Synthesis and structure of [Tp*Rh{P(C7H7)3}] - Competition between the ligands tris(3,5-dimethyl-1-pyrazolyl)borate (Tp*) and tris(1-cyclohepta-2,4,6-trienyl)phosphane. Proof of the κ2(N,B-H) coordination mode of the Tp* ligand

Zeitschrift fur Anorganische und Allgemeine Chemie

Volumn 626, Issue 2, 2000, Pages 552-555

  Herberhold, Max ^a   Eibl, Stefan ^a   Milius, Wolfgang ^a   Wrackmeyer, Bernd ^a  

^a UNIVERSITY OF BAYREUTH   (Germany)

Author keywords

Crystal structure; NMR, spectroscopy; Pyrazolylborates; Rhodium complexes; Tris(1 cyclohepta 2,4,6 trienyl)phosphane

Indexed keywords

EID: 0034388398     PISSN: 00442313     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1521-3749(200002)626:2<552::aid-zaac552>3.0.co;2-a     Document Type: Article

References (16)

1. S. Trofimenko, Chem. Rev. 1993, 93, 943.
2. G. Parkin, Adv. Inorg. Chem. 1995, 42, 291.
3. N. Kitajima, W. B. Tolman, Progr. Inorg. Chem. 1995, 43, 419.
4. M. Etienne, Coord. Chem. Rev. 1997, 156, 201 (M = V, Nb, Ta); P. K. Byers, A. J. Canty, R. Th. Honeyman, Adv. Organomet. Chem. 1992, 34, 1 (M = Pd, Pt); D. L. Reger, Coord. Chem. Rev. 1996, 147, 571 (M = Ga, In).
5. M. Etienne, Coord. Chem. Rev. 1997, 156, 201 (M = V, Nb, Ta); P. K. Byers, A. J. Canty, R. Th. Honeyman, Adv. Organomet. Chem. 1992, 34, 1 (M = Pd, Pt); D. L. Reger, Coord. Chem. Rev. 1996, 147, 571 (M = Ga, In).
6. M. Etienne, Coord. Chem. Rev. 1997, 156, 201 (M = V, Nb, Ta); P. K. Byers, A. J. Canty, R. Th. Honeyman, Adv. Organomet. Chem. 1992, 34, 1 (M = Pd, Pt); D. L. Reger, Coord. Chem. Rev. 1996, 147, 571 (M = Ga, In).
7. U. E. Bucher, A. Currao, R. Nesper, H. Rüegger, L. M. Venanzi, E. Younger, Inorg. Chem. 1995, 34, 66.
8. F. Malbose, P. Kalck, J.-C. Daran, M. Etienne, J. Chem. Soc. Dalton Trans. 1999, 271.
9. M. Herberhold, W. Milius, St. Eibl, Z. Anorg. Allg. Chem. 1999, 625, 341.
10. A. E. Corrochano, F. A. Jalon, A. Otero, M. M. Kubicki, P. Richard, Organometallics 1997, 16, 145.
11. cf. S. Trofimenko, Inorg. Chem. 1971, 10, 1372. The molecular structure has been determined (1997): W. Milius, St. Eibl, M. Herberhold, to be published.
12. cf. S. Trofimenko, Inorg. Chem. 1971, 10, 1372. The molecular structure has been determined (1997): W. Milius, St. Eibl, M. Herberhold, to be published.
13. M. Herberhold, K. Bauer, W. Milius, J. Organomet. Chem. 1995, 502, C1.
14. 3}] (4) have been deposited with the Cambridge Crystallographic Data Centre (CCDC-122428). Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK [fax (internat.): +44(0)1 22 33 36-0 33; E-mail: teched@chemcrys.cam.ac.uk).
15. S. Trofimenko, J. Am. Chem. Soc. 1967, 89, 3170.
16. W. von Philipsborn, Chem. Soc. Rev. 1999, 28, 95.