Assessment of Cooperativity in Self-Assembly

Journal of the American Chemical Society

Volumn 125, Issue 51, 2003, Pages 16097-16103

  Ercolani, Gianfranco ^a  

^a UNIVERSITY OF ROME TOR VERGATA   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

COOPERATIVE EFFECTS;

MOLECULAR PHYSICS; PORPHYRINS; REACTION KINETICS;

SELF ASSEMBLY;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; COOPERATION; MOLECULAR DYNAMICS; MOLECULAR INTERACTION; SELF ASSEMBLY;

EID: 0346364990     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja038396c     Document Type: Article

References (53)

1. (a) Berg, J. M.; Stryer, L.; Tymoczko, J. L. Biochemistry, 5th ed.; Freeman: New York, 2002.
2. (b) Fersht, A. Structure and Mechanism in Protein Science; Freeman: New York, 1999.
3. (c) Hill, T. L. Cooperativity Theory in Biochemistry; Springer-Verlag: Berlin, 1984.
4. (d) Cantor, R. C.; Schimmel, P. R. Biophysical Chemistry, Part III; Freeman: New York, 1980.
5. (a) Connors, K. A. Binding Constants: The Measurement of Molecular Complex Stability; Wiley: New York, 1987; Chapter 2.
6. (b) Perlmutter-Hayman, B. Acc. Chem. Res. 1986, 19, 90-96.
7. For recent reviews on self-assembly, see: (a) Lehn, J.-M. Supramolecular Chemistry: Concepts and Perspectives; VCH Publishers: Weinheim, 1995.
8. (b) Whitesides, G. M.; Simanek, E. E.; Mathias, J. P.; Seto, C. T.; Chin, D. N.; Mammen, M.; Gordon, D. M. Acc. Chem. Res. 1995, 28, 37-44.
9. (c) Lawrence, D. S.; Jiang, T.; Levett, M. Chem. Rev. 1995, 95, 2229-2260.
10. (d) Philp, D.; Stoddart, J. F. Angew. Chem., Int. Ed. Engl. 1996, 35, 1154-1196.
11. (e) Comprehensive Supramolecular Chemistry; Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Vögtle, F., Sauvage, J.-P., Hosseini, M. W., Eds.; Pergamon: Oxford, 1996; Vol. 9.
12. (f) Zeng, F. W.; Zimmerman, S. C. Chem. Rev. 1997, 97, 1681-1712.
13. (g) Linton, B.; Hamilton, A. D. Chem. Rev. 1997, 97, 1669-1680.
14. (h) Conn, M. M.; Rebek, J. Chem. Rev. 1997, 97, 1647-1668.
15. (i) Fujita, M. Chem. Soc. Rev. 1998, 27, 417-425.
16. (j) Caulder, D. L.; Raymond, K. N. J. Chem. Soc., Dalton Trans. 1999, 1185-1200.
17. (k) Leininger, S.; Olenyuk, B.; Stang, P. J. Chem. Rev. 2000, 100, 853-908.
18. (l) Lindoy, L. F.; Atkinson, I. Self-Assembly in Supramolecular Systems (Monographs in Supramolecular Chemistry; Stoddart, J. F., Ed.; The Royal Society of Chemistry: Cambridge, U.K., 2000.
19. (m) Molecular Self-Assembly (Structure and Bonding); Fujita, M., Ed.; Springer: Heidelberg, 2000; Vol. 96.
20. (n) Swiegers, G. F.; Malefetse, T. J. Chem.-Eur. J. 2001, 7, 3636-3643.
21. (o) Albrecht, M. Chem. Rev. 2001, 101, 3457-3497.
22. (p) Rowan, S. J.; Cantrill, S. J.; Cousins, G. R. L.; Sanders, J. K. M.; Stoddart, J. F. Angew. Chem., Int. Ed. 2002, 41, 898-952.
23. (q) Seidel, S. R.; Stang, P. J. Acc. Chem. Res. 2002, 35, 972-983.
24. (r) Supramolecular Chemistry and Self-Assembly, Special Issue. Science 2002, 295, 2395-2421.
25. Ercolani, G. J. Chem. Soc., Chem. Commun. 2001, 1416-1417.
26. Ercolani, G. J. Phys. Chem. B 1998, 102, 5699-5703.
27. Ercolani, G. J. Phys. Chem. B 2003, 107, 5052-5057.
28. Mammen, M.; Choi, S.-K.; Whitesides, G. M. Angew. Chem., Int. Ed. 1998, 37, 2754-2794.
29. Scatchard, G. Ann. N.Y. Acad. Sci. 1949, 51, 660.
30. (a) Hill, A. V. J. Physiol. (London) 1910, 40, 4.
31. (b) Hill, A. V. Biochem. J. 1913, 7, 471.
32. c. Lowry, T. H.; Richardson, K. S. Mechanism and Theory in Organic Chemistry, 3rd ed.; Harper & Row: New York, 1987; pp 175-177.
33. Constable, E. In Comprehensive Supramolecular Chemistry; Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Vögtle, F., Sauvage, J.-P., Hosseini, M. W., Eds.; Pergamon: Oxford, 1996; Vol. 9, pp 213-252.
34. Pfeil, A.; Lehn, J.-M. J. Chem. Soc., Chem. Commun. 1992, 838-840.
35. ij values were distractedly associated with stepwise binding constants, it is evident from the context that they refer to overall binding constants.
36. (a) Jacobson, H.; Stockmayer, W. H. J. Chem. Phys. 1950, 18, 1600-1606.
37. (b) Ercolani, G.; Mandolini, L.; Mencarelli, P.; Roelens, S. J. Am. Chem. Soc. 1993, 115, 3901-3908.
38. + ions.
39. 2 for the sake of consistency with the indexes in eq 3.
40. Garrett, T. M.; Koert, U.; Lehn, J.-M. J. Phys. Org Chem. 1992, 5, 529-532.
41. Floquet, S.; Ouali, N.; Bocquet, B.; Bernardinelli, G.; Imbert, D.; Bünzli, J.-C. G.; Hopfgartner, G.; Piguet, C. Chem.-Eur. J. 2003, 9, 1860-1875.
42. Taylor, P. N.; Anderson, H. L. J. Am. Chem. Soc. 1999, 121, 11538-11545.
43. For recent examples, see: (a) ref 7.
44. (b) Calderone, C. T.; Williams, D. H. J. Am. Chem. Soc. 2001, 123, 6262-6267.
45. (c) Tobey, S. L.; Anslyn, E. V. J. Am. Chem. Soc. 2003, 125, 10963-10970.
46. For reviews on the concept of EM and its application to ring closure reactions, see: (a) Kirby, A. J. Adv. Phys. Org. Chem. 1980, 17, 183-278.
47. (b) Mandolini, L. Adv. Phys. Org. Chem. 1986, 22, 1-111.
48. (c) Galli, C.; Mandolini, L. Eur. J. Org. Chem. 2000, 3117-3125.
49. (a) Page, M. I.; Jencks, W. P. Proc. Natl. Acad. Sci. U.S.A. 1971, 68, 1678-1683.
50. (b) Page, M. I. Chem. Soc. Rev. 1973, 2, 295-323.
51. There are however different views underscoring the role of enthalpic effects. For example, see: (a) ref 19b.
52. (b) Bruice, T. C.; Lightstone, F. C. Acc. Chem. Res. 1999, 32, 127-136.
53. Leung, M.-K.; Mandal, A. B.; Wang, C.-C.; Lee, G.-H.; Peng, S.-M.; Cheng, H.-L-; Her, G.-R.; Chao, I.; Lu, H.-F.; Sun, Y.-C.; Shiao, M.-Y.; Chou, P.-T. J. Am. Chem. Soc. 2002, 124, 4287-4297.