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Volumn 17, Issue 10, 2015, Pages 2400-2403

Cobalt(III)-Catalyzed C-H Bond Amidation with Isocyanates

Author keywords

[No Author keywords available]

Indexed keywords

AMIDE; COBALT; ISOCYANIC ACID DERIVATIVE; ORGANOMETALLIC COMPOUND;

EID: 84929584706     PISSN: 15237060     EISSN: 15237052     Source Type: Journal    
DOI: 10.1021/acs.orglett.5b00910     Document Type: Article
Times cited : (141)

References (83)
  • 54
    • 84879872019 scopus 로고    scopus 로고
    • Wang, C. Synlett 2013, 24, 1606
    • (2013) Synlett , vol.24 , pp. 1606
    • Wang, C.1
  • 81
    • 84929601650 scopus 로고    scopus 로고
    • note
    • For Co(III)-catalyzed C-H bond additions to aldehydes to provide indazoles and furans, we found that the use of the noncoordinating B(C6F5)4 counterion was highly beneficial. See ref 14g for details.
  • 82
    • 84929601651 scopus 로고    scopus 로고
    • note
    • Reaction at the site of lower steric hindrance to provide a single regioisomer is consistent with other reports of Co(III)-catalyzed C-H bond additions to polarized π-bonds. For examples of aldehyde additions and cyanations, see refs 14g, 14b, 14h, and 14i, respectively.
  • 83
    • 84929601652 scopus 로고    scopus 로고
    • note
    • When phenyl(pyrrolidin-1-yl)methanone was also tested as a directing group under the optimized reaction conditions, amidation was not observed. For a Ru(II)-catalyzed amidation of secondary benzamides leading to phthalimides, see ref 11a.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.