메뉴 건너뛰기




Volumn 130, Issue 15, 2008, Pages 5006-5007

Polyoxometalate embedding of a tetraruthenium(IV)-oxo-core by template-directed metalation of [γ-SiW10O36] 8-: A totally inorganic oxygen-evolving catalyst

Author keywords

[No Author keywords available]

Indexed keywords

OXYGEN; RUTHENIUM COMPLEX; SILICON DERIVATIVE; TUNGSTEN DERIVATIVE;

EID: 42149146066     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja077837f     Document Type: Article
Times cited : (554)

References (31)
  • 19
    • 42149176858 scopus 로고    scopus 로고
    • ex values of water exchange are 7 order of magnitude higher with respect to the mononuclear aqua ion. Patel, A.; Richens, D. T. Inorg. Chem. 1991, 30, 3792-3793.
    • ex values of water exchange are 7 order of magnitude higher with respect to the mononuclear aqua ion. Patel, A.; Richens, D. T. Inorg. Chem. 1991, 30, 3792-3793.
  • 21
    • 34447323043 scopus 로고    scopus 로고
    • This coordination mode is an emerging feature documented only for Fe(III) and Cr(III) POMs, see: (a) Botar, B, Kogerler, P, Hill, C. L. Inorg. Chem. 2007, 46, 5398-5403
    • This coordination mode is an emerging feature documented only for Fe(III) and Cr(III) POMs, see: (a) Botar, B.; Kogerler, P.; Hill, C. L. Inorg. Chem. 2007, 46, 5398-5403.
  • 23
    • 42149084082 scopus 로고    scopus 로고
    • 10-1 are EPR silent, indicating a diamagnetic behavior. Further investigation will address the catalyst evolution to competent species in solution (vide infra).
    • 10-1 are EPR silent, indicating a diamagnetic behavior. Further investigation will address the catalyst evolution to competent species in solution (vide infra).
  • 25
    • 42149140287 scopus 로고    scopus 로고
    • pc) of 89, 98, 59, and 166 mV (Figure S7).
    • pc) of 89, 98, 59, and 166 mV (Figure S7).
  • 26
    • 4644289909 scopus 로고    scopus 로고
    • Electrocatalytic water oxidation by a sandwich-type Ru-POM, (mixture of isomeric clusters) has been reported. Howells, A. R.; Sankarraj, A.; Shannon, C. J. Am. Chem. Soc. 2004, 126, 12258-12259.
    • (a) Electrocatalytic water oxidation by a sandwich-type Ru-POM, (mixture of isomeric clusters) has been reported. Howells, A. R.; Sankarraj, A.; Shannon, C. J. Am. Chem. Soc. 2004, 126, 12258-12259.
  • 27
    • 42149125159 scopus 로고    scopus 로고
    • 10, shows a sluggish reactivity, featuring ca. 20 min induction time, followed by slow oxygen evolution (1 order of magnitude slower than the POM-catalyzed reaction) and soon leveling off to a plateu yield, at <10% of Ce(IV) conversion.
    • 10, shows a sluggish reactivity, featuring ca. 20 min induction time, followed by slow oxygen evolution (1 order of magnitude slower than the POM-catalyzed reaction) and soon leveling off to a plateu yield, at <10% of Ce(IV) conversion.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.