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RuP-NDI'-RuP is clearly a triad from a structural viewpoint. From the functional viewpoint, however, symmetric triads can be effectively considered as pseudo-dyads.
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Free NDI is barely soluble in chlorinated solvents.
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36 takes place at the concentrations used in the spectroscopic investigations.
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91
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79955632059
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36 has little effect on the reduction potential of this species.
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79955610212
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Relative intensities of the component radical ion spectra from spectroelectrochemical experiments on equal concentration solutions of the AlP(ba), NDI' and RuP(py) models.
-
-
-
-
95
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84918669584
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For the NDI-AlP dyad, a centre-to-centre distance of 8.5 A, as obtained from the DFT-optimized structure, has been used. For the NDI-AlMPyP-RuP triad, in which the conformational freedom allows for a range of centre-to-centre distances, an average value of 12 Å has been assumed. Effective radii of 4 and 5 Å were assumed, respectively, for the NDI and porphyrin molecular fragments
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A. Weller, Z. Phys. Chem., 1982, 133, 93. For the NDI-AlP dyad, a centre-to-centre distance of 8.5 A, as obtained from the DFT-optimized structure, has been used. For the NDI-AlMPyP-RuP triad, in which the conformational freedom allows for a range of centre-to-centre distances, an average value of 12 Å has been assumed. Effective radii of 4 and 5 Å were assumed, respectively, for the NDI and porphyrin molecular fragments.
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79955636753
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note
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-5 M range) rules out hypothesis (i) Furthermore, hypothesis (ii) is consistent with a quantitative analysis of the absorption spectra of Fig. 6, which reveals a small (ca. 10% excess) of porphyrin over NDI spectral features.
-
-
-
-
97
-
-
79955613420
-
-
note
-
The 570-610 nm region, hidden in Fig. 10 by the excitation pulse, can be monitored by using 550 nm as excitation wavelength (see Figure SI14, ESI†.
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