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2 indicated the following composition: C, 65.86%; O, 33.34%; S, 0.47%; Mn, 0.12%; Na, 0.21%.
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85033184155
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note
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The adsorptions described here are most certainly irreversible.
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A specific enthalpic interaction between PET and the substrate polymer is not necessary for adsorption. The adsorption could be driven by a decrease in interfacial free energy and/ or by entropy (release of water molecules from the interface). These factors are discussed in: Shoichet, M. S.; McCarthy, T. J. Macromolecules 1991, 24, 1441.
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85033179908
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note
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The relatively high manganese concentration for the sevenlayer sample is anomalous. We have not repeated this experiment.
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