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Volumn 18, Issue 4, 1999, Pages 495-505

Energetics of homogeneous intermolecular vinyl and allyl carbon-hydrogen bond activation by the 16-electron coordinatively unsaturated organometallic fragment [Tp′Rh(CNCH2CMe3)]

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Indexed keywords


EID: 0000576703     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9808211     Document Type: Article
Times cited : (94)

References (85)
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    • Schaller, C. P.; Cummins, C. C.; Wolczanski, P. T. J. Am. Chem. Soc. 1996, 118, 591-611 and references therein. Bennett, J. L.; Wolczanski, P. T. J. Am. Chem. Soc. 1997, 119, 10696-10719.
    • (1997) J. Am. Chem. Soc. , vol.119 , pp. 10696-10719
    • Bennett, J.L.1    Wolczanski, P.T.2
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    • note
    • In calculations of this type entropies and solvation energies for the various metal alkyl and aryl hydride complexes are assumed to be equal. Thus, these terms cancel in the calculation of energy differences, and the free energy of reaction is then approximately equal to the enthalpy of reaction.
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    • note
    • 22 For an excellent discussion of the origin of stability, with consideration of covalent and ionic contributions to M-C bond enthalpies, sterics, and reaction coordination position see ref 22.
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    • (a) Schuster, R. E. Organic Synthesis; Wiley: New York, 1973; Collect. Vol. 5, p 772.
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    • Schuster, R.E.1
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    • -1): 294 (383).
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