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0347553840
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note
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-1; J. Szejtli, Comprehensive Supramolecular Chemistry, Vol. 3, Pergamon, Oxford, 1996), and thus dissociation rates follow directly from association rates and thermodynamics.
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25
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0348183353
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note
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-1 for calixarene guest 2.
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0037028971
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0347553838
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note
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-1) indicate that both Ad groups of the guest interact with both β-CD cavities of the dimer to form a 1:1 complex.
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28
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0348183351
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note
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Value obtained for a 1:1 model in which the β-CD SAM is treated as a SAM of dimeric hosts with a concentration of half the β-CD concentration at the surface.
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29
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0348183352
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note
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The contrast in the AFM images does not allow any conclusion on the amount of ink present on the patterns directly after printing or after subsequent washing. XPS and EIS measurements showed that: a) three to five monolayers of guest ink are transferred by μCP onto both OH- and β-CD-terminated SAMs; b) approximately one monolayer of guests is present after a first rinsing of the β-CD-terminated SAMs with water; c) submonolayer coverages remain on the β-CD-terminated SAMs upon prolonged washing with water and β-CD solutions (See Supporting Information). A monolayer is defined as a layer of the calixarene guest molecules bound through both Ad groups to two β-CD cavities at the surface.
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30
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0035815011
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