Mechanism of the gold(I)-catalyzed Rautenstrauch rearrangement: A center-to-helix-to-center chirality transfer

Journal of the American Chemical Society

Volumn 128, Issue 7, 2006, Pages 2434-2437

  Nieto Faza, Olalla ^a   Silva López, Carlos ^a   Álvarez, Rosana ^a   De Lera, Angel R ^a  

^a UNIVERSITY OF VIGO   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; COMPLEXATION; COMPUTATION THEORY; GOLD; PROBABILITY DENSITY FUNCTION;

CHIRALITY TRANSFER; CYCLIZATION; PIVALOYL ROTATION;

STEREOCHEMISTRY;

1 ETHYNYL 2 METHYLBUT 2 ENYL ACETATE; 3,4 DIMETHYLCYCLOPENT 2 ENONE; ACETIC ACID DERIVATIVE; ALKYNE; BUTANE; CATION; CYCLOPENTENONE DERIVATIVE; GOLD; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL BOND; CHIRALITY; CONFORMATION; CYCLIZATION; DENSITY FUNCTIONAL THEORY; RAUTENSTRAUCH REARRANGEMENT; STEREOSPECIFICITY;

EID: 33644555190     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja057127e     Document Type: Article

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