Layer-by-layer assembled hybrid materials for sustainable applications

Current Organic Chemistry

Volumn 18, Issue 18, 2014, Pages 2315-2333

  Skorb, Ekaterina V ^a,b   Volkova, Anna V ^c   Andreeva, Daria V ^d  

^a MAX PLANCK INSTITUTE OF COLLOIDS AND INTERFACES   (Germany)

^b BELARUSIAN STATE UNIVERSITY   (Belarus)

^c ST PETERSBURG STATE UNIVERSITY   (Russian Federation)

^d UNIVERSITY OF BAYREUTH   (Germany)

Author keywords

Atomic molecular layer deposition; Layer by Layer; Organic inorganic hybrids; Stimuli responsive multilayers

Indexed keywords

BIOLOGICAL MATERIALS; BLOCK COPOLYMERS; DEPOSITION; HYBRID MATERIALS; HYDROGELS; MECHANICAL PERMEABILITY; MEDICAL APPLICATIONS; MICELLES; MOLECULAR WEIGHT; NANOPARTICLES; POLYELECTROLYTES; YARN;

ATOMIC / MOLECULAR LAYER DEPOSITION; BLOCK CO POLYMERS; HYBRIDS MATERIAL; LAYER BY LAYER; MOLECULAR LAYER DEPOSITION; ORGANIC/INORGANIC HYBRIDS; POLYELECTROLYTE BLOCKS; PROPERTY; STIMULI-RESPONSIVE; STIMULUS RESPONSIVE MULTILAYER;

NANOTUBES;

EID: 84925870084     PISSN: 13852728     EISSN: None     Source Type: Journal    
DOI: 10.2174/1385272819666140806200646     Document Type: Article

References (199)

1. [1] Skorb, E.V.; Andreeva, D.V. Layer-by-Layer approaches for formation of smart self-healing materials. Polym. Chem., 2013, 4, 4834-4845.
2. [2] Skorb, E.V.; Andreeva, D.V. Surface nanoarchitecture for bio-applications: Self-regulated intelligent interfaces. Adv. Func. Mater., 2013, 23, 4483-4506.
3. [3] Lavalle, P.; Voegel, J.C.; Vautier, D.; Senger, B.; Schaaf, P.; Ball, V. Dynamic aspects of films Prepared by a sequential deposition of species: Perspectives for smart and responsive materials. Adv. Mater., 2011, 23, 1191-1221.
4. [4] Biggs, S.; Sakai, K.; Addison, T.; Schmid, A.; Ames, S.P.; Vamvakaki, M.; Butun, V.; Webber, G. Layer-by-layer formation of smart particle coatings using oppositely charged block copolymer micelles. Adv. Mater., 2007, 19, 247-250.
5. [5] Zhai, L. Stimuli-responsive polymer film. Chem. Soc. Rev., 2013, 42, 7148-7160.
6. [6] Köhler, K.; Shchukin, D.G.; Möhwald, H.; Sukhorukov, G.B. Thermal behavior of polyelectrolyte multilayer microcapsules. 1. The effect of odd and even layer number. J. Phys. Chem. B, 2005, 109, 18250-18259.
7. [7] Glinel, K.; Sukhorukov, G.B.; Möhwald, H.; Khrenov, V.; Tauer, K. Thermosensitive hollow capsules based on thermoresponsive polyelectrolytes. Macromol. Chem. Phys., 2003, 204, 1784-1790.
8. [8] Serpe, M.J.; Jones, C.D.; Lyon, L.A. Layer-by-layer deposition of thermoresponsive microgel thin films. Langmuir, 2003, 19, 8759-8764.
9. [9] Jaber, J.A.; Schlenoff, J.B. Polyelectrolyte multilayers with reversible thermal responsivity. Macromolecules, 2005, 38, 1300-1306.
10. [10] South, A.B.; Lyon, L.A. Autonomic self-healing of hydrogel thin films. Angew. Chem. Int. Ed., 2010, 49, 767-771.
11. [11] Liang, X.; Kozlovskaya, V.; Chen, Y.; Zavgorodnya, O.; Kharlampieva, E. Thermosensitive multilayer hydrogels of poly(N-vinylcaprolactam) as nanothin films and shaped capsules. Chem. Mater., 2012, 24, 3707-3719.
12. [12] Quinn, J.F.; Caruso, F. Facile tailoring of film morphology and release properties using Layer-by-Layer assembly of thermoresponsive materials. Langmuir, 2004, 20, 20-22.
13. [13] Erel-Unal, I.; Sukhishvili, S.A. Hydrogen-bonded multilayers of a neutral polymer and a polyphenol. Macromolecules, 2008, 41, 3962-3970.
14. [14] Kozlovskaya, V.; Baggett, J.; Godin, B.; Liu, X.; Kharlampieva, E. Hydrogen-bonded multilayers of silk fibroin: From coatings to cell-mimicking shaped microcontainers. ACS Macro Lett., 2012, 1, 384-387.
15. [15] Yang, S.Y.; Rubner, M.F. Micropatterning of polymer thin films with pHsensitive and cross-linkable hydrogen-bonded polyelectrolyte multilayers. J. Am. Chem. Soc., 2002, 124, 2100-2101.
16. [16] Sukhishvili, S.A.; Granick, S. Layered, erasable, ultrathin polymer films. J. Am. Chem. Soc., 2000, 122, 9550-9551.
17. [17] Fix, D.; Andreeva, D.V.; Lvov, Y.M.; Shchukin, D.G.; Moehwald, H. Application of inhibitor-loaded halloysite nanotubes in active anti-corrosive coatings. Adv. Func. Mater., 2009, 19, 1720-1727.
18. [18] Farhat, T.R.; Schlenoff, J.B. Ion transport and equilibria in polyelectrolyte multilayers. Langmuir, 2001, 17, 1184-1192.
19. [19] Farhat, T.R.; Schlenoff, J.B. Corrosion control using polyelectrolyte multilayers. Electrochem. Sol-State Lett., 2002, 5, 13-17.
20. [20] Yue, M.; Hoshino, Y.; Ohshiro, Y.; Imamura, K.; Miura, Y. Temperatureresponsive microgel films as reversible carbon dioxide absorbents in wet environment. Angew. Chem. Int. Ed., 2014, 53, 2654-2657.
21. [21] Behl, M.; Lendlein, A. Actively moving polymers. Soft Matter, 2007, 3, 58-67.
22. [22] Hemmerlé, J.; Roucoules, V.; Fleith, G.; Nardin, M.; Ball, V.; Lavalle, P.; Marie, P.; Voegel, J.C.; Schaaf, P. Mechanically responsive films of variable hydrophobicity made of polyelectrolyte multilayers. Langmuir, 2005, 21, 10328-10331.
23. [23] Su, Y.X.; Ren, K.F.; Wang, J.L.; Chang, G.X.; Ji, J. Electrochemically controlled stiffness of multilayers for manipulation of cell adhesion. ACS Appl. Mater. Interfaces, 2013, 5, 4597-4602.
24. [24] Abdelkebir, K.; Gaudiere, F.; Morin-Grognet, S.; Coquerel, G.; Atmani, H.; Labat, B.; Ladam, G. Protein-triggered instant disassembly of biomimetic Layer-by-Layer Films. Langmuir, 2011, 27, 14370-14379.
25. [25] Gensel, J.; Borke, T.; Pazos-Pérez, N.; Fery, A.; Andreeva D.V.; Betthausen, E.; Müller, A.; Möhwald, H.; Skorb, E.V. Cavitation engineered 3D sponge networks and their application in active surface construction. Adv. Mater., 2012, 24, 985-989.
26. [26] Yuan, Z.; Wang, Y.; Chen, D. Preparation and characterization of thermo-, pH-, and magneticfield-responsive organic/inorganic hybrid microgels based on poly(ethylene glycol). J. Mater. Sci., 2014, 49, 3287-3296.
27. [27] Ryu, J.H.; Jiwpanich, S.; Chacko, R.; Bickerton, S.; Thayumanavan, S. Surface-functionalizable polymer nanogels with facile hydrophobic guest encapsulation capabilities. J. Am. Chem. Soc., 2010, 132, 8246-8247.
28. [28] Atzmon, M. In situ thermal observation of explosive compound-formation reaction during mechanical alloying. Phys. Rev. Lett., 1990, 64, 487-490.
29. [29] Skorb, E.V.; Baidukova, O.; Andreeva, O.; Cherepanov, P.V.; Andreeva, D.V. Formation of polypyrrole/metal hybrid interfacial layer with selfregulation functions via ultrasonication. Bioinspired, Biomimetic Nanobiomat., 2013, 2, 123-129.
30. [30] Andreeva D.V.; Sviridov, D.V.; Masic, A.; Möhwald, H.; Skorb, E.V. Nanoengineered metal surface capsules: Construction of a metal-protection system. Small, 2012, 8, 823-825.
31. [31] Skorb, E.V.; Baidukova, O.; Goyal, A.; Brotchie, A.; Andreeva, D.V.; Möhwald, H. Sononanoengineered magnesium-polypyrrole hybrid capsules with synergetic trigger release. J. Mater. Chem., 2012, 22, 13841-13848.
32. [32] Besner, S.; Meunier, M. Femtosecond laser synthesis of AuAg nanoalloys: Photoinduced oxidation and ions release. J. Phys. Chem. C, 2010, 114, 10403-10409.
33. [33] Herbani, Y.; Nakamura, T.; Sato, S. Synthesis of near-monodispersed Au-Ag nanoalloys by high intensity laser irradiation of metal ions in hexane. J. Phys. Chem. C, 2011, 115, 21592-21598.
34. [34] Iler, R.K. Multilayers of colloidal particles. J. Colloid Interface Sci., 1966, 21, 569-594.
35. [35] Decher, G. Fuzzy nanoassemblies: Toward layered polymeric multicomposites. Science, 1997, 277, 1232-1237.
36. [36] Decher, G.; Hong, J.D. Buildup of ultrathin multilayer films by a selfassembly process, 1 consecutive adsorption of anionic and cationic bipolar amphiphiles on charged surfaces. Macromol. Symp., 1991, 46, 321-327.
37. [37] Decher, G.; Hong, J.D. Buildup of ultrathin multilayer films by a selfassembly process, 2 consecutive adsorption of anionic and cationic bipolar amphiphiles and polyelectrolytes on charged surfaces. BerBunsenges Phys. Chem., 1991, 95, 1430-1434.
38. [38] Decher, G.; Hong, J.D.; Schmitt, J. Buildup of ultrathin multilayer films by a self-assembly process: III. Consecutively alternating adsorption of anionic and cationic polyelectrolytes on charged surfaces. Thin Solid Films, 1992, 210, 831-836.
39. [39] Mendelsohn, J.D.; Barrett, C.J.; Chan, V.V.; Pal, A.J.; Mayes, A.M.; Rubner, M.F. Fabrication of microporous thin films from polyelectrolyte multilayers. Langmuir, 2000, 16, 5017-5023.
40. [40] Vargo, T.G.; Calvert, J.M.; Wynne, K.J.; Avlyanov, J.K.; MacDiarmid, A.G.; Rubner, M.F. Patterned polymer multilayer fabrication by controlled adhesion of polyelectrolytes to plasma-modified fluoropolymer surfaces. Supramol. Sci., 1995, 2, 169-174.
41. [41] Ramsden, J.; Lvov, Y.M.; Decher, G. Determination of optical constants of molecular films assembled via alternate polyion adsorption. Thin Solid Film., 1995, 254, 246-251.
42. [42] Yoo, D.; Shiratori, S.S.; Rubner, M.F. Controlling bilayer composition and surface wettability of sequentially adsorbed multilayers of weak polyelectrolytes. Macromolecules, 1998, 31, 4309-4318.
43. [43] Kotov, N.; Dékány, I.; Fendler, J.H. Layer-by-layer self-assembly of polyelectrolyte-semiconductor nanoparticle composite films. J. Phys. Chem., 1995, 99, 13065-13069.
44. [44] Lvov, Y.; Ariga, K.; Ichinose, I.; Kunitake, T. Assembly of multicomponent protein films by means of electrostatic layer-by-layer adsorption. J. Am. Chem. Soc., 1995, 117, 6117-6123.
45. [45] Ferreira, M.; Rubner, M.F. Molecular-level processing of conjugated Polymers. 1. Layer-by-layer manipulation of conjugated polyions. Macromolecules, 1995, 28, 7107-7114.
46. [46] Hiller, J.; Mendelsohn, J.D.; Rubner, M.F. Reversibly erasable nanoporous anti-reflection coatings from polyelectrolyte multilayers. Nature Mater., 2001, 1, 59-63.
47. [47] Decher, G.; Lvov, Y.; Schmitt, J. Proof of multilayer structure organization in self-assembled polycation polyanion molecular film. Thin Solid Film, 1994, 244, 772-777.
48. [48] Schlenoff, J.B.; Ly, H.; Li, M. Charge and mass balance in polyelectrolyte multilayers. J. Am. Chem. Soc., 1998, 7626-7634.
49. [49] Shiratori, S.S.; Rubner, M.F. pH-dependent thickness of sequentially adsorbed layers of weak polyelectrolytes. Macromolecules, 2000, 33, 4213-4219.
50. [50] Chen, W.; McCarthy, T.J. Layer-by-Layer deposition: A tool for surface modification. Macromolecules, 1997, 30, 78-86.
51. [51] Sukhishvili, S.A. Responsive polymer films and capsules via layer-by-layer assembly. Curr. Opin. Coll. Interfaces Sci., 2005, 10, 37-44.
52. [52] Lvov, Y.; Ariga, K.; Onda, M.; Ichinose, I.; Kunitake, T. Alternate assembly of ordered multilayers of SiO2 and other nanoparticles and polyions. Lagmuir, 1997, 13, 6195-6203.
53. [53] Skorb, E.V.; Sviridov, D.V.; Möhwald, H.; Shchukin, D.G. Light responsive protective coatings. Chem. Commun., 2009, (40), 6041-6043.
54. [54] Skorb, E.V.; Shchukin, D.G.; Möhwald, H.; Sviridov, D.V. Photocatalytically-active and photocontrollable coatings based on titania-loaded hybrid sol-gel films. J. Mater. Chem., 2009, 19, 4931-4937.
55. [55] Estephan, Z.; Quin, Z.; Lee, D.; Crocker, J.; Park, S.J. Responsive multidomain free-standing films of gold nanoparticles assembled by DNA-directed Layer-by-Layer approach. NanoLett., 2013, 13, 4449-4455.
56. [56] Decher, G.; Lehr, B.; Lowack, K.; Lvov, Y.; Schmitt, J. New nanocomposite films for biosensors: Layer-by-layer adsorbed films ofpolyelectrolytes, proteins or DNA. Biosens. Bioelectron., 1994, 9, 677-684.
57. [57] Andreeva, D.V.; Gorin, D.A.; Shchukin, D.G.; Sukhorukov, G.B. Magnetic microcapsules with low permeable polypyrrole skin layer. Macromol. Rapid Commun., 2006, 27, 931-936.
58. [58] Bunge, A.; Fischlechner, M.; Loew, M.; Arbuzova, A.; Herrmann, A.; Huster, D.; Characterization of lipid bilayers adsorbed on spherical LbLsupport. Soft Matter, 2009, 5, 3331-3339.
59. [59] Richert, L.; Lavalle, P.; Payan, E.; Shu, X.Z.; Prestwich, G.D.; Stoltz, J.F.; Schaaf, P.; Voegel, J.C.; Picart, C. Layer by Layer buildup of polysaccharide films: Physical chemistry and cellular adhesion aspects. Langmuir, 2004, 20, 448-458.
60. [60] Holmes, C.; Daoud, J.; Bagnaninchi, P.O.; Tabrizian, M. Polyelectrolyte multilayer coating of 3D scaffolds enhances tissue growth and gene delivery: non-invasive and label-free assessment. Adv. Health. Mater., 2014, 3, 572-580.
61. [61] Yan, Y.; Such, G.; Johnston, A.P.R.; Lomas, H.; Caruso, F. Toward therapeutic delivery with Layer-by-Layer engineered particles. ACS Nano, 2011, 5, 4252-4257.
62. [62] Lu, Y.; Sarshar, M.A.; Du, K.; Chou, T.; Choi, C.H.; Sukhishvili, S.A. Large-amplitude, reversible, pH-triggered wetting transitions enabled by Layer-by-Layer films. ACS Appl. Mater. Interfaces, 2013, 5, 12617-12623.
63. [63] Hager, M.D.; Greil, P.; Leyens, C.; Van der Zwaag, S.; Schubert, U.S. Selfhealing materias. Adv. Mater., 2010, 22, 5424-5430.
64. [64] Burattini, S.; Greenland, B.W.; Chappell, D.; Colquhoun, H.M.; Hayes, W. Healable polymeric materials: A tutorial review. Chem. Soc. Rev., 2010, 39, 1973-1985.
65. [65] Syrett, J.A.; Becer, C.R.; Haddleton, D.M. Self-healing and self-mendable polymers. Polym. Chem., 2010, 1, 978-987.
66. [66] Dameron, A.A.; Seghete, D.; Burton, B.B.; Davidson, S.D.; Cavanagh, A.S.; Bertrand, J.A.; George, S.M. Molecular layer deposition of alucone polymer films using trimethylaluminum and ethylene glycol. Chem. Mater., 2008, 20, 3315-3326.
67. [67] Ishchuk, S.; Taffa, D.H.; Hazut, O.; Kaynan, N.; Yerushalmi, R. Transformation of organic-inorganic hybrid films obtained by molecular layer deposition to photocatalytic layers with enhanced activity. ACS Nano, 2012, 6, 7263-7269.
68. [68] Tseng, Y.C.; Mane, A.U.; Elam, J.W.; Darling, S.B. Ultrathin molybdenum oxide anode buffer layer for organic photovoltaic cells formed using atomic layer deposition. Solar Energ. Mater. Solar Cells, 2012, 99, 235-239.
69. [69] Wilson, C.A.; McCormick, J.A.; Cavanagh, A.S.; Goldsteina, D.N.; Weimerb, A.W.; George, S.M. Tungsten atomic layer deposition on polymers. Thin Solid Films, 2008, 516, 6175-6185.
70. [70] Park, Y.; Han, K.S.; Lee, B.H.; Choa, S.; Leeb, K.H.; Imb, S.; Sung, M.M. High performance n-type organic-inorganic nanohybrid semiconductors for flexible electronic devices. Organic Electronics, 2011, 12, 348-352.
71. [71] Dobrynin, A.V.; Rubinstein, M. Theory of polyelectrolytes in solutions and at surfaces. Prog. Polym. Sci., 2005, 30, 1049-1118.
72. [72] Such, G.; Johnston, A.P.R.; Caruso, F. Engineered hydrogen-bonded polymer multilayers: From assembly to biomedical applications. Chem. Soc. Rev., 2011, 40, 19-29.
73. [73] Li, J.; He, L.; Wang, J.; Zhang, Z.T.; Shi, J.; Zhang, X.Z.; Cao, Y.P.; Chen, Y. Light-controlled drug releasing polymer films combining LbL selfassembly and host-guest interactions. eXPRESS Polym. Lett., 2014, 8, 143-153.
74. [74] Ferreira, Q.; Ribeiro, P.A.; Oliveira, O.N.; Raposo, M. Long-term stability at high temperatures for birefringence in PAZO/PAH Layer-by-Layer films. ACS Appl. Mater. Interfaces, 2012, 4, 1470-1477.
75. [75] Gao, L.; Fei, J.; Zhao, J.; Cui, W.; Cui, Y.; Li, J. pH and redox-responsive polysaccharide-based microcapsules with autofluoreacence for biomedical application. Chem. Eur. J., 2012, 18, 3185-3192.
76. [76] Yao, H.; Hu, N. Triply responsive films in bioelectrocatalysis with a binary architecture: Combined Layer-by-Layer assembly and hydrogel polymerization. J. Phys. Chem. B, 2011, 6691-6699.
77. [77] Costa, R.R.; Custodio, A.; Arias, F.J.; Rodriguez-Cabello, J.C.; Mano, J.F. Layer-by-Layer assembly of chitosan and recombinant biopolymers into biomimetic coatings with multiple stimuli-responsive properties. Small, 2011, 7, 2640-2649.
78. [78] Jenekhe, S.A.; Chen, X.L. Self-assembly of ordered microporous materials from rod-coil block copolymers. Science, 1999, 283, 372-275.
79. [79] Zhu, Z.; Sukhishvili, S.A. Temperature-induced swelling and small molecule release with hydrogen-bonded multilayers of block copolymer micelles. ACS Nano, 2009, 3, 3595-3605.
80. [80] Joseph, V.S.; Kim, S.; Zhang, Q.; Hoogenboom, R.; Hong, J.D. Multilayer films composed of a thermoresponsive cationic diblock copolymer and a photoresponsive dye. Polymer, 2013, 54, 4894-4901.
81. [81] Zhu, Z.; Sukhishvili, A. Layer-by-layer films of stimuli-responsive block copolymer micelles. J. Mater. Chem., 2012, 22, 7667-7671.
82. [82] Xu, L.; Zhu, Z.; Sukhishvili, S.A. Polyelectrolyte multilayers of diblock copolymer micelles with temperature-responsive cores. Langmuir, 2011, 27, 409-415.
83. [83] Erel, I.; Zhu, Z.; Zhuk, A.; Sukhishvili, S.A.J. Hydrogen-bonded layer-bylayer films of block copolymer micelles with pH-responsive cores. Colloid Interface Sci., 2011, 355, 61-69.
84. [84] Kellum, M.G.; Harris, C.A.; McCormick, C.L.; Morgan, S.E. Stimuliresponsive micelles of amphiphilic AMPS-b-AAL copolymers in Layer-by-Layer films. J. Pol. Sci. A: Pol. Chem., 2011, 49, 1104-1111.
85. [85] Zhao, Z.; Yin, L.; Yuan, G.; Wang, L. Layer-by-layer assembly of two temperature-responsive homopolymers at neutral pH and the temperaturedependent solubility of the multilayer film. Langmuir, 2012, 28, 2704-2709.
86. [86] Lee, D.Y.; Kim, E.K.; Shin, C.Y.; Shinde, D.V.; Lee, W.; Shrestha, N.K.; Lee, J.K.; Han, S.H. Layer-by-layer deposition and photovoltaic property of Ru-based metal-organic frameworks. ARC Advances, 2014, 4, 12037-12042.
87. [87] Park, C.W.; South, A.B.; Hu, X.; Verdes, C.; Kim, J.D.; Lyon, L.A. Gold nanoparticles reinforce self-healing microgel multilayers. Colloid. Polym. Sci., 2011, 289, 583-590.
88. [88] Liang, X.; Kozlovskaya, V.; Chen, Y.; Zavgorodnya, O.; Kharlampieva, E. Thermosensitive multilayer hydrogels of poly(N-vinylcaprolactam) as nanothin films and shaped capsules. Chem. Mater., 2012, 24, 3707-3719.
89. [89] Poon, Y.F.; Cao, Y.; Liu, Y.; Chan, V.; Chan-Park, M.B. Hydrogels based on dual curable chitosan-graft-polyethylene glycol-graft-methacrylate: Application to layer-by-layer cell encapsulation. ACS Appl. Mater. Interfaces, 2010, 2, 2012-2025.
90. [90] Drachuk, I.; Shchepelina, O.; Lisunova, M.; Harbaugh, S.; Kelley-Loughnane, N.; Stone, M.; Tsukruk, V.V. pH-responsive Layer-by-Layer nanoshells for direct regulation of cell activity. ACS Nano, 2012, 6, 4266-4278.
91. [91] Dal’Acqua, N.; Ramos Scheffer, F.; Boniatti, R.; Mendonca da Silva, R.V.; Viana de Melo, J.; da Silva Crespo, J.; Giovanela, M.; Barbalho Pereira, M.; Weibel, D.E.; Machado, G. Photocatalytic nanostructured self-assembled poly(allylamine hydrochloride)/poly(acrylic acid) polyelectrolyte films containing titanium dioxide-gold nanoparticles for hydrogen generation. J. Phys. Chem. C, 2013, 117, 23235-23243.
92. [92] Loh, K.J.; Kim, J.; Lynch, J.P.; Kam, N.W.S.; Kotov, N.A. Multifunctional layer-by-layer carbon nanotube-polyelectrolyte thin films for strain and corrosion sensing. Smart Mater. Struct., 2007, 16, 429-438.
93. [93] Frueh, J.; Nakashima, N.; He, Q.; Möhwald, H. Effect of linear elongation on carbon nanotube and polyelectrolyte structures in PDMS-supported nanocomposite LbL films. J. Phys. Chem. B, 2012, 116, 12257-12262.
94. [94] Westcott, S.L.; Kotov, N.A.; Ostrander, J.W.; Mamedov, A.A.; Reust, D.K.; Roark, J.P. Corrosion protection by multifunctional stratified coatings. NSTINanotech, 2004, 3, 288-291.
95. [95] Veerabadran, N.G.; Mongayt, D.; Torchilin, V.; Price, R.R.; Lvov, Y.M. Organized shells on clay nanotubes for controlled release of macromolecules. Macromol. Rap. Commun., 2009, 30, 99-103.
96. [96] Fix, D.; Andreeva, D.V.; Lvov, Y.M.; Shchukin, D.G.; Moehwald, H. Application of inhibitor-loaded halloysite nanotubes in active anti-corrosive coatings. Adv. Func. Mater., 2009, 19, 1720-1727.
97. [97] Zhuk, A.; Mirza, R.; Sukhishvili, S. Multiresponsive clay-containing Layerby-Layer films. ACS Nano, 2011, 5, 8790-8799.
98. [98] Nolte, M.; Fery, A. Freestanding polyelectrolyte multilayers as functional and construction elements. IEE Proc., Nanobiotechnol., 2006, 153, 112-120.
99. [99] Jiang, C.; Tsukruk, V.V. Freestanding nanostructures via layer-by-layer assembly. Adv. Mater., 2006, 18, 829-840.
100. [100] Skirtach, A.G.; Karageorgiev, P.; Bedard, M.F.; Sukhorukov, G.B.; Moehwald, H. Reversibly permeable nanomembranes of polymeric microcapsules. J. Am. Chem. Soc., 2008, 130, 11572-11573.
101. [101] Skirtach, A.G.; Dejugnat, C.; Braun, D.; Susha, A.S.; Rogach, A.L.; Parak, W.J.; Mohwald, H.; Sukhorukov, G.B. The role of metal nanoparticles in remote release of encapsulated materials. Nano Lett., 2005, 5, 1371-1373.
102. [102] Trybala, A.; Szyk-Warszynska, L.; Warszynski, P. The effect of anchoring PEI layer on the build-up of polyelectrolyte multilayer films at homogeneous and heterogeneous surfaces. Coll. Surfaces A Phys. Chem Engineer. Aspects, 2009, 343, 127-132.
103. [103] Kolasinska, M.; Krastev, R.; Warszynski, P. The effect of anchoring PEI layer on the build-up of polyelectrolyte multilayer films at homogeneous and heterogeneous surfaces. J. Coll. Interfaces Sci., 2007, 305, 46-56.
104. [104] Elzbieciak, M.; Kolasinska, M.; Zapotoczny, S.; Krastev, R.; Nowakowska, M.; Warszynski, P. Nonlinear growth of multilayer films formed from weak polyelectrolytes. Coll. Surfaces A Phys. Chem Engineer. Aspects, 2009, 343, 89-95.
105. [105] Kolasinska, M.; Krastev, R.; Gutberlet, T.; Warszynski P. Layer by layer deposition of polyelectrolytes. Dipping vs. Spraying. Langmuir, 2009, 25, 1224-1232.
106. [106] Lefaux, C.J.; Zimberlin, J.A.; Dobrynin, A.V.; Mather, P.T. Polyelectrolyte spin assembly: Influence of ionic strength on the growth of multilayered thin films. J. Pol. Sci.: B: Pol. Phys., 2004, 42, 3654-3666.
107. [107] Kiel, M.; Mitzscherling, S.; Leitenberger, W.; Santer, S.; Tiersch, B.; Sievers, T.K.; Möhwald, H.; Bargheer, M. Structural characterization of a spinassisted colloid-polyelectrolyte assembly: Stratified multilayer thin films. Langmuir, 2010, 26, 18499-18502.
108. [108] Dubas, S.T.; Schlenoff, J.B. Swelling and smoothing of polyelectrolyte multilayers by salt. Langmuir, 2001, 17, 7725-7725.
109. [109] Frueh, J.; Reiter, G.; Möhwald, H.; He, Q.; Krastev, R. Orientation change of polyelectrolytes in linearly elongated polyelectrolyte multilayer measured by polarized UV spectroscopy. Coll. Surfaces A: Physicochem. Eng. Aspects, 2012, 415, 366-373.
110. [110] Yoo, D.; Shiratori, S.; Rubner, M.F. Controlling bilayer composition and surface wettability of sequentially adsorbed multilayers of weak polyelectrolytes. Macromolecules, 1998, 31, 4309-4318.
111. [111] Estillore, N.C.; Advincula, C. Stimuli-responsive binary mixed polymer brushes and free-standing films by LbL-SIP. Langmuir, 2011, 27, 5997-6008.
112. [112] Cui, X.Q.; Li, C.M.; Bao, H.F.; Zheng, X.T.; Lu, Z.S. In situ fabrication of silver nanoarrays in hyaluronan/PDDA layer-by-layer assembled structure. J. Coll. Inteface Sci., 2008, 327, 459-465.
113. [113] Salomäki, M.; Vinokurov, I.A.; Kankare, J. Effect of temperature on the buildup of polyelectrolyte multilayers. Langmuir, 2005, 21, 11232-11240.
114. [114] Vogt, C.; Ball, V.; Mutterer, J.; Schaaf, P.; Voegel, J.C.; Senger, B.; Lavalle, P. Mobility of proteins in highly hydrated polyelectrolyte multilayer films. J. Phys. Chem. B, 2012, 116, 5269-5278.
115. [115] Ladam, G.; Schaad, P.; Voegel, J.C.; Schaaf, P.; Decher, G.; Cuisinier, F. In situ determination of the structural properties of initially deposited polyelectrolyte multilayers. Langmuir, 2000, 16, 1249-1255.
116. [116] Han, L.; Yin, J.; Wang, L.; Chia, K.K.; Cohen, R.; Rubner, M.F.; Ortiz, C.; Boyce, M.C. Tunable stimulus-responsive friction mechanisms of polyelectrolyte films and tube forests. Soft Matter, 2012, 8, 8642-8650.
117. [117] Webber, G.B.; Wanless, E.J.; Armes, S.P.; Tang, Y.; Li, Y.; Biggs, S. Nanoanemones: Stimulus-responsive copolymer-micelle surfaces. Adv. Mater., 2004, 16, 1794-1798.
118. [118] Biggs, S.; Sakai, K.; Addison, T.; Schmid, A.; Armes, S.P.; Vamvakaki, M.; Bütün, V.; Webber, G.B. Layer-by-Layer formation of smart particle coatings using oppositely charged block copolymer micelles. Adv. Mater., 2007, 19, 247-250.
119. [119] Ionov, L.; Sidorenko, A.; Stamm, M. Gradient mixed brushes: "Grafting To" approach. Macromolecules, 2004, 37, 7421-7423.
120. [120] Minko, S.; Luzinov, I.; Luchnikov, V.; Muller, M.; Patil, S.; Stamm, M. Bidisperse mixed brushes:_ Synthesis and study of segregation in selective solvent. Macromolecules, 2003, 36, 7268-7279.
121. [121] Minko, S.; Muller, M.; Motornov, M.; Nitschke, M.; Grundke, K.; Stamm, M. Two-level structured self-adaptive surfaces with reversibly tunable properties. J. Am. Chem. Soc., 2003, 125, 3896-3900.
122. [122] Motornov, M.; Sheparovych, R.; Katz, E.; Minko, S. Chemical gating with nanostructured responsive polymer brushes: Mixed brush versus homopolymer brush. ACS Nano, 2008, 2, 41-52.
123. [123] Jones, D.M.; Brown, A.A.; Huck, W.T.S. Surface-initiated polymerizations in aqueous media: Effect of initiator density. Langmuir, 2002, 18, 1265-1269.
124. [124] Ionov, L.; Minko, S.; Stamm, M.; Gohy, J.F.; Jerome, R.; Scholl, A. Reversible chemical patterning on stimuli-responsive polymer film: Environment-responsive lithography. J. Am. Chem. Soc., 2003, 125, 8302-8306.
125. [125] Lin, Y.H.; Teng, J.; Zubarev, E.R.; Shulha, H.; Tsukruk, V.V. In-situ observation of switchable nanoscale topography for Y-shaped binary brushes in fluids. Nano Lett., 2005, 5, 491-495.
126. [126] Tan, W.S.; Cohen, R.E.; Rubner, M.F.; Sukhishvili, S.A. Temperatureinduced, reversible swelling transitions in multilayers of a cationic triblock copolymer and a polyacid. Macromolecules, 2010, 43, 1950-1957.
127. [127] Tan, W.S.; Zhu, Z.; Sukhishvili, S.A.; Rubner, M.F.; Cohen, R.E. Effect of block copolymer architecture on the thermally induced swelling of micellecontaining multilayer thin films. Macromolecules, 2011, 44, 7767-7774.
128. [128] Barthes, J.; Mertz, D.; Bach, C.; Metz-Boutigue, M.H.; Senger, B.; Voegel, J.C.; Schaaf, P.; Lavalle, P. Stretch-induced biodegradation of polyelectrolyte multilayer films for drug release. Langmuir, 2012, 28, 13550-13554.
129. [129] Mertz, D.; Hemmerlé, J.; Mutterer, J.; Ollivier, S.; Voegel, J.C.; Schaaf, P.; Lavalle, P. Mechanically responding nanovalves based on polyelectrolyte multilayers. NanoLett., 2007, 7, 657-662.
130. [130] Mertz, D.; Hemmerlé, J.; Boulmedais, F.; Voegel, J.C.; Lavalle, P.; Schaaf, P. Polyelectrolyte multilayer films under mechanical stretch. Soft Matter, 2007, 3, 1413-1420.
131. [131] Kolesnikova, T.A.; Gorin, D.A.; Fernandes, P.; Kessel, S.; Khomutov, G.B.; Fery, A.; Shchukin, D.G.; Möhwald, H. Nanocomposite microcontainers with high ultrasound sensitivity. Adv. Funct. Mater., 2010, 20, 1189-1195.
132. [132] Andreeva, D.V.; Fix, D.; Shchukin, D.G.; Möhwald, H. Self-healing anticorrosion coatings based on pH-sensitive polyelectrolyte/inhibitor sandwichlike nanostructures. Adv. Mater., 2008, 20, 2789-2794.
133. [133] Andreeva, D.V.; Skorb, E.V.; Shchukin, D.G. Layer-by-layer polyelectrolyte/ inhibitor nanostructures for metal corrosion protection. Appl. Mater. Interf., 2010, 2, 1954-1962.
134. [134] Ma, Y.; Dong, W.F.; Hempenius, M.A.; Möhwald, H.; Vancso, G.J. Redox controlled molecular permeability of composite-wall microcapsules. Nat. Mater., 2006, 5, 724-729.
135. [135] Jin, Z.; Güven, G.; Bocharova, V.; Halámek, J.; Tokarev, I.; Minko, S.; Melman, A.; Mandler, D.; Katz, E. Electrochemically controlled drugmimicking protein release from iron-alginate thin-films associated with an electrode. ACS Appl. Mater. Interfaces, 2012, 4, 466-475.
136. [136] Städler, B.; Chandrawati, R.; Goldie, K.; Caruso, F. Capsosomes: Sub compartmentalizing polyelectrolyte capsules using liposomes. Langmuir, 2009, 25, 6725-6732.
137. [137] Städler, B.; Price, A.D.; Chandrawati, R.; Hosta-Rigau, L.; Zelikin, A.N.; Caruso, F. Polymer hydrogel capsules: en route toward synthetic cellular systems. Nanoscale, 2009, 1, 68-73.
138. [138] Chandrawati, R.; van Koeverden, M.P.; Lomas, H.; Caruso, F. Multicompartment particle assemblies for bioinspired encapsulated reactions. J. Phys. Chem. Lett., 2011, 2, 2639-2649.
139. [139] George, S.M.; Ott, A.W.; Klaus, J.W. Surface chemistry for atomic layer growth. J. Phys. Chem., 1996, 100, 13121-13131.
140. [140] George, S.M. Atomic layer deposition: An overview. Chem. Rev., 2010, 110, 111-131.
141. [141] Koltsov, S.I. Polucheniye i issledovaniye produktov vzaimodeystviya chetyrekhkhloristogo titana s silikagelem. Zhurnal Prikladnoi Khimii, 1969, 81, 1023-1028.
142. [142] Moshe, H.; Mastai, Y. Atomic layer deposition on self-assembled monolayers. Mater. Sci., 2013, Ch. 3.
143. [143] Koshtyal, Yu M.; Malkov, A.A.; Taulemesse, J.M.; Petrov, S.N.; Krasilin, A.A; Malygin, A.A. Structural and chemical transformations in the products of theinteraction of silica gel with vapours of TiCl4 and H2O. Appl. Surf. Sci., 2014, 288, 584-590.
144. [144] Backman, L.B.; Rautiainen, A.; Lindblad, M.; Krause, A. The interaction of cobalt species with alumina on Co/Al2O3 catalysts prepared by atomic layer deposition. Appl. Cat. A: General, 2009, 360, 183-191.
145. [145] Tran, T.H.Y.; Haije, W.G.; Longo, V.; Kessels, W.M.; Schoonman, M.J. Plasma-enhanced atomic layer deposition of titania on alumina for its potential use as a hydrogen-selective membrane. J. Membr. Sci., 2011, 378, 438-443.
146. [146] Niskanen, A.J.; Varpula, A.; Utriainen, M.; Natarajan, G.; Cameron, D.C.; Novikov, S.; Airaksinen, V.M.; Sinkkonen, J.; Franssila, S. Atomic layer deposition of tin dioxide sensing film in microhotplate gas sensors. Sens. & Actuat. B, 2010, 148, 227-232.
147. [147] Purniawan, A.; French, P.J.; Pandraud, G.; Sarro, P.M. TiO2 ALD nanolayer as evanescent waveguide for biomedical sensor applications. Proc. Engineer., 2010, 5, 1131-1135.
148. [148] Choi, D.W.; Kim, S.J.; Lee, J.H.; Chung, K.B.; Park, J.S. A study of thin film encapsulation on polymer substrate using low temperature hybrid ZnO/Al2O3 layers atomic layer deposition. Current Appl. Phys., 2012, 12, S19-S23.
149. [149] Groner, M.D.; George, S.M.; McLean, R.S.; Carcia, P.F. Gas diffusion barriers on polymers using Al2O3 atomic layer deposition. Appl. Phys. Lett., 2006, 88, 051907.
150. [150] Dameron, A.A.; Davidson, S.D.; Burton, B.B.; Carcia, P.F.; McLean, R.S.; George, S.M. Gas diffusion barriers on polymers using multilayers fabricated by Al2O3 and rapid SiO2 atomic layer deposition. J. Phys. Chem. C, 2008, 112, 4573-4580.
151. [151] Wang, J.C.; Weng, W.T.; Tsai, M.Y.; Lee, M.K.; Horng, S.F.; Perng, T.P.; Kei, C.C; Yuc, C.C.; Meng, H.F. Highly efficient flexible inverted organic solar cells using atomic layer deposited ZnO as electron selective layer. J. Mater. Chem., 2010, 20, 862-866.
152. [152] Minton, T.K.; Wu, B.; Zhang, J.; Lindholm, N.F.; Abdulagatov, A.I.; O'Patchen, J.; George, S.M.; Groner, M.D. Protecting polymers with atomic layer deposition coatings. ACS Appl. Mater. Interfaces, 2010, 9, 2515-2520.
153. [153] Shao, H.I.; Umemoto, S.; Kikutani, T.; Okui, N. Layer-by-layer polycondensation of nylon 66 by alternating vapor deposition polymerization. Polymer, 1997, 38, 459-462.
154. [154] Du, Y.; George, S.M. Molecular layer deposition of Nylon 66 films examined using in situ FTIR spectroscopy. J. Phys. Chem. C, 2007, 111, 8509-8517.
155. [155] Putkonen, M.; Harjuoja, J.; Sajavaara, T.; Niinisto, L. Atomic layer deposition of polyimide thin films. J. Mater. Chem., 2007, 17, 664-669.
156. [156] Miyamae, T.; Tsukagoshi, K.; Matsuoka, O.; Yamamoto, S.; Nozoye, H. Preparation of polyimide-polyamide random copolymer thin film by sequential vapor deposition polymerization. J. Appl. Phys., Part 1., 2002, 41, 746-748.
157. [157] Yoon, K.H.; Han, K.S.; Sung, M.M. Fabrication of a new type of organicinorganic hybrid superlattice films combined with titanium oxide and polydiacetylene. Nanoscale Res. Lett., 2012, 7, 71.
158. [158] George, S.M.; Lee, B.H.; Yoon, B.; Abdulagatov, A.I.; Hall, R.A. Metalcones: Hybrid organic-inorganic films fabricated using atomic and molecular layer deposition techniques. J. Nanosci. Nanotech., 2011, 11, 1-8.
159. [159] Yoon, B.; Seghete, D.; Cavanagh, A.S.; George, S.M. Molecular layer deposition of hybrid organic-inorganic alucone polymer films using a three-step ABC reaction sequence. Chem. Mater., 2009, 21, 5365-5374.
160. [160] Yoon, B.; O’Patchen, J.L.; Seghete, D.; Cavanagh, A.S.; George, S.M. Molecular layer deposition of hybrid organic-inorganic polymer films using diethylzinc and ethylene glycol. Chem. Vapor Deposit., 2009, 15, 112-121.
161. [161] Tynell, T.; Karppinen, M. ZnO: Hydroquinone superlattice structures fabricated by atomic/molecular layer deposition. Thin Solid Films, 2014, 551, 23-26.
162. [162] Sood, S.; Sundberg, P.; Malm, J.; Karppinen, M. Layer-by-layer deposition of Ti-4,4--oxydianiline hybrid thin films. Appl. Surf. Sci., 2011, 257, 6435-6439.
163. [163] Skorb, E.V.; Fix, D.; Andreeva, D.V.; Shchukin, D.G.; Möhwald, H. Surface modified mesoporous SiO2 containers for corrosion protection. Adv. Funct. Mater., 2009, 19, 2373-2379.
164. [164] Sonawanec, S.H.; Bhanvasea, B.A.; Jamalia, A.A.; Dubeya, S.K.; Kalea, S.S.; Pinjari, D.V.; Kulkarnic, R.D. Improved active anticorrosion coatings using layer-by-layer assembled ZnO nanocontainers with benzotriazole. Chem. Engineer. J., 2012, 189, 464-472.
165. [165] Kuila, T.; Bose, S.; Mishra, A.K.; Khanra, P.; Kim, N.H.; Lee, J.H. Chemical functionalization of graphene and its applications. Prog. Mater. Sci., 2012, 57, 1061-1105.
166. [166] Jani, A.M.M.; Losic, D.; Voelcker, N.H. Nanoporous anodic aluminium oxide: Advances in surface engineering and emerging applications. Prog. Mater. Sci., 2013, 58, 636-704.
167. [167] Skorb, E.V.; Antonouskaya, L.I.; Belyasova, N.A.; Shchukin, D.G.; Möhwald, H.; Sviridov, D.V. Antibacterial activity of thin-film photocatalysts based on metal-modified TiO2 and TiO2:In2O3 nanocomposite. Appl. Catal. B: Environ., 2008, 84, 94-99.
168. [168] Skorb, E.V.; Andreeva, D.V.; Raiski, A.P.; Belyasova, N.A.; Möhwald, H.; Sviridov, D.V. Titanium dioxide for photocatalytic-assisted prophage induction to lytic cycle. Photochem. Photobiol. Sci., 2011, 10, 1974-1978.
169. [169] Song, X.; Li, H.; Tong, W.; Gao, C. Fabrication of triple-labeled polyelectrolyte microcapsules for localized ratiometric pH sensing. J. Coll. Interf. Sci., 2014, 416, 252-257.
170. [170] del Mercato, L.L.; Abbasi, A.Z.; Parak, W.J. Synthesis and characterization of ratiometric ion-sensitive polyelectrolyte capsules. Small, 2011, 7, 351-363.
171. [171] Gil, P.R.; Nazarenus, M.; Ashraf, S.; Parak, W.J. pH-sensitive capsules as intracellular optical reporters for monitoring lysosomal pH changes upon stimulation. Small, 2012, 8, 943-948.
172. [172] Halozan, D.; Riebentanz, U.; Brumen, M.; Donath, E. Polyelectrolyte microcapsules and coated CaCO3 particles as fluorescence activated sensors in flowmetry. Colloids Surf. A, 2009, 342, 115-121.
173. [173] Sato, K.; Takahashi, S.; Anzai, J. Layer-by-layer thin films and microcapsules for biosensors and controlled release. Anal. Sci., 2012, 28, 929-938.
174. [174] Collier, J.H.; Mrksich, M. Engineering a biospecific communication pathway between cells and electrodes. Proc. Natl. Acad. Sci. USA, 2006, 103, 2021-2025.
175. [175] Pajor-Ńwierzy, A.; Kolasińska-Sojka, M.; Warszyński, P. The electroactive multilayer films of polyelectrolytes and Prussian blue nanoparticles and their application for H2O2 sensors. Colloid. Polym. Sci., 2014, 292, 455-465.
176. [176] Liu, Y.; Liu, Y.; Feng, H.; Wu, Y.; Joshi, L.; Zeng, X.; Li J. Layer-by-layer assembly of chemical reduced graphene and carbon nanotubes for sensitive electrochemical immunoassay. Biosens. Bioelectr., 2012, 35, 63-68.
177. [177] Suntivich, R.; Shchepelina, O.; Choi, I.; Tsukruk, V.V. Inkjet-assisted layerby-layer printing of encapsulated arrays. ACS Appl. Mater. Interfaces, 2012, 4, 3102-3110.
178. [178] Chan, V.; Jeong, J.H.; Bajaj, P.; Collens, M.; Saif, T.; Kong, H.; Bashir, R. Multi-material bio-fabrication of hydrogel cantilevers and actuators with stereolithography. Lab Chip, 2012, 12, 88-98.
179. [179] White, S.R.; Sottos, N.R.; Geubelle, P.H.; Moore, J.S.; Kessler, M.R.; Sriram, S.R.; Brown, E.N.; Viswanathan, S. Autonomic healing of polymer composites. Nature, 2001, 409, 794-797.
180. [180] Shchukin, D.; Möhwald, H. A coat of many functions. Science, 2013, 341, 1458-1459.
181. [181] Toohey, K.S.; Sottos, N.R.; Lewis, J.A.; Moore, J.S.; White, S.R. Self-healing materials with microvascular networks. Nature Lett., 2007, 6, 581-585.
182. [182] Harrington, M.J.; Gupta, H.S.; Fratzl, P.; Waite, J.H. Collagen insulated from tensile damage by domains that unfold reversibly: In situ X-ray investigation of mechanical yield and damage repair in the mussel byssus. J. Struct. Biol., 2009, 167, 47-54.
183. [183] Harrington, M.J.; Masic, A.; Holten-Andersen, N.; Waite, J.H.; Fratzl, P. Iron-clad fibers: A metal-based biological strategy for hard flexible coatings. Science, 2010, 328, 216-220.
184. [184] Zedler, L.; Hager, M.D.; Schubert, U.S.; Harrington, M.J.; Schmitt, M.; Popp, J.; Dietzek, B. Monitoring the chemistry of self-healing by vibrational spectroscopy -current state and perspectives. Mater. Today, 2014, 17, 58-69.
185. [185] Liao, X.; Chen, G.; Jiang, M. Hydrogels locked by molecular recognition aiming at responsiveness and functionality. Polym. Chem., 2013, 4, 1733-1745.
186. [186] Nakahata, M.; Takashima, Y.; Yamaguchi, H.; Harada, A. Redox-responsive self-healing materials formed from host-guest polymers. Nature Comm., 2011, 2, 511.
187. [187] Wong, T.S.; Kang, S.H.; Tang, S.K.Y.; Smythe, E.Y.; Hatton, B.D.; Grinthal, A.; Aizenberg, J. Bioinspired self-repairing slippery surfaces with pressure-stable omniphobicity. Nature Lett., 2011, 477, 443-447.
188. [188] Chong, S.F.; Sexton, A.; De Rose, R.; Kent, S.J.; Zelikin, A.N.; Caruso, F. A paradigm for peptide vaccine delivery using viral epitopes encapsulated in degradable polymer hydrogel capsules. Biomaterials, 2009, 30, 5178-5186.
189. [189] De Geest, B.G.; Willart, M.A.; Hammad, H.; Lambrecht, B.N.; Pollard, C.; Bogaert, P. Polymeric multilayer capsule-mediated vaccination induces protective immunity against cancer and viral infection. ACS Nano, 2012, 6, 2136-2149.
190. [190] Skorb, E.V.; Möhwald, H. Dynamic interfaces for responsive encapsulation systems. Adv. Mater., 2013, 36, 5029-5043.
191. [191] Silva, A.K.A.; Corato, R.; Pellegrino, T.; Chat, S.; Pugliese, G.; Luciani, N.; Gazeaua, F.; Wilhelm, C. Cell-derived vesicles as a bioplatform for the encapsulation of theranostic nanomaterials. Nanoscale, 2013, 5, 11374-11384.
192. [192] Mari-Buye, N.; O’Shaughnessy, S.; Colominas, C.; Semino, C.E.; Gleason, K.K.; Borros, S. Functionalized, swellable hydrogel layers as a platform for cell studies. Adv. Funct. Mater., 2009, 19, 1276-1286.
193. [193] Yang, H.; Zheng, Y.; Zhao, B.; Shao, T.; Shi, Q.; Zhou, N.; Cai, W. Encapsulation of liver microsomes into a thermosensitive hydrogel for characterization of drug metabolism and toxicity. Biomaterials, 2013, 34, 9770-9778.
194. [194] Mayfield, A.E.; Tilokee, E.L.; Latham, N.; McNeill, B.; Lam, B.K.; Ruel, M.; Suuronen, E.J.; Courtman, D.W.; Stewart, D.J.; Davis, D.R. The effect of encapsulation of cardiac stem cells within matrix-. enriched hydrogel capsules on cell survival, post-ischemic cell retention and cardiac function. Biomaterials, 2014, 35, 133-142.
195. [195] Qiao, P.; Wang, J.; Xie, Q.; Li, F.; Dong, L.; Xu, T. Delivering MC3T3-E1 cells into injectable calcium phosphate cement through alginate-chitosan microcapsules for bone tissue engineering. Mater. Sci. Engineer. C, 2013, 33, 4633-4639.
196. [196] Paunescu, D.; Puddu, M.; Soellner, J.O.B.; Stoessel, P.R.; Grass, R.N. Protection and deprotection of DNA -high-temperature stability of nucleic acid barcodes for polymer labeling. Nature Prot., 2013, 8, 2440-2448.
197. [197] Lathuilière, A.; Cosson, S.; Lutolf, M.P.; Schneider, B.L.; Aebischer, P. A high-capacity cell macroencapsulation system supporting the long-term survival of genetically engineered allogeneic cells. Biomaterials, 2014, 35, 779-791.
198. [198] van der Pol, E.; Boing, A.N.; Harrison, P.; Sturk, A.; Nieuwland, R. Classification, functions, and clinical relevance of extracellular vesicles. Pharmacol. Rev., 2012, 64, 676-705.
199. [199] Silva, A.K.A.; Corato, R.; Pellegrino, T.; Chat, S.; Pugliese, G.; Luciani, N.; Gazeaua, F.; Wilhelm, C. Cell-derived vesicles as a bioplatform for the encapsulation of theranostic nanomaterials. Nanoscale, 2013, 5, 11374-11384.