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Different hot stage designs have been described; see also refs, 11, 12, 13, 14, 15, 16, and 17: (a) Musevic, I.; Slak, G.; Blinc, R. Rev. Sci. Instrum. 1996, 67, 2554-2556. (b) Prilliman, S.G.; Kavanagh, A.M.; Scher, E.C.; Robertson, S.T.; Hwang, K.S.; Colvin, V.L. Rev. Sci. Instrum. 1998, 69, 3245-3250. (c) DiBattista M.; Patel, S.V.; Mansfield, J.F.; Schwank, J.W. Appl. Surf. Sci. 1999, 141, 119-128. (d) Takashige M.; Hamazaki, S.; Takahashi, Y.; Shimizu, F. Ferroelectrics 2000, 240, 1359-1366.
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Different hot stage designs have been described; see also refs, 11, 12, 13, 14, 15, 16, and 17: (a) Musevic, I.; Slak, G.; Blinc, R. Rev. Sci. Instrum. 1996, 67, 2554-2556. (b) Prilliman, S.G.; Kavanagh, A.M.; Scher, E.C.; Robertson, S.T.; Hwang, K.S.; Colvin, V.L. Rev. Sci. Instrum. 1998, 69, 3245-3250. (c) DiBattista M.; Patel, S.V.; Mansfield, J.F.; Schwank, J.W. Appl. Surf. Sci. 1999, 141, 119-128. (d) Takashige M.; Hamazaki, S.; Takahashi, Y.; Shimizu, F. Ferroelectrics 2000, 240, 1359-1366.
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-
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0011741919
-
-
note
-
If the temperature gradient between sample surface and AFM tip is eliminated, e.g., by working in liquid or by using heatable cantilevers, this effect is not present.
-
-
-
-
74
-
-
0011741011
-
-
note
-
It should be mentioned that it was necessary to adjust the excitation frequency of the cantilever oscillation at regular intervals due to condensation of n-alkanoic acid on top of the cantilever.
-
-
-
-
75
-
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0033884995
-
-
Plomp, M.; van Hoof, P.J.C.M.; van Enckevort, W.J.P. Surf. Sci. 2000, 448, 231-249.
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Plomp, M.1
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Van Enckevort, W.J.P.3
-
76
-
-
0011711027
-
-
note
-
In ref 22 the different relevant mechanisms of heat transfer are discussed. Solid solid conduction and conduction through a liquid film that forms owing to capillary condensation can be excluded based on the observed distance dependence; i.e., there is no physical contact between surface and tip. Due to its magnitude near-field radiative heat transfer may only become relevant for ultrahigh vacuum environments.
-
-
-
-
77
-
-
0011750067
-
-
note
-
Materials with low heat conduction are for instance typical organic and polymeric materials, with thermal conductivlties between 0.14 and 0.39 W/(K m).
-
-
-
-
79
-
-
0011709737
-
-
note
-
This estimate is based on the best fit for the experimental data obtained in argon and air and agrees very well with the geometry of the cantilever-tip assembly.
-
-
-
-
80
-
-
0011710512
-
-
note
-
This typical thickness is derived from AFM experiments.
-
-
-
-
82
-
-
0011710917
-
-
Reference 31, p 762
-
(b) Reference 31, p 762.
-
-
-
-
83
-
-
0011772921
-
-
note
-
It should be mentioned that the experimental data must be considered a lower estimate.
-
-
-
-
84
-
-
0011773767
-
-
note
-
Constant purge times were used; however, the glovebox is not sealed well enough to keep a 100% helium atmosphere.
-
-
-
-
87
-
-
0011773768
-
-
For a complete listing of references on morphological and kinetic work on the crystallization of PEO see refs 11, 12, 42, and 45
-
For a complete listing of references on morphological and kinetic work on the crystallization of PEO see refs 11, 12, 42, and 45.
-
-
-
-
88
-
-
0011739940
-
-
Personal communication
-
The film thicknesses of the solvent cast PEO films investigated by Vancso et al. were on the order of tens of micrometers (Vancso, G.J. Personal communication).
-
-
-
Vancso, G.J.1
-
89
-
-
0011710038
-
-
note
-
2.
-
-
-
-
91
-
-
0000405956
-
-
In addition, the lamellar growth rates are a strong function of film thickness for thicknesses below 200 nm (Schönherr, H.; Waymouth, R.M.; Hawker, C.J.; Frank, C.W. Polym. Mater. Sci. Eng. 2001, 84, 453-454). For the complete study of the film thickness and molar mass dependence of the crystallization of various PEO materials see: Schönherr, H.; Frank, C.W. In preparation.
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(2001)
Polym. Mater. Sci. Eng.
, vol.84
, pp. 453-454
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Schönherr, H.1
Waymouth, R.M.2
Hawker, C.J.3
Frank, C.W.4
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92
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0011743194
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In preparation
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In addition, the lamellar growth rates are a strong function of film thickness for thicknesses below 200 nm (Schönherr, H.; Waymouth, R.M.; Hawker, C.J.; Frank, C.W. Polym. Mater. Sci. Eng. 2001, 84, 453-454). For the complete study of the film thickness and molar mass dependence of the crystallization of various PEO materials see: Schönherr, H.; Frank, C.W. In preparation.
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Schönherr, H.1
Frank, C.W.2
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93
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0011741920
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note
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This estimate is based on the growth of a lamellar crystal over the distance of a typical scan size of 20 μm within the time elapsed to capture six subsequent images using the following parameters: resolution = 128 pixels/line, 16 lines scanned, scan rate = 2.5-5.0 Hz.
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96
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0011739726
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note
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43.
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97
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6544282165
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0042328491
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