific accounts covering the use ruthenium catalysts in this type of transformations, see
    • For specific accounts covering the use ruthenium catalysts in this type of transformations, see: C. Bruneau M. Neveux Z. Kabouche C. Ruppin P. H. Dixneuf Synlett 1991 755.
    • (1991) Synlett , pp. 755
    • Bruneau, C.1    Neveux, M.2    Kabouche, Z.3    Ruppin, C.4    Dixneuf, P.H.5
  • 28
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    • 85032760699 scopus 로고    scopus 로고
    • 3,7]decane chloride; DAPTA = 3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane; TPPMS = 3-diphenylphosphanyl-benzenesulfonate sodium salt
    • 3,7]decane chloride; DAPTA = 3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane; TPPMS = 3-diphenylphosphanyl-benzenesulfonate sodium salt.
  • 67
    • 85032771611 scopus 로고    scopus 로고
    • As observed in our previous work on nitrile hydrations using catalysts 3a–6d, no direct relationship between the solubility of these complexes in water and their catalytic activity exists. Detailed data about the solubility of 3a–6d in water at 20 °C can be found in ref. 20
    • As observed in our previous work on nitrile hydrations using catalysts 3a–6d, no direct relationship between the solubility of these complexes in water and their catalytic activity exists. Detailed data about the solubility of 3a–6d in water at 20 °C can be found in ref. 20.
  • 74
    • 0043210660 scopus 로고    scopus 로고
    • Ruthenium-catalyzed cleavage of the C≡C bond of propargylic alcohols to generate the corresponding alkenes and carbon monoxide has been described by R.-S. Liu, and co-workers
    • Ruthenium-catalyzed cleavage of the C≡C bond of propargylic alcohols to generate the corresponding alkenes and carbon monoxide has been described by R.-S. Liu, and co-workers: S. Datta C.-L. Chang K.-L. Yeh R.-S. Liu J. Am. Chem. Soc. 2003 125 9294.
    • (2003) J. Am. Chem. Soc. , vol.125 , pp. 9294
    • Datta, S.1    Chang, C.-L.2    Yeh, K.-L.3    Liu, R.-S.4
  • 76
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    • For a general review on catalytic reactions involving carbon-carbon triple bond cleavage, see
    • For a general review on catalytic reactions involving carbon-carbon triple bond cleavage, see: M. Tobisu N. Chatani Chem. Soc. Rev. 2008 37 300.
    • (2008) Chem. Soc. Rev. , vol.37 , pp. 300
    • Tobisu, M.1    Chatani, N.2
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    • 2] as catalyst: see ref. 10b
    • 2] as catalyst: see ref. 10b.
  • 82
    • 0003111389 scopus 로고    scopus 로고
    • Formation of allenylidene-ruthenium(II) complexes from ethisterone and mestranol has been described
    • Formation of allenylidene-ruthenium(II) complexes from ethisterone and mestranol has been described: V. Cadierno S. Conejero M. P. Gamasa J. Gimeno M. A. Rodríguez Organometallics 2002 21 203.
    • (2002) Organometallics , vol.21 , pp. 203
    • Cadierno, V.1    Conejero, S.2    Gamasa, M.P.3    Gimeno, J.4    Rodríguez, M.A.5
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    • +), 203 (70) 194 (100), 174 (50), 143 (20), 117 (20), 99 (15), 53 (20)
    • +), 203 (70) 194 (100), 174 (50), 143 (20), 117 (20), 99 (15), 53 (20).


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