Addition of benzenethiol to terminal alkynes catalyzed by hydrotris(3,5-dimethylpyrazolyl)borate-Rh(III) bis(thiolate) complex: Mechanistic studies with characterization of the key intermediate

Journal of Organometallic Chemistry

Volumn 691, Issue 14, 2006, Pages 3157-3164

  Misumi, Yoshiyuki ^a   Seino, Hidetake ^a   Mizobe, Yasushi ^a  

^a INSTITUTE OF INDUSTRIAL SCIENCE   (Japan)

Author keywords

Hydrothiolation of alkyne; Hydrotris(pyrazolyl)borate; Rhodathiacyclobutene; Rhodium(III) thiolato complexes

Indexed keywords

BENZENE; CATALYST ACTIVITY; COMPLEXATION; MOLECULAR STRUCTURE; SUBSTITUTION REACTIONS; X RAY DIFFRACTION;

HYDROTHIOLATION OF ALKYNE; HYDROTRIS(PYRAZOLYL)BORATE; RHODATHIACYCLOBUTENE; RHODIUM(III) THIOLATO COMPLEXES;

ORGANOMETALLICS;

EID: 33746893062     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2006.03.005     Document Type: Article

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