Solid-state and solution structures of a series of [(HBPz3Me2)Rh(CO)(PR3)] and [(HBPz3Me2,4Cl)Rh(CO)(PR3)] complexes

European Journal of Inorganic Chemistry

Volumn , Issue 10, 2001, Pages 2689-2697

  Malbosc, François ^a   Chauby, Valérie ^a   Serra Le Berre, Carole ^a   Etienne, Michel ^b   Daran, Jean Claude ^b   Kalck, Philippe ^a  

^a UNIVERSITÉ DE TOULOUSE   (France)

^b LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

Author keywords

Fluxional behavior; IR spectroscopy; Pyrazolylborato ligands; Rhodium; Square planar complexes

Indexed keywords

CRYSTAL STRUCTURE; LIGANDS; SOLID SOLUTIONS;

FLUXIONAL BEHAVIOR; IR-SPECTROSCOPY; PHOSPHANE LIGANDS; PHOSPHITE LIGANDS; PYRAZOLYL; PYRAZOLYLBORATO LIGAND; SOLID SOLUTION STRUCTURES; SOLID-STATE STRUCTURES; SQUARE PLANAR COMPLEX; X RAY CRYSTAL STRUCTURES;

RHODIUM COMPOUNDS;

RHENIUM COMPLEX;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; COMPLEX FORMATION; CRYSTAL STRUCTURE; NUCLEAR MAGNETIC RESONANCE; SOLID STATE; STRUCTURE ANALYSIS;

EID: 0034800138     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200109)2001:10<2689::aid-ejic2689>3.0.co;2-u     Document Type: Article

References (27)

1. S. Trofimenko, J. Am. Chem. Soc. 1966, 88, 1842.
2. S. Trofimenko, Chem. Rev. 1993, 93, 943.
3. C. Gemel, R. John, C. Slugovc, K. Mereiter, R. Schmid, K. Kirchner, J. Chem. Soc., Dalton Trans. 2000, 15, 2607.
4. F. Malbosc, Ph. Kalck, J.-C. Daran, M. Etienne, J. Chem. Soc., Dalton Trans. 1999, 271.
5. M. Paneque, S. Sirol, M. Trujillo, E. Gutiérnez-Publa, M. Angeles Monge, E. Carmona, Angew. Chem. Int. Ed. 2000, 39, 218.
6. U. E. Bucher, A. Currao, R. Nesper, H. Rügger, L. M. Venanzi, E. Younger, Inorg. Chem. 1995, 34, 66.
7. M. Akita, K. Ohta, Y. Takahashi, S. Hikichi, Y. Moro-oka, Organometallics 1997, 16, 4121.
8. C. K. Ghosh, W. A. G. Graham, J. Am. Chem. Soc. 1987, 109, 4726.
9. A. A. Punvoko, A. J. Lees, Inorg. Chem. 1996, 35, 675.
10. S. E. Bronsberg, H. Yang, M. C. Asplund, T. Lian, B. K. McNamara, K. T. Kotz, J. S. Yeston, M. Wilkens, H. Frei, R. G. Bergman, C. B. Harris, Science 1997, 278, 260.
11. V. Chauby, C. Serra-Le Berre, Ph. Kalck, J.-C. Daran, G. Commenges, Inorg. Chem. 1996, 35, 6354.
12. N. G. Connelly, D. J. H. Emslie, B. Metz, A. G. Orpen, M. J. Quayle, Chem. Commun. 1996, 2289.
13. BH bands, Ghosh proposed that the exchange phenomenon occurs between two isomeric trigonal bipyramids having a plane of symmetry.
14. T. T. Derencsényi, Inorg. Chem. 1981, 20, 665.
15. R. G. Bull, C. K. Ghosh, J. K. Hoyano, A. D. MacMaster, W. A. G. Graham, Chem. Commun. 1989, 341.
16. W. D. Jones, Activation of Unreactive Bonds and Organic Synthesis, Springer, Berlin, 1999, vol. 3, p. 9-46.
17. E. Gutiévrez, S. A. Hudson, A. Monge, E. Carmona, J. Chem. Soc., Dalton. Trans. 1992, 2651.
18. D. D. Perrin, W. L. F. Armarego, D. R. Perrin, Purification of Laboratory Chemicals, Pergamon Press, Oxford, 1980.
19. K. v. Auvers, K. Bäht, J. Prakt. Chem. 1927, 116, 65.
20. F. J. Lalor, T. J. Desmond, G. M. Cotter, C. A. Shanahan, G. Ferguson, M. Pervez, B. Ruhl, J. Chem. Soc., Dalton. Trans. 1995, 1709.
21. S. Trofimenko, J. Am. Chem. Soc. 1967, 89, 3170.
22. A. Altomare, M. C. Burla, M. Camalli, G. L. Cascarano, C. Giacovazzo, A. Guagliardi, A. G. G. Moliterni, G. Polidori, R. Spagni, J. Appl. Crystallogr. 1999, 32, 115-119.
23. [23a] H. D. Flack, Acta Crystallogr., Sect. A 1983, 39, 876-881.
24. [23b] G. Bernardinelli, H. D. Flack, Acta Crystallogr., Sect. A 1985, 41, 500-511.
25. E. Prince, Mathematical Techniques in Crystallography, Springer-Verlag, Berlin, 1982.
26. D. J. Watkin, C. K. Prout, J. R. Carruthers, P. W. Betteridge, CRYSTALS Issue 11, Chemical Crystallography Laboratory, University of Oxford, Oxford, 1999.
27. M. N. Burnett, C. K. Johnson, ORTEP III, Report ORNL-6895, Oak Ridge National Laboratory, Oak Ridge, Tennessee, 1996.