BpCu-catalyzed cyclopropanation of olefins: A simple system that operates under homogeneous and heterogeneous conditions (Bp = dihydridobis(pyrazolyl)borate)

Organometallics

Volumn 17, Issue 14, 1998, Pages 3051-3057

  Díaz Requejo, M Mar ^a   Nicasio, M Carmen ^a   Pérez, Pedro J ^a  

^a UNIVERSITY OF HUELVA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001019192     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om980061u     Document Type: Article

References (28)

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25. 12 (b) NMR spectra of 1 in the presence of a 5-10-fold excess of olefin display very broad resonances. We suggest the existence of an equilibrium between 1 and the corresponding olefin complex, the equilibrium favoring on the latter, as an explanation of the slowing of the reaction rate in the presence of olefin.
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