High energy and quantum efficiency in photoinduced charge separation

Journal of the American Chemical Society

Volumn 129, Issue 2, 2007, Pages 313-320

  Weber, John M ^a   Rawls, Matthew T ^a   MacKenzie, Valerie J ^a   Limoges, Bradford R ^a   Elliott, C Michael ^a  

^a Department of Environmental and Radiological Health Sciences   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BIMOLECULAR SYSTEM; CHARGE SEPARATED STATES (CSS); PHOTOINDUCED CHARGE SEPARATION; SUPRAMOLECULAR TRIAD ASSEMBLIES;

CHROMOPHORES; ELECTRONS; GROUND STATE; MOLECULAR DYNAMICS; QUANTUM EFFICIENCY; RUTHENIUM COMPOUNDS;

ELECTROPHORESIS;

BIPYRIDINE DERIVATIVE; N METHYLPHENOTHIAZINE DERIVATIVE; PHENOTHIAZINE DERIVATIVE; RUTHENIUM DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHROMATOPHORE; ELECTRON TRANSPORT; ENERGY TRANSFER; EXCITATION; MOLECULAR DYNAMICS; QUANTUM MECHANICS; SUPRAMOLECULAR CHEMISTRY;

EID: 33846209235     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0665500     Document Type: Article

References (35)

1. Deisenhofer, J.; Michel, H. Annu. Rev. Cell Biol. 1991, 7, 1-23.
2. Deisenhofer, J.; Michel, H. Annu. Rev. Biophys. Biophys. Chem. 1991, 20, 247-266.
3. Greenfield, S. R.; Wasielewski, M. R. Photosynth. Res. 1996, 48, 83-97.
4. Kalyanasundaram, K. Photochemistry of Polypyricline and Porphyrin Complexes: Academic Press: San Diego, CA, 1992.
5. Schanze, K. S.; Walters, K. A. In Organic and Inorganic Photochemistry; Ramamurthy, V., Schanze, K. S., Eds.: Marcel Dekker: New York, 1998; Vol. 2. pp 75-127.
6. Armaroli, N. Photochem. Photobiol. Sci. 2003, 2, 73-87.
7. Scandola, F.; Chiorboli, C.; Indelli, M. T.; Rampi, M. T. In Biological and Artificial Supermolecular Systems; Wiley: Weinheim, 2003; Vol. 3, pp 337-403.
8. Gust, D.; Moore, T. A.; Moore, A. L. Acc. Chem. Res. 2001, 34, 40-48.
9. Gust, D.; Moore, T. A. Porphyrin Handb. 2000, 8, 153-190.
10. Bahr, J. L.; Kuciauskas, D.; Liddell, P. A.; Moore, A. L.; Moore, T. A.; Gust, D. Photochem. Photobiol. 2000, 72, 598-611.
11. Danielson, E.; Elliott, C. M.; Merken, J. W.; Meyer, T. J. J. Am. Chem. Soc. 1987, 109, 2519-2520.
12. Cooley, L. F.; Larson, S. L.; Elliott, C. M.; Kelley, D. F. J. Phys. Chem. 1991, 95, 10694-10700.
13. Larson, S. L. Ph.D. Dissertation. Colorado State University, Fort Collins, CO, 1994.
14. Larson, S. L.; Elliott, C. M.; Kelley, D. F. J. Phys. Chem. 1995, 99, 6530-6539.
15. Klumpp, T.; Linsenmann, M.; Larson, S. L.; Limoges, B. R.; Buerssner, D.; Krissinel, E. B.; Elliott, C. M.; Steiner, U. E. J. Am. Chem. Soc. 1999, 121, 4092.
16. Klumpp, T.; Linsenmann, M.; Larson, S. L.; Limoges, B. R.; Buerssner, D.; Krissinel, E. B.; Elliott, C. M.; Steiner, U. E. J. Am. Chem. Soc. 1999, 121, 1076-1087.
17. Kodis, G.; Liddell, P. A.; Moore, A. L.; Moore, T. A.; Gust, D. J. Phys. Org. Chem. 2004, 17, 724-734.
18. Schmehl, R. H.; Ryu, C. K.; Elliott, C. M.; Headford, C. L. E.; Ferrere, S. Adv. Chem. Ser. 1990, 226, 211-223.
19. Cooley, L. F.; Headford, C. E. L.; Elliott, C. M.; Kelley, D. F. J. Am. Chem. Soc. 1988, 110, 6673-6682.
20. Ryu, C. K.; Wang, R.; Schmehl, R. H.; Ferrere, S.; Ludwikow, M.; Merkert, J. W.; Headford, C. E. L.; Elliott, C. M. J. Am. Chem. Soc. 1992, 114, 430-438.
21. Larson, S. L.; Elliott, C. M.; Kelley, D. F. Inorg. Chem. 1996, 35, 2070-2076.
22. Yonemoto, E. H.; Riley, R. L.; Kim, Y. I.; Atherton, S. J.; Schmehl, R. H.; Mallouk, T. E. J. Am. Chem. Soc. 1992, 114, 8081-8087.
23. Balzani, V.; Juris, A.; Barigelletti, F.; Campagna, S.; Belser, P.; von Zelewsky, A. Coord. Chem. Rev. 1988, 84, 85-277.
24. Wilkinson, G.; Evans, I. P.; Spencer, A. J. Chem. Soc., Dalton Trans. 1973, 204-209.
25. O'Connor, D. V.; Phillips, D. Time-Correlated Single-Photon Counting; Academic Press: London. 1984.
26. 2+ are excited as exist in the equilibrium solution. The validity of this assumption can be defended on the basis of the very minor change observed in the MLCT spectrum upon addition of N-MePTZ (see Figure 6).
27. max, differs significantly for the two solvents (see also Supporting Information).
28. Yonemoto, E. H.; Saupe, G. B.; Schmehl, R. H.; Hubig, S. M.; Riley, R. L.; Iverson, B. L.; Mallouk, T. E. J. Am. Chem. Soc. 1994, 116, 4786-4795.
29. Atkins, P. W. Physical Chemistry, 5th ed.; W. H. Freeman: New York, 1994.
30. Ohno, T.; Yoshimura, A.; Prasad, D. R.; Hoffman, M. Z. J. Phys. Chem. 1991, 95, 4723-4728.
31. Sun, H.; Hoffman, M. Z. J. Phatochem. Photobiol, A 1994, 84, 97-99.
32. Linsenmann, M. Ph.D. Dissertation, University of Konstanz, Konstanz, Germany, 1997.
33. Deronzier, A.; Essakalli, M. J. Phys. Chem. 1991, 95, 1737-1742.
34. McClenaghan, N. D.; Loiseau, F.; Puntoriero, F.; Serroni, S.; Campagna, S. Chem. Commun. 2001, 2634-2635.
35. Limoges, B. Ph.D. Dissertation, Colorado State University, Fort Collins, CO, 2001.