Theory of polyelectrolytes in solutions and at surfaces

Progress in Polymer Science (Oxford)

Volumn 30, Issue 11, 2005, Pages 1049-1118

  Dobrynin, Andrey V ^a   Rubinstein, Michael ^b  

^a UNIVERSITY OF CONNECTICUT   (United States)

^b University of North Carolina at Chapel Hill   (United States)

Author keywords

Condensation of counterions; Counterions; Distribution of counterions; Dynamics of polyelectrolytes; Hydrophobic polyelectrolytes; Ion containing polymers; Polyelectrolyte solutions; Polyelectrolytes; Rheology of polyelectrolytes

Indexed keywords

ADSORPTION; CONDENSATION; CONFORMATIONS; DISSOCIATION; HYDROPHOBICITY; INTERFACES (MATERIALS); IONIZATION; MULTILAYERS; PERMITTIVITY; RHEOLOGY; SOLUTIONS; SOLVENTS; SURFACE CHEMISTRY;

CONDENSATION OF COUNTERIONS; COUNTERIONS; DISTRIBUTION OF COUNTERIONS; DYNAMICS OF POLYELECTROLYTES; HYDROPHOBIC POLYELECTROLYTES; ION-CONTAINING POLYMERS; POLYELECTROLYTE SOLUTIONS; RHEOLOGY OF POLYELECTROLYTES;

POLYELECTROLYTES;

EID: 26644435758     PISSN: 00796700     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.progpolymsci.2005.07.006     Document Type: Review

References (260)

1. S. Forster, and M. Schmidt Polyelectrolytes in solution Adv Polym Sci 120 1995 51 133
2. J.L. Barrat, and J.F. Joanny Theory of polyelectrolyte solutions Adv Chem Phys 94 1996 1 66
3. K.S. Schmitz Macroions in solution and colloidal suspension 1993 VCH Publishers
4. C. Tanford Physical chemistry of macromolecules 1961 Wiley New York
5. F. Oosawa Polyelectrolytes 1971 Marcel Dekker New York
6. Polyelectrolytes. New York: Marcel Dekker; 1993.
7. T. Radeva Physical chemistry of polyelectrolytes 2001 Marcel Dekker New York
8. M. Doi, and S.F. Edwards The theory of polymer dynamics 1989 Clarendon Press Oxford
9. P.G. de Gennes Scaling concepts in polymer physics 1979 Cornell University Press Ithaca, NY
10. M. Rubinstein, and R.H. Colby Polymer physics 2003 Oxford University Press New York
11. R.M. Fuoss Viscosity function for polyelectrolytes J Polym Sci 3 1948 603
12. G. Decher Multilayer films (polyelectrolytes) In: The polymeric materials encyclopedia: synthesis, properties and applications 1996 CRC Press Boca Raton, FL
13. G. Decher Fuzzy nanoassemblies: toward layered polymeric multicomposites Science 277 1997 1232 1237
14. G. Decher, M. Eckle, J. Schmitt, and B. Struth Layer-by-layer assembled multicomposite films Curr Opin Colloid Interface Sci 3 1998 32 39
15. P.T. Hammond Recent explorations in electrostatic multilayer thin film assembly Curr Opin Colloid Interface Sci 4 1999 430 442
16. M. Schonhoff Self-assembled polyelectrolyte multilayers Curr Opin Colloid Interface Sci 8 2003 86 95
17. M. Schonhoff Layered complexes: physics of formation and molecular properties J Phys Condens Matter 15 2003 R1781 R1808
18. D. Frenkel, and B. Smit Understanding molecular simulations 2001 Academic Press San Diego
19. D.C. Rapaport The art of molecular dynamics simulation 1995 Cambridge University Press New York
20. W. Kuhn, O. Kunzle, and A. Katchalsky Verhalten polyvalenter fadenmolekelionen in losung Helv Chim Acta 1948 1994 2037
21. L.D. Landau, and E.M. Lifshitz Electrodynamics of continuous media 1984 Addison-Wesley Reading, MA
22. A.Y. Grosberg, and A.R. Khokhlov Statistical physics of macromolecules 1994 AIP Press New York
23. P.-G. de Gennes, P. Pincus, F. Brochard, and R.M. Velasco Remarks on polyelectrolyte conformation J Phys (France) 37 1976 1461 1476
24. A.R. Khokhlov, and K.A. Khachaturian On the theory of weakly charged polyelectrolytes Polymer 23 1982 1793 1802
25. A.V. Dobrynin, R.H. Colby, and M. Rubinstein Scaling theory of polyelectrolyte solutions Macromolecules 28 1995 1859 1871
26. Q. Liao, A.V. Dobrynin, and M. Rubinstein Molecular dynamics simulations of polyelectrolyte solutions: nonuniform stretching of chains and scaling behavior Macromolecules 36 2003 3386 3398
27. G. Migliorini, V. Rostiashvili, and T.A. Vilgis Weak violation of universality for polyelectrolyte chain: variational theory and simulations Eur Phys J E 4 2001 475 487
28. M. Castelnovo, P. Sens, and J.F. Joanny Charge distribution on annealed polyelectrolytes Eur Phys J E 1 2000 115 125
29. M. Ullner, B. Jonsson, and P.O. Widmark Conformational properties and apparent dissociation constants of titrating polyelectrolytes: Monte Carlo simulations and scaling arguments J Chem Phys 100 1994 3365 3366
30. A. Katchalsky, and H. Eisenberg Molecular weight of polyacrylic and polymethacrylic acid J Polym Sci 6 1951 145 154
31. H. Morawetz Revisiting some phenomena in polyelectrolyte solutions J Polym Sci Part B Polym Phys 40 2002 1080 1086
32. D.A. McQuarrie Statistical mechanics 1976 Harper & Row New York
33. L. Rayleigh Philos Mag 14 1882 184
34. A.V. Dobrynin, M. Rubinstein, and S.P. Obukhov Cascade of transitions of polyelectrolytes in poor solvent Macromolecules 29 1996 2974 2979
35. H.H. Hooper, S. Beltran, A.P. Sassi, H.W. Blanch, and J.M. Prausnitz Monte Carlo simulations of hydrophobic polyelectrolytes. Evidence for a structural transition in response to increasing chain ionization J Chem Phys 93 1990 2715 2723
36. P.G. Higgs, and H. Orland Scaling behavior of polyelectrolytes and polyampholytes: simulation by an ensemble growth method J Chem Phys 95 1991 4506 4518
37. P. Chodanowski, and S. Stoll Monte Carlo simulations of hydrophobic polyelectrolytes: evidence of complex configurational transitions J Chem Phys 111 1999 6069 6081
38. A.V. Lyulin, B. Dunweg, O.V. Borisov, and A.A. Darinskii Computer simulation studies of a single polyelectrolyte chain in poor solvent Macromolecules 32 1999 3264 3278
39. F.J. Solis, and M. Olvera de la Cruz Variational approach to necklace formation in polyelectrolytes Macromolecules 31 1998 5502 5506
40. A.C. Balazs, C. Singh, E. Zhulina, S.S. Chern, Y. Lyatskaya, and G. Pickett Theory of polymer chains tethered at interfaces Prog Surf Sci 55 1997 181 269
41. G. Migliorini, N. Lee, V. Rostiashvili, and T.A. Vilgis Polyelectrolyte chains in poor solvent, a variational description of necklace formation Eur Phys J E 6 2001 259 270
42. M.N. Tamashiro, and H. Schiessel Stepwise unwinding of polyelectrolytes under stretching Macromolecules 33 2000 5263 5272
43. T.A. Vilgis, A. Johner, and J.F. Joanny Stretching necklaces Eur Phys J E 2 2000 289 300
44. T.A. Vilgis, A. Johner, and J.F. Joanny Polyelectrolyte gels in poor solvent: elastic moduli Eur Phys J E 3 2000 237 244
45. C. Holm, J.F. Joanny, K. Kremer, R.R. Netz, P. Reineker, and C. Seidel Polyelectrolyte theory Adv Polym Sci 166 2004 67 111
46. H.J. Limbach, C. Holm, and K. Kremer Structure of polyelectrolytes in poor solvent Europhys Lett 60 2002 566 572
47. A.R. Khokhlov On the collapse of weakly charged polyelectrolytes J Phys A 13 1980 979 987
48. E. Raphael, and J.-F. Joanny Annealed and quenched polyelectrolytes Europhys Lett 13 1990 623 628
49. A.V. Dobrynin, and M. Rubinstein Counterion condensation and phase separation in solutions of hydrophobic polyelectrolytes Macromolecules 34 2001 1964 1972
50. G.S. Manning Limiting laws and counterion condensation in polyelectrolyte solutions 1. Colligative properties J Chem Phys 51 1969 924 933
51. G.S. Manning Counterion condensation theory constructed from different models Physica A 231 1996 236 253
52. G.S. Manning The critical onset of counterion condensation: A survey of its experimental and theoretical basis Ber Bunsen Ges Phys Chem Chem Phys 100 1996 909 922
53. G.S. Manning, and J. Ray Counterion condensation revisited J Biomol Struct Dyn 16 1998 461 476
54. M. Muthukumar Theory of counter-ion condensation on flexible polyelectrolytes: adsorption mechanism J Chem Phys 120 2004 9343 9350
55. E.Y. Kramarenko, A.R. Khokhlov, and K. Yoshikawa A three-state model for counterions in a dilute solution of weakly charged polyelectrolytes Macromol Theory Simul 9 2000 249 256
56. A. Katchalsky, Z. Alexandrowicz, and O. Kedem Polyelectrolyte solutions B.E. Conway R.G. Barradas Chemical physics of ionic solutions 1966 Wiley London 295 346
57. Z. Alexandrowicz, and A. Katchalsky Colligative properties of polyelectrolyte solutions in excess of salt J Polym Sci Part A 1 1963 3231 3260
58. T. Alfrey, P.V. Berg, and H. Morawetz The counterion distribution in solutions of rod-shaped polyelectrolytes J Polym Sci 7 1951 543 551
59. R.M. Fuoss, A. Katchalsky, and S. Lifson The potential of an infinite rod-like molecule and the distribution of counterions Proc Natl Acad Sci USA 37 1951 579 586
60. A. Deshkovski, S. Obukhov, and M. Rubinstein Counterion phase transitions in dilute polyelectrolyte solutions Phys Rev Lett 86 2001 2341 2344
61. Q. Liao, A.V. Dobrynin, and M. Rubinstein Molecular dynamics simulations of polyelectrolyte solutions: osmotic coefficient and counterion condensation Macromolecules 36 2003 3399 3410
62. R.R. Netz, and H. Orland Variational charge renormalization in charged systems Eur Phys J E 11 2003 301 311
63. A.Y. Grosberg, T.T. Nguyen, and B.I. Shklovskii Colloquium: the physics of charge inversion in chemical and biological systems Rev Mod Phys 74 2002 329 345
64. P. Gonzalez-Mozuelos, and M. Olvera de la Cruz Ion condensation in salt-free dilute polyelectrolyte solutions J Chem Phys 103 1995 3145 3157
65. P.J. Flory Molecular configuration of polyelectrolytes J Chem Phys 21 1953 162 163
66. H. Schiessel, and P. Pincus Counterion-condensation-induced collapse of highly charged polyelectrolytes Macromolecules 31 1998 7953 7959
67. H. Schiessel Counterion condensation on flexible polyelectrolytes: dependence on ionic strength and chain concentration Macromolecules 32 1999 5673 5680
68. N.V. Brilliantov, D.V. Kuznetsov, and R. Klein Chain collapse and counterion condensation in dilute polyelectrolyte solutions Phys Rev Lett 81 1998 1433 1436
69. H.J. Limbach, and C. Holm End effects of strongly charged polyelectrolytes: a molecular dynamics study J Chem Phys 114 2001 9674 9682
70. M.J. Stevens, and K. Kremer The nature of flexible linear polyelectrolytes in salt-free solution - a molecular-dynamics study J Chem Phys 103 1995 1669 1690
71. U. Micka, C. Holm, and K. Kremer Strongly charged, flexible polyelectrolytes in poor solvents: molecular dynamics simulations Langmuir 15 1999 4033 4044
72. U. Micka, and K. Kremer Strongly charged flexible polyelectrolytes in poor solvents - from stable spheres to necklace chains Europhys Lett 49 2000 189 195
73. A.V. Dobrynin M. Kotelyanskii D.N. Theodorou Simulation methods for polymers 2004 Marcel Dekker New York 259 312
74. R.G. Winkler, M. Gold, and P. Reineker Collapse of polyelectrolyte macromolecules by counterion condensation and ion pair formation: a molecular dynamics simulation study Phys Rev Lett 80 1998 3731 3734
75. H.J. Limbach, and C. Holm Conformational properties of poor solvent polyelectrolytes Comput Phys Commun 147 2002 321 324
76. S. Ulrich, A. Laguecir, and S. Stoll Titration of hydrophobic polyelectrolytes using Monte Carlo simulations J Chem Phys 122 2005 0949111 0949119
77. T. Odijk Polyelectrolytes near the rod limit J Polym Phys Part B Polym Phys 15 1977 477 483
78. J. Skolnick, and M. Fixman Electrostatic persistence length of a wormlike polyelectrolyte Macromolecules 10 1977 944 948
79. T. Odijk Possible scaling relations for semidilute polyelectrolyte solutions Macromolecules 12 1979 658 693
80. R.R. Netz, and H. Orland Variational theory for a single polyelectrolyte chain Eur Phys J B 8 1999 81 98
81. B.Y. Ha, and D. Thirumalai Persistence length of flexible polyelectrolyte chains J Chem Phys 110 1999 7533 7541
82. M. Manghi, and R.R. Netz Variational theory for a single polyelectrolyte chain revisited Eur Phys J E 14 2004 67 77
83. H. Li, and T.A. Witten Fluctuations and persistence length of charged flexible polymers Macromolecules 28 1995 5921 5927
84. T.B. Liverpool, and M. Stapper The scaling behaviour of screened polyelectrolytes Europhys Lett 40 1997 485 490
85. M. Schmidt Numerical evaluation of the electrostatic persistence length of polyelectrolytes Macromolecules 24 1991 5361 5364
86. J.L. Barrat, and J.-F. Joanny Persistence length of polyelectrolyte chains Europhys Lett 24 1993 333 339
87. B.Y. Ha, and D. Thirumalai Electrostatic persistence length of a polyelectrolyte chain Macromolecules 28 1995 577 581
88. S.F. Edwards, and P. Singh Size of polymer molecule in solution J Chem Soc Faraday Trans II 75 1979 1001 1019
89. M. Muthukumar Double screening in polyelectrolyte solutions: limiting laws and crossover formulas J Chem Phys 105 1996 5183 5199
90. K. Ghosh, G.A. Carri, and M. Muthukumar Configurational properties of a single semiflexible polyelectrolyte J Chem Phys 115 2001 4367 4375
91. D. Bratko, and K.A. Dawson A mean field approach to the structure of polyelectrolytes J Chem Phys 99 1993 5352 5364
92. C.E. Reed, and W.F. Reed Monte-Carlo electrostatic persistence length compared with experiment and theory J Chem Phys 94 1991 8479 8486
93. C. Seidel Polyelectrolyte simulation Ber Bunsen Ges Phys Chem Chem Phys 100 1996 757 763
94. H. Schafer, and C. Seidel Structure of polyelectrolytes in solutions. A Monte Carlo study Macromolecules 30 1997 6658 6661
95. M. Ullner, B. Jonsson, C. Peterson, O. Sommelius, and B. Soderberg The electrostatic persistence length calculated from Monte Carlo, variational and perturbation methods J Chem Phys 107 1997 1279 1287
96. U. Micka, and K. Kremer The persistence length of polyelectrolyte chains J Phys Condens Matter 8 1996 9463 9470
97. U. Micka, and K. Kremer Persistence length of the Debye-Huckel model of weakly charged flexible polyelectrolyte chains Phys Rev E 54 1996 2653 2662
98. M. Tricot Comparison of experimental and theoretical persistence length of some polyelectrolytes at various ionic strengths Macromolecules 17 1984 1698 1703
99. C.E. Reed, and W.F. Reed Monte-Carlo study of light-scattering by linear polyelectrolytes J Chem Phys 97 1992 7766 7776
100. S. Forster, M. Schmidt, and M. Antonietti Experimental and theoretical investigation of the electrostatic persistence length of flexible polyelectrolytes at various ionic strengths J Phys Chem 96 1992 4008 4014
101. A.E.J. de Nooy, A.C. Besemer, H. van Bekkum, J. van Dijk, and J.A.M. Smit TEMPO-mediated oxidation of pullalan and influence of ionic strength and linear charge density on the dimensions of the obtained polyelectrolyte chain Macromolecules 29 1996 6541 6547
102. K. Nishida, H. Urakawa, K. Kaji, B. Gabrys, and J.S. Higgins Electrostatic persistence length of NaPSS polyelectrolytes determined by a zero average contrast SANS technique Polymer 38 1997 6083 6085
103. J.J. Tanahatoe Dynamic light scattering of flexible higly charged polyelectrolytes at infinite dilution J Phys Chem B 101 1997 10442 10445
104. M. Beer, M. Schmidt, and M. Muthukumar The electrostatic expansion of linear polyelectrolytes: effect of gegenions, co-ions, and hydrophobicity Macromolecules 30 1997 8375 8385
105. T.T. Nguyen, and B.I. Shklovskii Persistence length of a polyelectrolyte in salty water: Monte Carlo study Phys Rev E 66 2002
106. R. Everaers, A. Milchev, and V. Yamakov The electrostatic persistence length of polymers beyond the OSF limit Eur Phys J E 8 2002 3 14
107. M. Ullner, and C.E. Woodward Orientational correlation function and persistence lengths of flexible polyelectrolytes Macromolecules 35 2002 1437 1445
108. F. Bordi, C. Cametti, J.S. Tan, D.C. Boris, W.E. Krause, and N. Plucktaveesak Determination of polyelectrolyte charge and interaction with water using dielectric spectroscopy Macromolecules 35 2002 7031 7038
109. F. Bordi, R.H. Colby, C. Cametti, L. De Lorenzo, and T. Gili Electrical conductivity of polyelectrolyte solutions in the semidilute and concentrated regime: the role of counterion condensation J Phys Chem B 106 2002 6887 6893
110. P. Pfeuty Conformation des polyelectrolytes ordre dans les solutions de polyelectrolytes J Phys France Coll 39 1978 C2-149
111. M. Rubinstein, R.H. Colby, and A.V. Dobrynin Dynamics of semidilute polyelectrolyte solutions Phys Rev Lett 73 1994 2776 2779
112. M. Drifford, and J.P. Dalbiez Light scattering by dilute solutions of salt-free polyelectrolytes J Phys Chem 88 1984 5368
113. M. Nierlich, C.E. Williams, F. Boue, J.P. Cotton, M. Daoud, and B. Farnoux Small angle neutron scattiring by semidilute solutions of polyelectrolytes J Phys (Paris) 40 1979 701
114. M. Nierlich, F. Boue, and A. Lapp Radius of gyration of a polyion in salt free polyelectrolyte solutions measured by SANS J Phys (Paris) 46 1985 649 658
115. R. Kakehashi, H. Yamazoe, and H. Maeda Osmotic coefficients of vinylic polyelectrolyte solutions without added salt Colloid Polym Sci 276 1998 28 33
116. R. Kakehashi, and H. Maeda Donnan equilibria of simple electrolytes in polyelectrolyte solutions J Chem Soc Faraday Trans 92 1996 3117 3121
117. R. Kakehashi, and H. Maeda Donnan equilibria of simple electrolytes in polyelectrolyte solutions. 2. Extension to polycations and the effect of charge densities J Chem Soc Faraday Trans 92 1996 4441 4444
118. E. Raspaud, M. de Conceicao, and F. Livolant Do free DNA counterions control the osmotic pressure? Phys Rev Lett 84 2000 2533 2536
119. P.L. Hansen, R. Podgornik, and A.V. Parsegian Osmotic properties of DNA: critical evaluation of counterion condensation theory Phys Rev E 64 1997 0219071 0219074
120. M. Reddy, and J.A. Marinsky A further investigation of the osmotic properties of hydrogen and sodium polystyrenesulfonate J Phys Chem 74 1970 3884 3891
121. L. Wang, and V.A. Bloomfield Osmotic pressure of polyelctrolytes with added salt Macromolecules 23 1990 804 809
122. R.S. Koene, T. Nicolai, and M. Mandel Scaling relations for aqueous polyelectrolyte-salt solutions. 3. Osmotic pressure as a function of molar mass and ionic strength in the semidilute regime Macromolecules 16 1983 231 237
123. A. Takahashi, N. Kato, and M. Nagasawa The osmotic pressure of polyelectrolyte in neutral salt solutions J Phys Chem 74 1970 944
124. T.A. Kavassalis, and J. Noolandi New view of entanglements in dense polymer systems Phys Rev Lett 59 1987 2674 2677
125. T.A. Kavassalis, and J. Noolandi A new theory of entanglements and dynamics in dense polymer systems Macromolecules 21 1988 2869 2879
126. T.A. Kavassalis, and J. Noolandi Entanglement scaling in polymer melts and solutions Macromolecules 22 1989 2709 2720
127. D.C. Boris, and R.H. Colby Rheology of sulfonated polystyrene solutions Macromolecules 31 1998 5746 5755
128. M.G. Oostwal, M.H. Blees, J. de Bleijser, and J.C. Leyte Chain self-diffusion in aqueous salt-free solutions of sodium poly(styrenesulfonate) Macromolecules 26 1993 7300 7308
129. M.G. Oostwal, and T. Odijk Novel dynamic scaling hypothesis for semidilute and concentrated solutions of polymers and polyelectrolytes Macromolecules 26 1993 6489 6497
130. A.V. Dobrynin, and M. Rubinstein Hydrophobic polyelectrolytes Macromolecules 32 1999 915 922
131. Essafi W. PhD Thesis, Paris; 1996.
132. M.N. Spiteri, F. Boue, A. Lapp, and J.P. Cotton Persistence length for a PSSNa polyion in semidilute solution as a function of the ionic strength Phys Rev Lett 77 1996 5218 5220
133. M.N. Spiteri, F. Boue, A. Lapp, and J.P. Cotton Polyelectrolyte persistence length in semidilute solution as a function of the ionic strength Physica B 234 1997 303 305
134. C. Heitz, M. Rawiso, and J. Francois X-ray scattering study of a poly(methacrylic acid) sample as a function of its neutralization degree Polymer 40 1999 1637 1650
135. T.A. Waigh, R. Ober, C.E. Williams, and J.C. Galin Semidilute and concentrated solutions of a solvophobic polyelectrolyte in nonaqueous solvents Macromolecules 34 2001 1973 1980
136. D. Qu, D. Baigl, C.E. Williams, H. Mohwald, and A. Fery Dependence of structural forces in polyelectrolyte solutions on charge density: a combined AFM/SAXS study Macromolecules 36 2003 6878 6883
137. D. Baigl, R. Ober, D. Qu, A. Fery, and C.E. Williams Correlation length of hydrophobic polyelectrolyte solutions Europhys Lett 62 2003 588 594
138. V.O. Aseyev, S.I. Klenin, H. Tenhu, I. Grillo, and E. Geissler Neutron scattering studies of the structure of a polyelectrolyte globule in a water-acetone mixture Macromolecules 34 2001 3706 3709
139. M.J. Lee, M.M. Green, F. Mikes, and H. Morawetz NMR spectra of polyelectrolytes in poor solvents are consistent with the pearl necklace model of the chain molecules Macromolecules 35 2002 4216 4217
140. A. Kiriy, G. Gorodyska, S. Minko, W. Jaeger, P. Stepanek, and M. Stamm Cascade of coil-globule conformational transitions of single flexible polyelectrolyte molecules in poor solvent J Am Chem Soc 124 2002 13454 13462
141. S. Minko, A. Kiriy, G. Gorodyska, and M. Stamm Single flexible hydrophobic polyelectrolyte molecules adsorbed on solid substrate: transition between a stretched chain, necklace-like conformation and a globule J Am Chem Soc 124 2002 3218 3219
142. Liao Q, Dobrynin AV, Rubinstein M. Molecular dynamics simulations of polyelectrolytes in poor solvent. Submitted for publication.
143. A.R. Khokhlov, and I.A. Nyrkova Compatability enhancement and microdomain structuring in weakly charged polyelectrolyte mixtures Macromolecules 25 1992 1493 1502
144. M. Muthukumar Phase diagram of polyelectrolyte solutions: weak polymer effect Macromolecules 35 2002 9142 9145
145. V.Y. Borue, and I.Y. Erukhimovich A statistical theory of weakly charged polyelectrolytes: fluctuations, eqaution of state, and microphase separation Macromolecules 21 1988 3240 3249
146. T.A. Vilgis, and R. Borsali Mean-field theory of concentrated polyelectrolyte solutions Phys Rev A 43 1991 6857 6873
147. K.K. Mahdi, and M. Olvera de la Cruz Phase diagrams of salt-free polyelectrolyte semidilute solutions Macromolecules 33 2000 7649 7654
148. A.V. Ermoshkin, and M. Olvera de la Cruz Polyelectrolytes in the presence of multivalent ions: gelation versus segregation Phys Rev Lett 2003 90
149. G. Orkoulas, S.K. Kumar, and A.Z. Panagiotopoulos Monte Carlo study of coulombic criticality in polyelectrolytes Phys Rev Lett 90 2003 048303
150. N. Volk, D. Vollmer, M. Schmidt, W. Oppermann, and K. Huber Conformation and phase diagrams of flexible polyelectrolytes 2004
151. J.-F. Joanny, and L. Leibler Weakly charged polyelectrolytes in a poor solvent J Phys 51 1990 545 557
152. O. Braun, F. Boue, and F. Candau Microphase separation in weakly charged hydrophobic polyelectrolytes Eur Phys J E 7 2002 141 151
153. E.E. Dormidontova, I.Y. Erukhimovich, and A.R. Khokhlov Microphase separation in poor-solvent polyelectrolyte solutions - phase-diagram Macromol Theory Simul 3 1994 661 675
154. R.W. Chang, and A. Yethiraj Strongly charged flexible polyelectrolytes in poor solvents: molecular dynamics simulations with explicit solvent J Chem Phys 118 2003 6634 6647
155. A. Yethiraj Conformational properties and static structure factor of polyelectrolyte solutions Phys Rev Lett 78 1997 3789 3792
156. A. Yethiraj Theory for chain conformations and static structure of dilute and semidilute polyelectrolyte solutions J Chem Phys 108 1998 1184 1192
157. A. Yethiraj, and C.Y. Shew Structure of polyelectrolyte solutions Phys Rev Lett 77 1996 3937 3940
158. K.S. Schweizer, and J.G. Curro PRISM theory of the strucuture, thermodynamics, and phase transitions of polymer liquids and alloys Adv Polym Sci 116 1994 319 377
159. D. Laria, D. Wu, and D. Chandler Reference interaction site model polaron theory of the hydrated electron J Chem Phys 95 1991 4444 4453
160. L.V. Zherenkova, Y.A. Kriksin, S.K. Talitskikh, and P.G. Khalatur Application of the integral equation theory to rodlike polyelectrolytes in a poor solvent Polym Sci Ser A 44 2002 791 799
161. T. Hofmann, R.G. Winkler, and P. Reineker Integral equation theory approach to rodlike polyelectrolytes: counterion condensation J Chem Phys 114 2001 10181 10188
162. T. Hofmann, R.G. Winkler, and P. Reineker Influence of salt on the structure of polyelectrolyte solutions: an integral equation theory approach J Chem Phys 119 2003 2406 2413
163. C.Y. Shew, and A. Yethiraj Self-consistent integral equation theory for semiflexible chain polyelectrolyte solutions J Chem Phys 113 2000 8841 8847
164. C.Y. Shew, and A. Yethiraj Integral equation theory for the structure of DNA solutions J Chem Phys 116 2002 5308 5314
165. L. Zherenkova, P. Khalatur, and K. Yoshikawa Self-consistent integral equation theory for semiflexible polyelectrolytes in poor solvent Macromol Theory Simul 12 2003 339 353
166. T. Hofmann, R.G. Winkler, and P. Reineker Self-consistent integral equation theory for solutions of finite extensible semiflexible polyelectrolyte chains J Chem Phys 118 2003 6624 6633
167. M. Muthukumar Double screening in polyelectrolyte solutions: limiting laws and crossover formulas J Chem Phys 105 1996 5183 5199
168. Q. Wang, T. Taniguchi, and G.H. Fredrickson Self-consistent field theory of polyelectrolyte systems J Phys Chem B 108 2004 6733 6744
169. M. Kawaguchi, and A. Takahashi Polymer adsorption at solid liquid interfaces Adv Colloid Interface Sci 37 1992 219 317
170. G.J. Fleer, M.A. Cohen Stuart, J.M.H.M. Scheutjens, T. Gasgove, and B. Vincent Polymer at interfaces 1993 Chapman and Hall London
171. A.K. Bajpai Interface behaviour of ionic polymers Prog Polym Sci 22 1997 523 564
172. J. Lyklema Fundamentals of interface and colloid science: solid-liquid interfaces 1995 Academic Press London
173. R.R. Netz, and D. Andelman Neutral and charged polymers at interfaces Phys Rep Rev Sect Phys Lett 380 2003 1 95
174. F.W. Wiegel Adsorption of a macromolecule to a charged surface J Phys Condens Matter 10 1977 299
175. F.W. Wiegel In: Phase transition and critical phenomena VII 1983 Academic New York
176. T. Odijk Binding of long flexible chain to a rod-like macromolecule Macromolecules 13 1980 1542 1546
177. M. Muthukumar Adsorption of a polyelectrolyte chain to a charged surface J Chem Phys 86 1987 7230 7235
178. M. Muthukumar Pattern-recognition by polyelectrolytes J Chem Phys 103 1995 4723 4731
179. C.Y. Kong, and M. Muthukumar Monte Carlo study of adsorption of a polyelectrolyte onto charged surfaces J Chem Phys 109 1998 1522 1527
180. M. Ellis, C.Y. Kong, and M. Muthukumar Polyelectrolyte adsorption on heterogeneously charged surfaces J Chem Phys 112 2000 8723 8729
181. O.V. Borisov, E.B. Zhulina, and T.M. Birshtein Polyelectrolyte molecule conformation near charged surface J Phys II 4 1994 913 929
182. V. Yamakov, A. Milchev, O. Borisov, and B. Dunweg Adsorption of a polyelectrolyte chain on a charged surface: a Monte Carlo simulation of sealing behavior J Phys Condens Matter 11 1999 9907 9923
183. S. Beltran, H. Hooper, H. Blanch, and J. Prausnitz Monte Carlo study of polyelectrolyte adsorption - isolated chains on a planar charged surfaces Macromolecules 24 1991 3178 3184
184. C.A. Hoeve Theory of polymer adsorption at interfaces J Polym Sci C34 1971 1 10
185. C.A. Hoeve The general theory of polymer adsorption at a surface J Polym Sci C30 1970 361 367
186. F.Th. Hesselink On the theory of polyelectrolyte adsorption. The effect of adsorption behavior of the electrostatic contribution to the adsorption free energy J Colloid Interface Sci 60 1977 448 466
187. J.M. Scheutjens, and G.J. Fleer Statistical theory of the adsorption of interacting chain molecules. 1. Partition function, segment density distribution, and adsorption isotherm J Phys Chem 83 1979 1619 1635
188. J.M. Scheutjens, and G.J. Fleer Statistical theory of the adsorption of interacting chain molecules. 2. Train, loop, and tail size distribution J Phys Chem 84 1980 178 190
189. H.A. van der Schee, and J. Lyklema Lattice theory of polyelectrolyte adsorption J Phys Chem 88 1984 6661 6672
190. O. Evers, G.J. Fleer, J.M.H. Scheutjens, and J. Lyklema Adsorption of weak polyelectrolytes from aqueous solution J Colloid Interface Sci 111 1986 446 454
191. M.R. Bohmer, O. Evers, and J.M.H. Scheutjens Weak polyelectrolytes between two surfaces - adsorption and stabilization Macromolecules 23 1990 2288 2301
192. A.W.P. Vermeer, F.A.M. Leermakers, and L.K. Koopal Adsorption of weak polyelectrolytes on surfaces with a variable charge. Self-consistent-field calculations Langmuir 13 1997 4413 4421
193. M.A. Dahlgren, and F.A.M. Leermakers Depletion zones in polyelectrolyte systems - polydispersity effects and colloidal stability Langmuir 11 1995 2996 3006
194. R. Varoqui, A. Johner, and A. Elaissari Conformation of weakly charged polyelectrolyte at a liquid solid interface J Chem Phys 94 1991 6873 6878
195. R. Varoqui Structure of weakly charged polyelectrolyte at a solid-liquid interface J Phys II 3 1993 1097 1108
196. R. Varoqui Structure and stability of weakly charged polyelectrolyte at a solid-liquid interface In: Macro-ion characterization, ACS simposium series vol. 548 1994 p. 421-35
197. I. Borukhov, D. Andelman, and H. Orland Scaling laws of polyelectrolyte adsorption Macromolecules 31 1998 1665 1671
198. X. Chatellier, and J.F. Joanny Adsorption of polyelectrolyte solutions on surfaces: a Debye-Huckel theory J Phys II 6 1996 1669 1686
199. I. Borukhov, D. Andelman, and H. Orland Polyelectrolyte solutions between charged surfaces Europhys Lett 32 1995 499 504
200. I. Borukhov, D. Andelman, and H. Orland Effect of polyelectrolyte adsorption on intercolloidal forces J Phys Chem B 103 1999 5042 5057
201. I. Borukhov Adsorption of polyelectrolytes and inter-colloidal forces Physica A 249 1998 315 320
202. A. Yethiraj Forces between surfaces immersed in polyelectrolyte solutions J Chem Phys 111 1999 1797 1800
203. M.A. Carignano, and N. Dan Density inhomogeneities of highly charged polyelectrolyte solutions confined between uncharged and nonadsorbing walls Langmuir 14 1998 3475 3478
204. W. Barford, R. Ball, and C.M. Nex A nonequilibrium configuration theory of polyelectrolyte adsorption J Chem Soc Faraday Trans I 82 1986 3233 3244
205. W. Barford, and R. Ball Towards a complete configurational theory of nonequilibrium polymer adsorption J Chem Soc Faraday Trans I 83 1987 2515 2523
206. M.A.C. Stuart, C.W. Hoogendam, and A. deKeizer Kinetics of polyelectrolyte adsorption J Phys Condens Matter 9 1997 7767 7783
207. R.R. Netz, and J.F. Joanny Adsorption of semiflexible polyelectrolytes on charged planar surfaces: charge compensation, charge reversal, and multilayer formation Macromolecules 32 1999 9013 9025
208. A.V. Dobrynin, A. Deshkovski, and M. Rubinstein Adsorption of polyelectrolytes at an oppositely charged surface Phys Rev Lett 84 2000 3101 3104
209. A.V. Dobrynin, A. Deshkovski, and M. Rubinstein Adsorption of polyelectrolytes at oppositely charged surfaces Macromolecules 34 2001 3421 3436
210. A.V. Dobrynin Effect of solvent quality on polyelectrolyte adsorption at an oppositely charged surface J Chem Phys 114 2001 8145 8153
211. A.V. Dobrynin, and M. Rubinstein Adsorption of hydrophobic polyelectrolytes at oppositely charged surfaces Macromolecules 35 2002 2754 2768
212. A.V. Dobrynin, and M. Rubinstein Effect of short-range interactions on polyelectrolyte adsorption at charged surfaces J Phys Chem B 107 2003 8260 8269
213. T.T. Nguyen, A.Y. Grosberg, and B.I. Shklovskii Screening of a charged particle by multivalent counterions in salty water: strong charge inversion J Chem Phys 113 2000 1110 1125
214. T.T. Nguyen, A.Y. Grosberg, and B.I. Shklovskii Macroions in salty water with multivalent ions: giant inversion of charge Phys Rev Lett 85 2000 1568 1571
215. J.F. Joanny Polyelectrolyte adsorption and charge inversion Eur Phys J B 9 1999 117 122
216. J.F. Joanny, M. Castelnovo, and R. Netz Adsorption of charged polymers J Phys Condens Matter 12 2000 A1 A7
217. O.V. Borisov, F. Hakem, T.A. Vilgis, J.F. Joanny, and A. Johner Adsorption of hydrophobic polyelectrolytes onto oppositely charged surfaces Eur Phys J E 6 2001 37 47
218. B.I. Shklovskii Wigner crystal model of counterion induced bundle formation of rodlike polyelectrolytes Phys Rev Lett 82 1999 3268 3271
219. B.I. Shklovskii Screening of a macroion by multivalent ions: correlation-induced inversion of charge Phys Rev E 60 1999 5802 5811
220. I. Rouzina, and V.A. Bloomfield Competitive electrostatic binding of charged ligands to polyelectrolytes: planar and cylindrical geometries J Phys Chem 100 1996 4292 4304
221. R.R. Netz Electrostatistics of counter-ions at and between planar charged walls: from Poisson-Boltzmann to the strong-coupling theory Eur Phys J E 5 2001 557 574
222. S. Safran Statistical thermodynamics of surfaces, interfaces and membranes 1994 Addison-Wesley Reading, MA
223. R.R. Netz Debye-Huckel theory for interfacial geometries Phys Rev E 60 1999 3174 3182
224. R. Messina Effect of image forces on polyelectrolyte adsorption Phys Rev E 70 2004 0518021 0518029
225. C.-H. Cheng, and P.-Y. Lai Adsorption transition of a polyelectrolyte on a high-dielectric charge substrate Phys Rev E 70 2004 0618051 0618054
226. G. Durand, F. Lafuma, and R. Audebert Adsorption of cationic polyelctrolytes at clay-colloid interface in dilute aqueous suspensions-effect of the ionic strength of the medium Prog Colloid Polym Sci 266 1988 278 282
227. E. Hendrickson, and R.D. Neuman Polyacrylamide adsorption from very dilute solutions J Colloid Interface Sci 110 1986 243 251
228. R.H. Pelton Electrolyte effects in the adsorption and desorption of a cationic polyacrylamide on cellulose fibers J Colloid Interface Sci 111 1986 475 485
229. G. Durand-Piana, F. Lafuma, and R. Audebert Flocculation and adsorption properties of cationic polyelectrolytes toward Na-montmorillonite dilute suspensions J Colloid Interface Sci 119 1987 474 480
230. T.K. Wang, and R. Audebert Adsorption of cationic copolymers of acrylamide at the silica water interface - hydrodynamic layer thickness measuremenrts J Colloid Interface Sci 121 1988 32 41
231. R.J. Davies, L.R. Dix, and C. Toprakcioglu Adsorption of poly-l-lysine to mica powder J Colloid Interface Sci 129 1989 145 152
232. V. Shubin, and P. Linse Effect of electrolytes on adsorption of cationic polyacrylamide on silica - ellipsometric study and theoretical modeling J Phys Chem 99 1995 1285 1291
233. M. Kawaguchi, H. Kawaguchi, and A. Takahashi Competitive and displacement adsorption of polyelectrolyte and water-soluble nonionic polymer at the silica surface J Colloid Interface Sci 124 1988 57 62
234. Bonekamp, BC. PhD thesis, Wagenningen Agricultural University, The Netherlands; 1984.
235. J. Marra, H.A. van der Schee, G.J. Fleer, and J. Lyklema R. Ottiwel C.H. Rochester A.L. Smith Adsorption in solutions 1983 Academic Press London 245
236. F.J. Solis, and M. Olvera de la Cruz Surface-induced layer formation in polyelectrolytes J Chem Phys 110 1999 11517 11522
237. M. Castelnovo, and J.-F. Joanny Formation of polyelectrolyte multilayers Langmuir 16 2000 7524 7532
238. R. Messina, C. Holm, and K. Kremer Polyelectrolyte adsorption and multilayering on charged colloidal particles J Polym Sci Part B Polym Phys 42 2004 3557 3570
239. V. Panchagnula, J. Jeon, and A.V. Dobrynin Molecular dynamics simulations of electrostatic layer-by-layer self-assembly Phys Rev Lett 93 2004 037801-1
240. S.Y. Park, C.J. Barrett, M.F. Rubner, and A.M. Mayes Anomalous adsorption of polyelectrolyte layers Macromolecules 34 2001 3384 3388
241. C.J. Lefaux, J.A. Zimberlin, A.V. Dobrynin, and P.T. Mather Polyelectrolyte spin assembly: influence of ionic strength on the growth of multilayered thin films J Polym Sci Part B Polym Phys 42 2004 3654 3666
242. M. Muthukumar Theory of viscoelastic properties of polyelectrolyte solutions Polymer 42 2001 5921 5923
243. M. Muthukumar Dynamics of polyelectrolyte solutions J Chem Phys 107 1997 2619 2635
244. M. Sedlak Dynamic light scattering from binary mixtures of polyelectrolytes. I. Influence of mixing on the fast and slow polyelectrolyte mode behavior J Chem Phys 107 1997 10799 10804
245. M. Sedlak Dynamic light scattering from binary mixtures of polyelectrolytes. II. Appearance of the medium polyelectrolyte mode upon mixing and comparison with experiments on binary mixtures of neutral polymers J Chem Phys 107 1997 10805 10815
246. M. Sedlak Mechanical properties and stability of multimacroion domains in polyelectrolyte solutions J Chem Phys 116 2002 5236 5245
247. M. Sedlak Long-time stability of multimacroion domains in polyelectrolyte solutions J Chem Phys 116 2002 5246 5255
248. A. Sehgal, and T.A.P. Seery The ordinary-extraordinary transition revisited: a model polyelectrolyte in a highly polar organic solvent Macromolecules 31 1998 7340 7346
249. J. Kotz, S. Kosmella, and T. Beitz Self-assembled polyelectrolyte systems Prog Polym Sci 26 2001 1199 1232
250. C.I. Huang, and M. Olvera de la Cruz Polyelectrolytes in multivalent salt solutions: monomolecular versus multimolecular aggregation Macromolecules 35 2002 976 986
251. E. Dubois, and F. Boue Conformation of poly(styrenesulfonate) polyions in the presence of multivalent ions: small-angle neutron scattering experiments Macromolecules 34 2001 3684 3697
252. F.J. Solis, and M. Olvera de la Cruz Flexible linear polyelectrolytes in multivalent salt solutions: solubility conditions Eur Phys J E 4 2001 143 152
253. I.I. Potemkin, V.V. Vasilevskaya, and A.R. Khokhlov Associating polyelectrolytes: finite size cluster stabilization versus physical gel formation J Chem Phys 111 1999 2809 2817
254. V.A. Bloomfield DNA condensation by multivalent cations Biopolymers 44 1997 269 282
255. I. Rouzina, and V.A. Bloomfield Macroion attraction due to electrostatic correlation between screening counterions. 1. Mobile surface-adsorbed ions and diffuse ion cloud J Phys Chem 100 1996 9977 9989
256. Y. Levin Electrostatic correlations: from plasma to biology Rep Prog Phys 65 2002 1577 1632
257. A.V. Dobrynin, R.H. Colby, and M. Rubinstein Polyampholytes J Polym Sci Part B Polym Phys 42 2004 3513 3538
258. Y. Qiu, and K. Park Environment-sensitive hydrogels for drug delivery Adv Drug Deliv Rev 53 2001 321 339
259. G.F. Elliott, and S.A. Hodson Cornea, and the swelling of polyelectrolyte gels of biological interest Rep Prog Phys 61 1998 1325 1365
260. J. Ruhe, M. Ballauff, M. Biesalski, P. Dziezok, F. Grohn, and D. Johannsmann Polyelectrolyte brushes Adv Polym Sci 165 2004 79 150