Total synthesis of (-)-coriolin

Journal of Organic Chemistry

Volumn 64, Issue 8, 1999, Pages 2648-2656

  Mizuno, Hajime ^a   Domon, Kei ^a   Masuya, Keiichi ^a   Tanino, Keiji ^a   Kuwajima, Isao ^a,b  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^b KITASATO INSTITUTE   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALKADIENE; ALLYL COMPOUND; CORIOLIC ACID; EPOXIDE; HYDROXYL GROUP; NATURAL PRODUCT; SILANE DERIVATIVE; SILOXANE; SPIRO COMPOUND; SULFIDE; TRIACYLGLYCEROL LIPASE; VINYL DERIVATIVE;

ARTICLE; CHEMICAL REACTION; CYCLIZATION; ENANTIOMER; EPOXIDATION; OPTICAL ROTATION; STEREOCHEMISTRY; SYNTHESIS;

EID: 0033574497     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo981478c     Document Type: Article

References (61)

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54. 26
55. 17 in the early stage of the total synthesis, and the rotation of (-)-coriolin was again confirmed at the last stage. We have also confirmed that compound 15 was obtained in optically pure form by our method (Suporting Information). Therefore, it seems that there are some errors in structual assignment made by Demuth, not only for 15 but also for 18.
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57. 26
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