[Ir(COD)Cl]2 as a catalyst precursor for the intramolecular hydroamination of unactivated alkenes with primary amines and secondary alkyl- or arylamines: A combined catalytic, mechanistic, and computational investigation

Journal of the American Chemical Society

Volumn 132, Issue 1, 2010, Pages 413-426

  Hesp, Kevin D ^a   Tobisch, Sven ^b   Stradiotto, Mark ^a  

^a DALHOUSIE UNIVERSITY   (Canada)

^b UNIVERSITY OF ST ANDREWS   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION MECHANISMS; ALKYLAMINE; AMINE FUNCTIONALITY; AMINE UNITS; ARRHENIUS ANALYSIS; ARYL AMINES; C-C BONDS; C-C DOUBLE BONDS; CATALYST LOADINGS; CATALYST OPTIMIZATION; CATALYST PRECURSORS; CATALYTIC PERFORMANCE; COCATALYST; COMPUTATIONAL INVESTIGATION; CONCENTRATION OF; ELECTRON DENSITIES; FIRST-ORDER DEPENDENCE; H-BONDS; HYDROAMINATIONS; INTRAMOLECULAR ADDITIONS; INTRAMOLECULAR HYDROAMINATION; KINETIC ANALYSIS; KINETIC ISOTOPE EFFECTS; LATTER MECHANISM; NUCLEOPHILIC ATTACK; OXIDATIVE ADDITIONS; PHOSPHINE COLIGANDS; PLAUSIBLE MECHANISMS; PRECATALYSTS; PRIMARY AMINES; PROTONOLYSIS; PYRROLIDINES; RATE DEPENDENCE; REACTION MECHANISM; REDUCTIVE ELIMINATION; TRANSITION STATE STRUCTURE; UNACTIVATED OLEFINS; ZWITTERIONIC INTERMEDIATE;

ALKYLATION; AMINATION; AMMONIUM COMPOUNDS; CATALYSIS; CATALYSTS; CHLORINE COMPOUNDS; CYCLIZATION; ISOTOPES; OLEFINS; ORGANIC COMPOUNDS; PHOSPHORUS COMPOUNDS; REACTION RATES; SUBSTRATES;

IRIDIUM;

ALKENE; ALKENE DERIVATIVE; AMINE; AMPHOLYTE; CARBON; HYDROGEN; LIGAND; N BENZYL 2,2 DIPHENYLPENT 4 EN 1 AMINE; NITROGEN; PHOSPHINE; PYRROLIDINE DERIVATIVE; UNCLASSIFIED DRUG;

ADDITION REACTION; AMINATION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL ANALYSIS; CHEMICAL BOND; CHEMICAL STRUCTURE; CYCLIZATION; ELIMINATION REACTION; HYDROAMINATION; KINETICS; PROTON TRANSPORT; REACTION ANALYSIS; REDUCTION;

EID: 74849103679     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja908316n     Document Type: Article

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