Enediolate-dilithium amide mixed aggregates in the enantioselective alkylation of arylacetic acids: Structural studies and a stereochemical model

Journal of the American Chemical Society

Volumn 135, Issue 45, 2013, Pages 16853-16864

  Ma, Yun ^b   Stivala, Craig E ^a   Wright, Ashley M ^a   Hayton, Trevor ^a   Liang, Jun ^b   Keresztes, Ivan ^b   Lobkovsky, Emil ^b   Collum, David B ^b   Zakarian, Armen ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b Cornell University ^*  (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ASYMMETRIC ALKYLATION; COMPUTATIONAL STUDIES; DENSITY FUNCTIONALS; ENANTIOSELECTIVE ALKYLATION; SOLUTION STRUCTURES; SPECTROSCOPIC STUDIES; STEREOCHEMICAL MODELS; STRUCTURAL STUDIES;

ALKYLATION; AMIDES; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SPECTROSCOPIC ANALYSIS; X RAY CRYSTALLOGRAPHY;

AGGREGATES;

AMIDE; ARYLACETIC ACID DERIVATIVE; CARBOXYLIC ACID DERIVATIVE; CATION; LITHIUM DERIVATIVE; PHENYLACETIC ACID;

ALKYLATION; ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL STRUCTURE; CONFORMATION; CRYSTAL STRUCTURE; DENSITY FUNCTIONAL THEORY; DIMERIZATION; ENANTIOSELECTIVITY; HETERONUCLEAR MULTIPLE BOND CORRELATION; HETERONUCLEAR SINGLE QUANTUM COHERENCE; LITHIATION; NITROGEN NUCLEAR MAGNETIC RESONANCE; SOLID STATE; SOLVATION; STEREOCHEMISTRY; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

ACETATES; ALKYLATION; AMIDES; ANIONS; CRYSTALLOGRAPHY, X-RAY; DIMERIZATION; LITHIUM; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, MOLECULAR; ORGANOMETALLIC COMPOUNDS; STEREOISOMERISM;

EID: 84884853720     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja403076u     Document Type: Article

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