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Volumn 37, Issue 19, 1998, Pages 4838-4848

Effect of Protonation on Peroxo-Copper Bonding: Spectroscopic and Electronic Structure Study of [Cu2(UN-0-)(OOH)]2+

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Indexed keywords


EID: 0000550858     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic980606c     Document Type: Article
Times cited : (75)

References (79)
  • 1
    • 0003008954 scopus 로고
    • Valentine, J. S., Foote, C. S., Greenberg, A., Liebman, J. F., Eds.; Blackie Academic & Professional: Glasgow, Scotland
    • Fox, S.; Karlin, K. O. In Active Oxygen in Biochemistry; Valentine, J. S., Foote, C. S., Greenberg, A., Liebman, J. F., Eds.; Blackie Academic & Professional: Glasgow, Scotland, 1995; pp 188-231.
    • (1995) Active Oxygen in Biochemistry , pp. 188-231
    • Fox, S.1    Karlin, K.O.2
  • 23
    • 1842724038 scopus 로고    scopus 로고
    • Personal communication
    • Fujisawa, K. Personal communication.
    • Fujisawa, K.1
  • 29
    • 1842824913 scopus 로고
    • Ph.D. Thesis, The Johns Hopkins University
    • Mahroof-Tahir, M. Ph.D. Thesis, The Johns Hopkins University, 1992.
    • (1992)
    • Mahroof-Tahir, M.1
  • 34
    • 1842774582 scopus 로고
    • Ph.D. Thesis, Harvard University
    • Cook, M. R. Ph.D. Thesis, Harvard University, 1981.
    • (1981)
    • Cook, M.R.1
  • 44
    • 1842774581 scopus 로고
    • Ph.D. Thesis, University of Calgary
    • Verluis, L. Ph.D. Thesis, University of Calgary, 1989.
    • (1989)
    • Verluis, L.1
  • 47
    • 85086811088 scopus 로고    scopus 로고
    • -1 peak overlaps the Raman scattering from the quartz sample tube and is obtained by subtraction of the quartz signal
    • -1 peak overlaps the Raman scattering from the quartz sample tube and is obtained by subtraction of the quartz signal.
  • 49
    • 85086813164 scopus 로고    scopus 로고
    • note
    • -1).
  • 57
    • 1842774579 scopus 로고    scopus 로고
    • note
    • cu-to-Cu CT transition would not be resolved.
  • 59
    • 1842673781 scopus 로고    scopus 로고
    • note
    • 2 π orbitals oriented in the CuOO plane and a v subscript indicates the π orbitals with a node in this plane.
  • 63
    • 1842774578 scopus 로고    scopus 로고
    • note
    • Some of the peroxide orbitals that are recombined have different distributions of partitioned charge with respect to the two oxygen atoms so that the recombined orbitals imply a degree of O-O electron density localisation different from that observed in the original individual orbitals. This difference is small and does not significantly affect the results.
  • 70
    • 1842824910 scopus 로고    scopus 로고
    • note
    • 3+ in aqueous solution show little if any increase in frequency upon protonation.
  • 74
    • 1842673779 scopus 로고    scopus 로고
    • note
    • Although the "end-on monomer" peroxo-copper complex contains two copper ions, the term "monomer" is used since the peroxide has been shown to bind to only one of these copper ions (Figure 2, left).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.