Metal-free α-amination of secondary amines: Computational and experimental evidence for azaquinone methide and azomethine ylide intermediates

Journal of Organic Chemistry

Volumn 78, Issue 8, 2013, Pages 4132-4144

  Dieckmann, Arne ^a   Richers, Matthew T ^b   Platonova, Alena Yu ^b,c   Zhang, Chen ^b   Seidel, Daniel ^b   Houk, K N ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b RUTGERS UNIVERSITY   (United States)

^c URAL FEDERAL UNIVERSITY   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

AZOMETHINE YLIDES; BARRIER HEIGHTS; EXPERIMENTAL EVIDENCE; EXPERIMENTAL STUDIES; IMINIUM IONS; RATE-LIMITING STEPS; REACTIVE INTERMEDIATE; SECONDARY AMINES;

CHEMISTRY; ORGANIC COMPOUNDS;

AMINES;

AMINE; AZAQUINONE METHIDE; AZOMETHINE YLIDE; DEUTERIUM; MORPHOLINE; PIPERIDINE; PYRROLIDINE DERIVATIVE; REAGENT; UNCLASSIFIED DRUG;

AMINATION; ARTICLE; COMPUTATIONAL FLUID DYNAMICS; CYCLIZATION; CYCLOADDITION;

AMINATION; AMINES; AZA COMPOUNDS; AZO COMPOUNDS; METALS; QUINONES; STEREOISOMERISM; THIOSEMICARBAZONES;

EID: 84876532805     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo400483h     Document Type: Article

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