Reductive elimination/oxidative addition of carbon-hydrogen bonds at Pt(IV)/Pt(II) centers: Mechanistic studies of the solution thermolyses of TpMe2Pt(CH3)2H

Journal of the American Chemical Society

Volumn 125, Issue 28, 2003, Pages 8614-8624

  Jensen, Michael P ^a   Wick, Douglas D ^a   Reinartz, Stefan ^b   White, Peter S ^b   Templeton, Joseph L ^b   Goldberg, Karen I ^a  

^a UNIVERSITY OF WASHINGTON   (United States)

^b The University of North Carolina at Chapel Hill   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; ENTHALPY; OXIDATION; PLATINUM; REACTION KINETICS;

ACTIVATION ENTHALPY;

CHEMICAL BONDS;

ACETONITRILE; BENZENE; CARBON; HYDROGEN; ISOTOPE; METHANE; METHYL GROUP; PLATINUM; SOLVENT; TOLUENE;

ARTICLE; ATOM; BINDING AFFINITY; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; ELIMINATION REACTION; ENERGY; ENTHALPY; HYDROGEN BOND; MEASUREMENT; OXIDATION; PARAMETER; STUDY;

EID: 0037699430     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja028477t     Document Type: Article

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80. For some examples with Pt(II)/Pt(IV) see: (a) Siegbahn, P. E. M.; Crabtree, R. H. J. Am. Chem. Soc. 1996, 118, 4442. (b) Hill, G. S.; Puddephatt, R. J. Organometallics 1998, 17, 1478. (c) Heiberg, H.; Swang, O.; Ryan, O. B.; Gropen, O. J. Phys. Chem. A 1999, 103, 10004. (d) Bartlett, K. L.; Goldberg, K. I.; Borden, W. T. J. Am. Chem. Soc. 2000, 122, 1456. (e) Mylvaganam, K.; Bacskay, G. B.; Hush, N. S. J. Am. Chem. Soc. 2000, 122, 2041. (f) Heiberg, H.; Johansson, L.: Gropen, O.; Ryan, O. B.; Swang, O.; Tilset, M. J. Am. Chem. Soc. 2000, 122, 10831. (g) Gilbert, T. M.; Hristov, I.; Ziegler, T. Organometallics 2001, 20, 1183. (h) Bartlett, K. L.; Goldberg, K. I.: Borden, W. T. Organometallics 2001, 20, 2669. (i) Kua, J.: Xu, X.; Periana, R. A.; Goddard, W. A., III. Organometallics 2002, 21, 511. (j) Ref 27b.
81. For some examples with Pt(II)/Pt(IV) see: (a) Siegbahn, P. E. M.; Crabtree, R. H. J. Am. Chem. Soc. 1996, 118, 4442. (b) Hill, G. S.; Puddephatt, R. J. Organometallics 1998, 17, 1478. (c) Heiberg, H.; Swang, O.; Ryan, O. B.; Gropen, O. J. Phys. Chem. A 1999, 103, 10004. (d) Bartlett, K. L.; Goldberg, K. I.; Borden, W. T. J. Am. Chem. Soc. 2000, 122, 1456. (e) Mylvaganam, K.; Bacskay, G. B.; Hush, N. S. J. Am. Chem. Soc. 2000, 122, 2041. (f) Heiberg, H.; Johansson, L.: Gropen, O.; Ryan, O. B.; Swang, O.; Tilset, M. J. Am. Chem. Soc. 2000, 122, 10831. (g) Gilbert, T. M.; Hristov, I.; Ziegler, T. Organometallics 2001, 20, 1183. (h) Bartlett, K. L.; Goldberg, K. I.: Borden, W. T. Organometallics 2001, 20, 2669. (i) Kua, J.: Xu, X.; Periana, R. A.; Goddard, W. A., III. Organometallics 2002, 21, 511. (j) Ref 27b.
82. For some examples with Pt(II)/Pt(IV) see: (a) Siegbahn, P. E. M.; Crabtree, R. H. J. Am. Chem. Soc. 1996, 118, 4442. (b) Hill, G. S.; Puddephatt, R. J. Organometallics 1998, 17, 1478. (c) Heiberg, H.; Swang, O.; Ryan, O. B.; Gropen, O. J. Phys. Chem. A 1999, 103, 10004. (d) Bartlett, K. L.; Goldberg, K. I.; Borden, W. T. J. Am. Chem. Soc. 2000, 122, 1456. (e) Mylvaganam, K.; Bacskay, G. B.; Hush, N. S. J. Am. Chem. Soc. 2000, 122, 2041. (f) Heiberg, H.; Johansson, L.: Gropen, O.; Ryan, O. B.; Swang, O.; Tilset, M. J. Am. Chem. Soc. 2000, 122, 10831. (g) Gilbert, T. M.; Hristov, I.; Ziegler, T. Organometallics 2001, 20, 1183. (h) Bartlett, K. L.; Goldberg, K. I.: Borden, W. T. Organometallics 2001, 20, 2669. (i) Kua, J.: Xu, X.; Periana, R. A.; Goddard, W. A., III. Organometallics 2002, 21, 511. (j) Ref 27b.
83. For some examples with Pt(II)/Pt(IV) see: (a) Siegbahn, P. E. M.; Crabtree, R. H. J. Am. Chem. Soc. 1996, 118, 4442. (b) Hill, G. S.; Puddephatt, R. J. Organometallics 1998, 17, 1478. (c) Heiberg, H.; Swang, O.; Ryan, O. B.; Gropen, O. J. Phys. Chem. A 1999, 103, 10004. (d) Bartlett, K. L.; Goldberg, K. I.; Borden, W. T. J. Am. Chem. Soc. 2000, 122, 1456. (e) Mylvaganam, K.; Bacskay, G. B.; Hush, N. S. J. Am. Chem. Soc. 2000, 122, 2041. (f) Heiberg, H.; Johansson, L.: Gropen, O.; Ryan, O. B.; Swang, O.; Tilset, M. J. Am. Chem. Soc. 2000, 122, 10831. (g) Gilbert, T. M.; Hristov, I.; Ziegler, T. Organometallics 2001, 20, 1183. (h) Bartlett, K. L.; Goldberg, K. I.: Borden, W. T. Organometallics 2001, 20, 2669. (i) Kua, J.: Xu, X.; Periana, R. A.; Goddard, W. A., III. Organometallics 2002, 21, 511. (j) Ref 27b.
84. For some examples with Pt(II)/Pt(IV) see: (a) Siegbahn, P. E. M.; Crabtree, R. H. J. Am. Chem. Soc. 1996, 118, 4442. (b) Hill, G. S.; Puddephatt, R. J. Organometallics 1998, 17, 1478. (c) Heiberg, H.; Swang, O.; Ryan, O. B.; Gropen, O. J. Phys. Chem. A 1999, 103, 10004. (d) Bartlett, K. L.; Goldberg, K. I.; Borden, W. T. J. Am. Chem. Soc. 2000, 122, 1456. (e) Mylvaganam, K.; Bacskay, G. B.; Hush, N. S. J. Am. Chem. Soc. 2000, 122, 2041. (f) Heiberg, H.; Johansson, L.: Gropen, O.; Ryan, O. B.; Swang, O.; Tilset, M. J. Am. Chem. Soc. 2000, 122, 10831. (g) Gilbert, T. M.; Hristov, I.; Ziegler, T. Organometallics 2001, 20, 1183. (h) Bartlett, K. L.; Goldberg, K. I.: Borden, W. T. Organometallics 2001, 20, 2669. (i) Kua, J.: Xu, X.; Periana, R. A.; Goddard, W. A., III. Organometallics 2002, 21, 511. (j) Ref 27b.
85. For some examples with Pt(II)/Pt(IV) see: (a) Siegbahn, P. E. M.; Crabtree, R. H. J. Am. Chem. Soc. 1996, 118, 4442. (b) Hill, G. S.; Puddephatt, R. J. Organometallics 1998, 17, 1478. (c) Heiberg, H.; Swang, O.; Ryan, O. B.; Gropen, O. J. Phys. Chem. A 1999, 103, 10004. (d) Bartlett, K. L.; Goldberg, K. I.; Borden, W. T. J. Am. Chem. Soc. 2000, 122, 1456. (e) Mylvaganam, K.; Bacskay, G. B.; Hush, N. S. J. Am. Chem. Soc. 2000, 122, 2041. (f) Heiberg, H.; Johansson, L.: Gropen, O.; Ryan, O. B.; Swang, O.; Tilset, M. J. Am. Chem. Soc. 2000, 122, 10831. (g) Gilbert, T. M.; Hristov, I.; Ziegler, T. Organometallics 2001, 20, 1183. (h) Bartlett, K. L.; Goldberg, K. I.: Borden, W. T. Organometallics 2001, 20, 2669. (i) Kua, J.: Xu, X.; Periana, R. A.; Goddard, W. A., III. Organometallics 2002, 21, 511. (j) Ref 27b.
86. For some examples with Pt(II)/Pt(IV) see: (a) Siegbahn, P. E. M.; Crabtree, R. H. J. Am. Chem. Soc. 1996, 118, 4442. (b) Hill, G. S.; Puddephatt, R. J. Organometallics 1998, 17, 1478. (c) Heiberg, H.; Swang, O.; Ryan, O. B.; Gropen, O. J. Phys. Chem. A 1999, 103, 10004. (d) Bartlett, K. L.; Goldberg, K. I.; Borden, W. T. J. Am. Chem. Soc. 2000, 122, 1456. (e) Mylvaganam, K.; Bacskay, G. B.; Hush, N. S. J. Am. Chem. Soc. 2000, 122, 2041. (f) Heiberg, H.; Johansson, L.: Gropen, O.; Ryan, O. B.; Swang, O.; Tilset, M. J. Am. Chem. Soc. 2000, 122, 10831. (g) Gilbert, T. M.; Hristov, I.; Ziegler, T. Organometallics 2001, 20, 1183. (h) Bartlett, K. L.; Goldberg, K. I.: Borden, W. T. Organometallics 2001, 20, 2669. (i) Kua, J.: Xu, X.; Periana, R. A.; Goddard, W. A., III. Organometallics 2002, 21, 511. (j) Ref 27b.
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