Synthesis and structural comparison of TpiPr2Rh[cis-1,2-bis(diphenylphosphino)ethene]: factors determining hapticity (κ2 vs κ3) of the Tpipr2 ligand in Tpipr2Rh(diphosphine) complexes

Organometallics

Volumn 19, Issue 18, 2000, Pages 3744-3747

  Akita, Munetaka ^a   Hashimoto, Mariko ^a   Hikichi, Shiro ^a   Moro oka, Yoshihiko ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

BENZENE; COALESCENCE; COMPLEXATION; INFRARED SPECTROSCOPY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOSPHORUS COMPOUNDS; SPECTROSCOPIC ANALYSIS; STRUCTURE (COMPOSITION); SYNTHESIS (CHEMICAL); TEMPERATURE;

DIPHOSPHINE COMPLEXES; PENDANT PYRAZOLYL GROUP; RHODADIPHOSPHACYCLE;

ORGANOMETALLICS;

EID: 0034276162     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0003640     Document Type: Article

References (4)

1. (a) Trofimenko, S. Chem. Rev. 1993, 93, 943.
2. (b) Trofimenko, S. Scorpionates: The Coordination Chemistry of Polypyrazolylborate Ligands; Imperial College Press: London, England, 1999.
3. (c) Kitajima, N.; Tolman, W. B. Prog. Inorg. Chem. 1995, 43, 419.
4. ipr2; coe = cyclooctene; spl = square planar; spy = square pyramidal; tbp = trigonal bipyramidal.