Intramolecular hydroamination of unbiased and functionalized primary aminoalkenes catalyzed by a rhodium aminophosphine complex

Journal of the American Chemical Society

Volumn 132, Issue 39, 2010, Pages 13813-13822

  Julian, Lisa D ^a   Hartwig, John F ^a  

^a UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYL CHAIN; AMINOPHOSPHINES; ELECTRON DONATION; FUNCTIONALIZED; HIGH ACTIVITY; HIGH REACTIVITY; HYDROAMINATION PRODUCTS; HYDROAMINATIONS; INTRAMOLECULAR HYDROAMINATION; LIMITING STEP; MECHANISTIC DATA; METAL CENTERS; MILD TEMPERATURES; P MODES; PROTONOLYSIS; RELATIVE RATES; RHODIUM CATALYSTS; RHODIUM COMPLEXES; ROOM TEMPERATURE; TRANSITION-METAL COMPLEX;

CATALYSIS; CATALYST ACTIVITY; CHLORINE COMPOUNDS; CYANIDES; CYCLIZATION; ESTERS; ETHERS; FUNCTIONAL GROUPS; IRIDIUM; KETONES; METAL COMPLEXES; OLEFINS; PALLADIUM; PALLADIUM COMPOUNDS; PLATINUM; PLATINUM COMPOUNDS; RHODIUM; TRANSITION METALS;

RHODIUM COMPOUNDS;

ALCOHOL; ALKENE DERIVATIVE; ALKYL GROUP; AMINE; CHLORIDE; ESTER; ETHER; FUNCTIONAL GROUP; IRIDIUM COMPLEX; KETONE DERIVATIVE; NITRILE; PALLADIUM COMPLEX; PHOSPHINE DERIVATIVE; PLATINUM COMPLEX; RHODIUM DERIVATIVE;

AMINATION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL BOND; CYCLIZATION; ELECTRON; MOLECULAR PROBE; PROTON TRANSPORT; REACTION ANALYSIS; STEREOCHEMISTRY; TEMPERATURE DEPENDENCE;

ALKENES; AMINATION; CATALYSIS; CRYSTALLOGRAPHY, X-RAY; CYCLIZATION; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; PHOSPHINES; RHODIUM; STEREOISOMERISM;

EID: 77957318019     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja1052126     Document Type: Article

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