On the interpretation of deuterium kinetic isotope effects in C-H bond functionalizations by transition-metal complexes

Angewandte Chemie - International Edition

Volumn 51, Issue 13, 2012, Pages 3066-3072

  Simmons, Eric M ^a   Hartwig, John F ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

C H functionalization; energy diagrams; isotope effects; kinetics; rate determining step

Indexed keywords

C-H BOND; C-H BOND CLEAVAGE; C-H FUNCTIONALIZATION; DEUTERIUM KINETIC ISOTOPE EFFECT; ENERGY DIAGRAM; FUNCTIONALIZATIONS; ISOTOPE EFFECTS; KINETIC ISOTOPE EFFECTS; RATE DETERMINING STEP; TRANSITION-METAL COMPLEX;

CARRIER MOBILITY; DEUTERIUM; ENZYME KINETICS; EXPERIMENTS; FUNCTIONAL GROUPS; METAL COMPLEXES; REACTION KINETICS; TRANSITION METALS;

KINETICS;

CARBON; COORDINATION COMPOUND; DEUTERIUM; HYDROGEN;

ARTICLE; CHEMISTRY; KINETICS;

CARBON; COORDINATION COMPLEXES; DEUTERIUM; HYDROGEN; KINETICS;

EID: 84858776560     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201107334     Document Type: Article

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