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ex values of water exchange are 7 order of magnitude higher with respect to the mononuclear aqua ion. Patel, A.; Richens, D. T. Inorg. Chem. 1991, 30, 3792-3793.
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ex values of water exchange are 7 order of magnitude higher with respect to the mononuclear aqua ion. Patel, A.; Richens, D. T. Inorg. Chem. 1991, 30, 3792-3793.
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34447323043
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This coordination mode is an emerging feature documented only for Fe(III) and Cr(III) POMs, see: (a) Botar, B, Kogerler, P, Hill, C. L. Inorg. Chem. 2007, 46, 5398-5403
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This coordination mode is an emerging feature documented only for Fe(III) and Cr(III) POMs, see: (a) Botar, B.; Kogerler, P.; Hill, C. L. Inorg. Chem. 2007, 46, 5398-5403.
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(b) Botar, B.; Geletii, Y. V.; Kogerler, P.; Musaev, D. G.; Morokuma, K.; Weinstock, I. A.; Hill, C. L. J. Am. Chem. Soc. 2006, 128, 11268-11277.
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Hill, C.L.7
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10-1 are EPR silent, indicating a diamagnetic behavior. Further investigation will address the catalyst evolution to competent species in solution (vide infra).
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10-1 are EPR silent, indicating a diamagnetic behavior. Further investigation will address the catalyst evolution to competent species in solution (vide infra).
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pc) of 89, 98, 59, and 166 mV (Figure S7).
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pc) of 89, 98, 59, and 166 mV (Figure S7).
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26
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Electrocatalytic water oxidation by a sandwich-type Ru-POM, (mixture of isomeric clusters) has been reported. Howells, A. R.; Sankarraj, A.; Shannon, C. J. Am. Chem. Soc. 2004, 126, 12258-12259.
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(a) Electrocatalytic water oxidation by a sandwich-type Ru-POM, (mixture of isomeric clusters) has been reported. Howells, A. R.; Sankarraj, A.; Shannon, C. J. Am. Chem. Soc. 2004, 126, 12258-12259.
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10, shows a sluggish reactivity, featuring ca. 20 min induction time, followed by slow oxygen evolution (1 order of magnitude slower than the POM-catalyzed reaction) and soon leveling off to a plateu yield, at <10% of Ce(IV) conversion.
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10, shows a sluggish reactivity, featuring ca. 20 min induction time, followed by slow oxygen evolution (1 order of magnitude slower than the POM-catalyzed reaction) and soon leveling off to a plateu yield, at <10% of Ce(IV) conversion.
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(a) Sens, C.; Romero, I.; Rodriguez, M.; Llobet, A.; Parella, T.; Benet-Buchholz, J. J. Am. Chem. Soc. 2004, 126, 7798-7799.
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(c) Liu, F.; Cardolaccia, T.; Hornstein, B. J.; Schoonover, J. R.; Meyer, T. J. J. Am. Chem. Soc. 2007, 129, 2446-2447.
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Alstrum-Acevedo, J.H.1
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