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2542597208
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note
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Obviously, the host-guest terminology applied here is arbitrary, and the model can be applied as well to multivalent hosts binding to guest-functionalized SAMs, multivalent ligands binding to receptor interfaces, etc..
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79
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2542617061
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note
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Competition with a monovalent guest, to block free surface host sites, is fully symmetric, both regarding thermodynamics and kinetics, with competition with a monovalent host. This is made plausible by noting that the overall interaction is determined by monovalent interactions and that it is arbitrary which partner of such an interaction is occupied by a monovalent competitor. Therefore, the mathematics of this type of competition is not incorporated here but could be worked out analogously. The case given here, competition with a species which prevents adsorption of the multivalent analyte, is most common when data are collected based on surface coverages.
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81
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84
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2542606357
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note
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2.
-
-
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85
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2542578892
-
-
note
-
tot = 0.1 mM, Figure 3) and electrochemistry data obtained for 3a and 3b (see ref 66). The difference (factor 1.3) is attributed to the surface roughness of the samples.
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87
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0032178662
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Beulen, M. W. J.; Bügler, J.; Lammerink, B.; Geurts, F. A. J.; Biemond, E. M. E. F.; Van Leerdam, K. G. C.; Van Veggel, F. C. J. M.; Engbersen, J. F. J.; Reinhoudt, D. N. Langmuir 1998, 14, 6424-6429.
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Beulen, M.W.J.1
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Lammerink, B.3
Geurts, F.A.J.4
Biemond, E.M.E.F.5
Van Leerdam, K.G.C.6
Van Veggel, F.C.J.M.7
Engbersen, J.F.J.8
Reinhoudt, D.N.9
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88
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5544308103
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Beulen, M. W. J.; Bügler, J.; De Jong, M. R.; Lammerink, B.; Huskens, J.; Schönherr, H.; Vancso, G. J.; Boukamp, B. A.; Wieder, H.; Offenhäuser, A.; Knoll, W.; Van Veggel, F. C. J. M.; Reinhoudt, D. N. Chem.-Eur. J. 2000, 6, 1176-1183.
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Offenhäuser, A.10
Knoll, W.11
Van Veggel, F.C.J.M.12
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89
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0035477684
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De Jong, M. R.; Huskens, J.; Reinhoudt, D. N. Chem.-Eur. J. 2001, 7, 4164-4170.
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De Jong, M.R.1
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90
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2542557685
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note
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s and V are dictated by our SPR setup.
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91
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2542594175
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Unpublished results
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Ludden, M. W. J.; Sartori, A.; Casnati, A.; Ungaro, R.; Huskens, J.; Reinhoudt, D. N. Unpublished results.
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Ludden, M.W.J.1
Sartori, A.2
Casnati, A.3
Ungaro, R.4
Huskens, J.5
Reinhoudt, D.N.6
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92
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2542604854
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note
-
SPR titrations for 2b, 3a, and 3b were performed using the same equipment and the same methodology as described for 2a (see ref 49) and earlier data (refs 48 and 59).
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93
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0030873618
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Castro, R.; Cuardo, I.; Alonso, B.; Casado, C. M.; Morán, M.; Kaifer, A. E. J. Am. Chem. Soc. 1997, 119, 5760-5761.
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94
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0034286427
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Michels, J. J.; Baars, M. W. P. L.; Meijer, E. W.; Huskens, J.; Reinhoudt, D. N. J. Chem. Soc., Perkin Trans. 2 2000, 1914-1918.
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Michels, J.J.1
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Reinhoudt, D.N.5
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95
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2542569731
-
-
note
-
-1. In principle, the same reasoning can be held for the larger dendrimers such as 3b, but its effect on both stoichiometry and binding affinity becomes negligible, since the number of dendritic arms in these cases is always larger than the number of accessible surface sites when solely judged on molecular sizes, and the change of the prefactor in eq 6 is only marginal.
-
-
-
-
97
-
-
2542554500
-
-
note
-
max < n, an analogous expression can be derived which contains an extra prefactor determined by statistical factors as given in eqs 5 and 6.
-
-
-
-
98
-
-
2542601771
-
-
note
-
l] is about 0.01 M, as it is limited by solubility.
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-
-
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99
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0344065544
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Balzani, V.; Clemente-León, M.; Credi, A.; Lowe, J. N.; Badjić, J. D.; Stoddart, J. F.; Williams, D. J. Chem.-Eur. J. 2003, 9, 5348-5360.
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Clemente-León, M.2
Credi, A.3
Lowe, J.N.4
Badjić, J.D.5
Stoddart, J.F.6
Williams, D.J.7
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100
-
-
2542581849
-
-
note
-
-1 in this case.
-
-
-
-
101
-
-
2542551431
-
-
note
-
max, indicating negative cooperativity.
-
-
-
-
102
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85022633060
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(a) Sasaki, D. Y.; Kurihara, K.; Kunitake, T. J. Am. Chem. Soc. 1991, 113, 9685-9686.
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Kunitake, T.5
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0040271412
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