Platinum(II)-catalyzed cyclization sequence of aryl alkynes via C(sp 3)-H activation: A DFT study

Journal of Organic Chemistry

Volumn 77, Issue 14, 2012, Pages 6076-6083

  Li, Zhi Feng ^a,b   Fan, Yanzhong ^a   Deyonker, Nathan J ^c   Zhang, Xiting ^a   Su, Cheng Yong ^a   Xu, Huiying ^a   Xu, Xianyan ^a   Zhao, Cunyuan ^a  

^a SUN YAT SEN UNIVERSITY   (China)

^b TIANSHUI NORMAL UNIVERSITY   (China)

^c University of Memphis   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AIM ANALYSIS; ARYL ALKYNES; C ATOMS; CARBENOIDS; DFT STUDY; ELECTROCYCLIZATION; ELECTRONIC EFFECTS; ELECTRONWITHDRAWING; FREE-ENERGY DIAGRAMS; HYDROALKYLATION; INSERTION MECHANISM; INSERTION REACTIONS; POLARIZABLE CONTINUUM MODEL; RATE-LIMITING STEPS; RELATIVE ENERGIES; SOLVENT EFFECTS; TRANSITION STATE;

ACETYLENE; CONTINUUM MECHANICS; CYCLIZATION; DENSITY FUNCTIONAL THEORY; ELECTRONIC STRUCTURE; HYDROGEN; ORGANIC COMPOUNDS; ORGANIC SOLVENTS; REACTION KINETICS;

PLATINUM;

1,4 HYDROGEN; ALKYNE DERIVATIVE; CARBENOID; CARBON; HYDROGEN; PHENYL GROUP; PLATINUM; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE; UNCLASSIFIED DRUG; VINYLIDENE;

ARTICLE; CATALYSIS; CATALYST; CYCLIZATION; DENSITY FUNCTIONAL THEORY; ELECTROCYCLIZATION; ELECTRON; SEQUENCE ALIGNMENT; STRUCTURE ANALYSIS; THERMODYNAMICS;

ALKYLATION; ALKYNES; CATALYSIS; CYCLIZATION; INDENES; MOLECULAR STRUCTURE; PLATINUM; QUANTUM THEORY; THERMODYNAMICS;

EID: 84864056381     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo300849t     Document Type: Article

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