Catalytic intramolecular hydroamination with a bifunctional iridium pyrazolato complex: Substrate scope and mechanistic elucidation

Organometallics

Volumn 31, Issue 23, 2012, Pages 8444-8455

  Kashiwame, Yohei ^a   Kuwata, Shigeki ^a   Ikariya, Takao ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

AMINO GROUP; BI-FUNCTIONAL CATALYSTS; BIFUNCTIONAL; BOND CLEAVAGES; CATALYST OPTIMIZATION; CATALYTIC TURNOVER; DFT CALCULATION; DIASTEREO-SELECTIVITY; HYDROAMINATIONS; HYDROXY GROUPS; INTRAMOLECULAR CYCLIZATIONS; INTRAMOLECULAR HYDROAMINATION; KINETIC ANALYSIS; MILD TEMPERATURES; NITROGEN-CONTAINING HETEROCYCLES; PYRAZOLATO; PYRAZOLATO LIGAND; RATE DETERMINING STEP; SIDE REACTIONS; STOICHIOMETRIC REACTION; SYN-ADDITION; TRANSITION STATE;

AMINATION; CYCLIZATION; DENSITY FUNCTIONAL THEORY; FUNCTIONAL GROUPS; IRIDIUM; LIGANDS; OLEFINS;

IRIDIUM COMPOUNDS;

EID: 84870901936     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om301063n     Document Type: Article

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