Factors that control catalytic two-versus four-electron reduction of dioxygen by copper complexes

Journal of the American Chemical Society

Volumn 134, Issue 16, 2012, Pages 7025-7035

  Fukuzumi, Shunichi ^a,b   Tahsini, Laleh ^a   Lee, Yong Min ^a   Ohkubo, Kei ^b   Nam, Wonwoo ^a   Karlin, Kenneth D ^a,c  

^a Ewha Womans University   (South Korea)

^b OSAKA UNIVERSITY   (Japan)

^c JOHNS HOPKINS UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BINUCLEATING LIGANDS; CATALYTIC CONDITIONS; CATALYTIC CYCLES; COPPER COMPLEXES; CU COMPLEXES; DECAMETHYLFERROCENE; DIOXYGENS; DIRECT REACTIONS; ELECTRON TRANSFER; FOUR-ELECTRON REDUCTION; HYDROPEROXO COMPLEX; HYDROXIDE GROUPS; KINETIC STUDY; LOW TEMPERATURES; MIXED-VALENT; MIXED-VALENT COMPOUNDS; PEROXOCOMPLEXES; PROTONATED; REACTION PATHWAYS; REDUCTANTS; TRIFLUOROACETIC ACIDS; TWO-ELECTRON REDUCTION;

ACETONE; COPPER; ELECTRON TRANSITIONS; PHENOLS; PROTONATION;

COPPER COMPOUNDS;

ACETONE; COPPER COMPLEX; DECAMETHYLFERROCENE; FERROCENE DERIVATIVE; HYDROGEN PEROXIDE; HYDROXIDE; LIGAND; OCTAMETHYLFERROCENE; OXYGEN; PHENOL; TRIFLUOROACETIC ACID; UNCLASSIFIED DRUG;

ABSORPTION SPECTROSCOPY; ARTICLE; BINDING AFFINITY; CATALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; CONTROLLED STUDY; CROSS COUPLING REACTION; ELECTRON; ELECTRON TRANSPORT; KINETICS; LOW TEMPERATURE; OXIDATION REDUCTION REACTION; PROTON TRANSPORT; SYNTHESIS; ULTRAVIOLET SPECTROSCOPY;

CATALYSIS; COPPER; ELECTRONS; HYDROGEN PEROXIDE; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; OXYGEN; QUANTUM THEORY;

EID: 84860334001     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja211656g     Document Type: Article

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