Experimental characterization and computational study of unique C,N-chelated lithium dianions

Journal of the American Chemical Society

Volumn 132, Issue 38, 2010, Pages 13212-13213

  Gruver, Jocelyn M ^a   West, Scott P ^b   Collum, David B ^a   Sarpong, Richmond ^b  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b Department of Obstetrics Gynecology   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BOND FORMING; COMPUTATIONAL STUDIES; COMPUTATIONAL TECHNIQUE; DIANIONS; EXPERIMENTAL CHARACTERIZATION; HIGHLY ORDERED STRUCTURE; MONOMERIC SPECIES;

LITHIUM;

CHELATION;

LITHIUM DERIVATIVE; MONOMER;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION; SOLVATION; SYNTHESIS;

ANIONS; LITHIUM COMPOUNDS; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, MOLECULAR;

EID: 77957168556     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja106852n     Document Type: Article

References (21)

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18. For full reference listing, see the Supporting Information.
19. The computations use the Gaussian standard state of 1.0 atm. If the THF concentration is corrected to neat THF (approximately 13 M), each solvation step benefits from approximately 2.0 kcal/mol of additional stabilization at-78 °C (195 K).
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21. The low solvation number of the internal lithium in 9c is a property shared by all open dimers (ref 8).