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Volumn 47, Issue 35, 2008, Pages 6594-6597

[1,5]-hydride transfer/cyclizations on alkynyl fischer carbene complexes: Synthesis of 1,2-dihydroquinolinyl carbene complexes and cascade reactions

Author keywords

Annulations; Carbenes; Chromium; Heterocycles; Hydrides

Indexed keywords

CHEMICAL REACTIONS; SYNTHESIS (CHEMICAL);

EID: 53249123367     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200802268     Document Type: Article
Times cited : (95)

References (33)
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    • Angew. Chem. Int. Ed. 2007, 46, 2284-2287;
    • (2007) Angew. Chem. Int. Ed , vol.46 , pp. 2284-2287
  • 19
    • 53249095403 scopus 로고    scopus 로고
    • Experimental details on the syntheses of the carbenes (1) are provided on the Supporting Information.
    • Experimental details on the syntheses of the carbenes (1) are provided on the Supporting Information.
  • 20
    • 53249107118 scopus 로고    scopus 로고
    • DFTcomputational calculations were carried out by employing the B3LYP functional. Geometry optimizations were carried out by employing the 6-31G* basis set for C, H, N, and O, and the LANL2DZ ECP for Cr. Single-point energy calculations on the optimized structures were conducted by employing the 6-31++ G** basis set for the C, H, N, and O and LANL2DZ for Cr. See the Supporting Information for details.
    • DFTcomputational calculations were carried out by employing the B3LYP functional. Geometry optimizations were carried out by employing the 6-31G* basis set for C, H, N, and O, and the LANL2DZ ECP for Cr. Single-point energy calculations on the optimized structures were conducted by employing the 6-31++ G** basis set for the C, H, N, and O and LANL2DZ for Cr. See the Supporting Information for details.
  • 23
    • 53249134379 scopus 로고    scopus 로고
    • -1 higher than that for TS(A1-A2).
    • -1 higher than that for TS(A1-A2).
  • 29
    • 53249095398 scopus 로고    scopus 로고
    • CCDC 687236 (3a) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
    • CCDC 687236 (3a) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
  • 32
    • 0038524273 scopus 로고    scopus 로고
    • For general reviews, see: b
    • For general reviews, see: b) K. H. Dötz, P. Tomuschat, Chem. Soc. Rev. 1999, 28, 187-198;
    • (1999) Chem. Soc. Rev , vol.28 , pp. 187-198
    • Dötz, K.H.1    Tomuschat, P.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.