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In the reactions of interest alkanethiols are dramatically less reactive compared to arylthiols because of stronger S-H bond and lower acidity (see section 3 of the Supporting Information for BDE and pKa values, At the moment only quite expensive homogeneous Rh systems were reported to catalyze the transformations of that type involving AlkS groups, see: (a) Arisawa, M, Yamaguchi, M. Org. Lett. 2001, 3, 763
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In the reactions of interest alkanethiols are dramatically less reactive compared to arylthiols because of stronger S-H bond and lower acidity (see section 3 of the Supporting Information for BDE and pKa values). At the moment only quite expensive homogeneous Rh systems were reported to catalyze the transformations of that type involving AlkS groups, see: (a) Arisawa, M.; Yamaguchi, M. Org. Lett. 2001, 3, 763.
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See also refs 4a and 5c
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(h) See also refs 4a and 5c.
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45
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34250799580
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See section 2 of the Supporting Information for experimental details.
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See section 2 of the Supporting Information for experimental details.
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46
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34250899046
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See the Supporting Information for detailed description
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See the Supporting Information for detailed description.
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47
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34250810637
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Description of both procedures is given in section 4 of the Supporting Information.
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Description of both procedures is given in section 4 of the Supporting Information.
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48
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34250791443
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Mechanistic study is described in section 5 of the Supporting Information.
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Mechanistic study is described in section 5 of the Supporting Information.
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