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Nucleophilic reactions: (a) Truce, W. E.; Simms, J. A. J. Am. Chem. Soc. 1956, 78, 2756-2759.
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Metal-catalyzed reactions: using Pd: (a) Bäckvall, J. E.; Ericsson, A. J. Org. Chem. 1994, 59, 5850-5851. Using Pd, Rh, Ni, and Pt:
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65
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Ogawa, A.1
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Koelle, U.1
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McDonald, F.E.1
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Han, L.B.1
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29144490813
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Cao, C.; Fraser, L. R.; Love, J. A. J. Am. Chem. Soc. 2005, 127, 17614-17615.
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2 complexes in alkyne hydrothiolation, see: Misumi, Y.; Seino, H.; Yasushi, M. J. Organomet. Chem. 2006, 691, 3157-3164.
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2 complexes in alkyne hydrothiolation, see: Misumi, Y.; Seino, H.; Yasushi, M. J. Organomet. Chem. 2006, 691, 3157-3164.
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Shoai, S.; Bichler, P.; Kang, B.; Buckley, H.; Love, J. A. In preparation.
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34250810313
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For the first example of Pd-catalyzed hydrothiolation using alkyl thiols, see
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For the first example of Pd-catalyzed hydrothiolation using alkyl thiols, see: Ananikov, V. P.; Orlov, N. V.; Beletskaya, I. P.; Khrustalev, V. N.; Antipin, M. Y.; Timofeeva, T. V. J. Am. Chem. Soc. 2007, 129, 7252-7253.
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Rearrangements in octahedral titanium pyrazolylborate complexes: (a) LeCloux, D. D.; Keyes, M. C.; Osawa, M.; Reynolds, V.; Tolman, W. B. Inorg. Chem. 1994, 33, 6361-6368.
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Rearrangements in octahedral titanium pyrazolylborate complexes: (a) LeCloux, D. D.; Keyes, M. C.; Osawa, M.; Reynolds, V.; Tolman, W. B. Inorg. Chem. 1994, 33, 6361-6368.
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36249029490
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R denticity, see: (a) Bucher, U. E.; Fässler, T. F.; Hunziker, M.; Nesper, R.; Rüegger, H.; Venanzi, L. M. Gazz. Chim. Ital. 1995, 125, 181-188.
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(h) Connelly, N. G.; Emslie, D. J. H.; Geiger, W. E.; Hayward, O. D.; Linehan, E. B.; Orpen, A. G.; Quayle, M. J.; Rieger, P. H. J. Chem. Soc., Dalton Trans. 2001, 670-683.
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(i) Malbosc, F.; Chauby, V.; Serra-Le Berre, C.; Etienne, M.; Daran, J. C.; Kalck, P. Eur. J. Inorg. Chem 2001, 10, 2689-2697.
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99
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36249026777
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11B NMR spectroscopy is a technique that has been used to determine the coordination geometry around the metal. It was found that κ2 complexes show resonances between δ -5.90 and -6.99 versus κ3 complexes with resonances between δ-8.44 and -9.76 (see ref 30e, These resonances appear to be independent of both solvent and charge on the metal for group 9 and 10 metals (see ref 30e, Thus, there appears to be a strong correlation between the boron chemical shift and the denticity of the tris(pyrazolyl)borate ligand
-
3 complexes with resonances between δ-8.44 and -9.76 (see ref 30e). These resonances appear to be independent of both solvent and charge on the metal for group 9 and 10 metals (see ref 30e). Thus, there appears to be a strong correlation between the boron chemical shift and the denticity of the tris(pyrazolyl)borate ligand.
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100
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0000052215
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Rhodium pyrazolylborate complexes with only CO or olefin as ancillary ligands: (a) Cocivera, M.; Ferguson, G.; Laior, F. J.; Szczecinski, P. Organometallics 1982, 1, 1139-1142.
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Rhodium pyrazolylborate complexes with only CO or olefin as ancillary ligands: (a) Cocivera, M.; Ferguson, G.; Laior, F. J.; Szczecinski, P. Organometallics 1982, 1, 1139-1142.
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Rhodium pyrazolylborate monophosphine complexes: (a) Malbosc, F.; Kalck, P.; Daran, J. C.; Etienne, M. J. Chem. Soc. Dalton Trans. 1999, 271-272.
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Rhodium pyrazolylborate monophosphine complexes: (a) Malbosc, F.; Kalck, P.; Daran, J. C.; Etienne, M. J. Chem. Soc. Dalton Trans. 1999, 271-272.
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106
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0000460691
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Rhodium pyrazolylborate bisphosphine complexes: (a) Baena, M. J.; Reyes, M. L.; Rey, L.; Carmona, E.; Nicasio, M. C.; Pérez, P. J.; Gutierrez, E.; Monge, A. Inorg. Chim. Acta 1998, 273, 244-254.
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Rhodium pyrazolylborate bisphosphine complexes: (a) Baena, M. J.; Reyes, M. L.; Rey, L.; Carmona, E.; Nicasio, M. C.; Pérez, P. J.; Gutierrez, E.; Monge, A. Inorg. Chim. Acta 1998, 273, 244-254.
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0001356856
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33748446079
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111
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36248954732
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For complex 3 our data is consistent with that reported by Connelly and coworkers (see ref 30h) but differs from the previously reported assigned spectra by Hill and coworkers see ref 34b
-
For complex 3 our data is consistent with that reported by Connelly and coworkers (see ref 30h) but differs from the previously reported assigned spectra by Hill and coworkers (see ref 34b).
-
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112
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36248931238
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2.
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2.
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113
-
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36248938402
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At elevated temperatures (100 °C) complex 5 decomposes, presumably to a rhodium hydrido species, as evidenced by the appearance of a hydride peak in the 1H NMR
-
1H NMR.
-
-
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114
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36248964923
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Alkyl vinyl sulfide 19a isomerizes to the internal olefin over prolonged exposure to the catalyst see ref 18, However, at short reaction times, the 1,1-disubstituted alkene can be obtained selectively
-
Alkyl vinyl sulfide 19a isomerizes to the internal olefin over prolonged exposure to the catalyst (see ref 18). However, at short reaction times, the 1,1-disubstituted alkene can be obtained selectively.
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Bruker SAINT software package, version 7.03A; Bruker AXS Inc, Madison, WI, 1997-2003
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Bruker SAINT software package, version 7.03A; Bruker AXS Inc.: Madison, WI, 1997-2003.
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Bruker SAINT software package. Version 2.10; Bruker AXS Inc, Madison, WI, 2003
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Sluis, P. V. D.; Spek, A. L. Acta Crystallogr., Sect A 1990, 46, 194-201.
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(1990)
Acta Crystallogr., Sect A
, vol.46
, pp. 194-201
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Sluis, P.V.D.1
Spek, A.L.2
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