DFT study on the mechanism and regioselectivity of gold(I)-catalyzed synthesis of highly substituted furans based on 1-(1-alkynyl)cyclopropyl ketones with nucleophiles

Organometallics

Volumn 28, Issue 3, 2009, Pages 741-748

  Fang, Ran ^a   Su, Cheng Yong ^a   Zhao, Cunyuan ^a   Phillips, David Lee ^b  

^a SUN YAT SEN UNIVERSITY   (China)

^b UNIVERSITY OF HONG KONG   (Hong Kong)

Author keywords

[No Author keywords available]

Indexed keywords

ACETYLENE; ACTIVATION ENERGY; CARBONYLATION; CATALYST REGENERATION; CHEMICAL BONDS; CONTINUUM MECHANICS; DENSITY FUNCTIONAL THEORY; DICHLOROMETHANE; GOLD; GOLD COMPOUNDS; HYDROGEN; KETONES; NUCLEOPHILES; OXYGEN; POTENTIAL ENERGY; POTENTIAL ENERGY SURFACES; PROPANE; QUANTUM CHEMISTRY; REGIOSELECTIVITY; RESONANCE;

ALKYNYL; C-C BONDS; CARBOCATION; CARBONYL OXYGENS; CATALYZED SYNTHESIS; COMPUTATIONAL RESULTS; CYCLOISOMERIZATION; CYCLOPROPANE MOIETIES; CYCLOPROPYL KETONES; DENSITY FUNCTIONAL THEORY CALCULATIONS; DFT STUDIES; EXPERIMENTAL OBSERVATIONS; GOLDS (I); HYDROGEN ATOMS; KEY REACTIONS; OXONIUM IONS; OXYGEN ATOMS; POLARIZABLE CONTINUUM MODELS; RESONANCE STRUCTURES; RING OPENINGS; SOLVENT EFFECTS; TRANSITION STRUCTURES; TRIPLE BONDS;

COORDINATION REACTIONS;

EID: 61849106583     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om800751u     Document Type: Article

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