Facile Ru-H2 heterolytic activation and intramolecular proton transfer assisted by basic N-centers in the ligands

Journal of the American Chemical Society

Volumn 127, Issue 44, 2005, Pages 15364-15365

  Jalón, Félix A ^a   Manzano, Blanca R ^a   Caballero, Agustín ^a   Carrión, M Carmen ^a   Santos, Lucía ^a   Espino, Gustavo ^b   Moreno, Miquel ^c  

^a UNIVERSITY OF CASTILLA LA MANCHA   (Spain)

^b UNIVERSITY OF BURGOS   (Spain)

^c UNIVERSITAT AUTÒNOMA DE BARCELONA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

LIGAND; PHOSPHINE DERIVATIVE; PYRIDINE DERIVATIVE; RUTHENIUM;

ARTICLE; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; ENERGY; HYDROGEN BOND; ISOMERIZATION; MOLECULAR DYNAMICS; PROTON TRANSPORT;

EID: 27644559587     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja055116f     Document Type: Article

References (13)

1. Papish, E. T.; Magee, M. P.; Norton, J. R. In Recent Advances in Hydride Chemistry; Peruzzini, M., Poli, R., Eds.; Elsevier: New York, 2002; Chapter 4, p 39.
2. Chinn, M. S.; Heinekey, D. M. J. Am. Chem. Soc. 1990, 112, 5166.
3. (a) Ayllón, J. A.; Sayers, S. F.; Sabo-Etienne, S.; Donnadieu, B.; Chaudret, B.; Clot, E. Organometallics 1999, 18, 3981.
4. (b) Gruet, K.; Eisenstein, O.; Lee, D. H.; Patel, B. Macchioni, A.; Crabtree, R. H. New J. Chem. 2003, 27, 80.
5. Caballero, A.; Jalón, F. A.; Manzano, B. R. Chem. Commun. 1998, 1879.
6. Bakhmutov, V. I. Eur. J. Inorg. Chem. 2005, 44, 245.
7. (a) Bautista, M. T.; Earl, K. A.; Maltby, P. A.; Morris, R. H.; Scheweitzer, C. T.; Sella A. J. Am. Chem. Soc. 1988, 110, 7031.
8. (b) Desrosiers, P. J.; Cai, L.; Lin, Z.; Richards, R.; Halpern, J. J. Am. Chem. Soc. 1991, 113, 4173.
9. Crabtree, R. H.; Siegbahn, P. E. M.; Eisenstein, O.; Rheingold, A.; Koetzle, T. F. Acc. Chem. Res. 1996, 29, 348.
10. Smith, K.-T.; Rømming, C.; Tilset, M. J. Am. Chem. Soc. 1993, 115, 8681.
11. Tomasi, J.; Persico, M. Chem. Rev. 1994, 94, 2027.
12. (a) Epstein, L. M.; Shubina, E. S. Coord. Chem. Rev. 2002, 231, 165.
13. (b) Belkova, N. V.; Gutsul, E. I.; Shubina, E. S.; Epstein, L. M. Z. Phys. Chem. 2003, 217, 1525.