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note
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The pairs of ortho and meta phenyl protons are not equivalent, and their resonances are split into a pair of multiplets each (assignments were made with a NOESY experiment, see Supporting Information).
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68
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31044442942
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note
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1b has a mobility on silica gel that is intermediate between those of the corresponding free-base 1 and the fully zincated adduct 1a. This guarantees that 1b is a real species and not an equimolar mixture of 1 and 1a. The same considerations apply to 2b.
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The feature at 520 nm in the spectrum of 2a is attributed to a minor (ca. 5%) amount of free-base absorption arising from incomplete Zn insertion.
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Kasha, M.1
Rawls, H.R.2
El-Bayoumi, M.A.3
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73
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31044439277
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see Supporting Information
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y, θ = 90°. With these figures, the expected exciton splittings (energy differences between the red-shifted x-polarized transition and the blue-shifted y-polarized transition) are calculated to be in a ratio 2.2 for staggered vs planar compounds (see Supporting Information).
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74
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31044445683
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note
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The feature at 720 nm is attributed to a minor (ca. 5%) amount of free-base emission arising from incomplete zinc insertion.
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75
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0035796203
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Prodi, A.; Kleverlaan, C. J.; Indelli, M. T.; Scandola, F.; Alessio, E.; Iengo, E. Inorg. Chem. 2001, 40, 3498-3504.
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(2001)
Inorg. Chem.
, vol.40
, pp. 3498-3504
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Prodi, A.1
Kleverlaan, C.J.2
Indelli, M.T.3
Scandola, F.4
Alessio, E.5
Iengo, E.6
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78
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0010104094
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-1. Calculations performed using PhotochemCAD (Du, H.; Fuh, R. A.; Li, J.; Corkan, A.; Lindsey, J. S. Photochem. Photobiol. 1998, 68, 141-142).
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(1998)
Photochem. Photobiol.
, vol.68
, pp. 141-142
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Du, H.1
Fuh, R.A.2
Li, J.3
Corkan, A.4
Lindsey, J.S.5
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79
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12044255821
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See, for example: (a) Gust, D.; Moore, T. A.; Moore, A. L.; Gao, F.; Luttrull, D.; DeGraziano, J. M.; Ma, X. C.; Makings, L. R.; Lee, S.-J.; Trier, T. T.; Bittersmann, E.; Seely, G. R.; Woodward, S.; Bensasson, R. V.; Rougee, M.; De Schryver F. C.; Van der Auweraer, M. J. Am. Chem. Soc. 1991, 113, 3638-3649.
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(1991)
J. Am. Chem. Soc.
, vol.113
, pp. 3638-3649
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Gust, D.1
Moore, T.A.2
Moore, A.L.3
Gao, F.4
Luttrull, D.5
DeGraziano, J.M.6
Ma, X.C.7
Makings, L.R.8
Lee, S.-J.9
Trier, T.T.10
Bittersmann, E.11
Seely, G.R.12
Woodward, S.13
Bensasson, R.V.14
Rougee, M.15
De Schryver, F.C.16
Van Der Auweraer, M.17
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80
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0035799966
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(b) Cho, H. S.; Kim, Y., H.; Kim, Y. R.; Jeoung, S. C.; Kim, D.; Kim, S. K.; Aratani, N.; Shinmori, H.; Osuka, A. J. Phys. Chem. A 2001, 105, 4200-4210.
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(2001)
J. Phys. Chem. A
, vol.105
, pp. 4200-4210
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Cho, H.S.1
Kim, Y.H.2
Kim, Y.R.3
Jeoung, S.C.4
Kim, D.5
Kim, S.K.6
Aratani, N.7
Shinmori, H.8
Osuka, A.9
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