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Volumn 50, Issue 11, 2011, Pages 4868-4881

Synthesis and structure of ruthenium(IV) complexes featuring N-heterocyclic ligands with an N-H group as the hydrogen-bond donor: Hydrogen interactions in solution and in the solid state

Author keywords

[No Author keywords available]

Indexed keywords

HETEROCYCLIC COMPOUND; HYDROGEN; LIGAND; ORGANOMETALLIC COMPOUND; RUTHENIUM;

EID: 79958155573     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic200547k     Document Type: Article
Times cited : (22)

References (140)
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    • A similar intramolecular hydrogen bond has also been claimed as responsible for the high chemical shift (13.6-13.9 ppm) of the SH protons in other ruthenium(IV) complexes with 2 7-dimethyloctadienediyl- and thiolčontaining ligands.15a 1)
    • A similar intramolecular hydrogen bond has also been claimed as responsible for the high chemical shift (13.6-13.9 ppm) of the SH protons in other ruthenium(IV) complexes with 2,7-dimethyloctadienediyl- and thiolčontaining ligands.15a 1) (a) Johnson, C. S., Jr. Prog. Nucl. Magn. Reson. Spectrosc. 1999, 34, 203.
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    • H = hydrodynamic radius
    • H = hydrodynamic radius.
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    • The reported diffusion coefficients are taken from the resonance of the aliphatic CH2 protons in both compounds
    • The reported diffusion coefficients are taken from the resonance of the aliphatic CH2 protons in both compounds.
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    • Other examples of catalytic redox isomerization of allylic alcohols in aqueous media have been reported
    • Other examples of catalytic redox isomerization of allylic alcohols in aqueous media have been reported.


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