Competitive C-H bond activation and β-hydride elimination at platinum(II)

Journal of the American Chemical Society

Volumn 129, Issue 12, 2007, Pages 3460-3461

  Kloek, Susan M ^a   Goldberg, Karen I ^a  

^a UNIVERSITY OF WASHINGTON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CYCLOHEXANE; ORGANOMETALLIC COMPOUND; PLATINUM COMPLEX; POLYCYCLIC AROMATIC HYDROCARBON;

ARTICLE; CHEMICAL BOND; ELIMINATION REACTION; OXIDATION; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; REDUCTION; SOLID STATE; TEMPERATURE DEPENDENCE; X RAY CRYSTALLOGRAPHY;

EID: 33947612173     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0669629     Document Type: Article

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13. See Supporting Information.
14. 3 signal.
15. In the thermolysis of 1b, the Pt(II) olefin hydride complex having cis imine and hydride groups (cis-2b) was observed as a kinetic product (maximum of 40% of the observed products at 60% conversion). Deuterium was present in all of the isopropyl and olefinic resonances, and cis-2b reacted further to fully convert to the thermodynamic product 2b by the end of the thermolysis. See supporting information.
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