Solvent enhancement of reaction selectivity: A unique property of cationic chiral dirhodium carboxamidates

Journal of the American Chemical Society

Volumn 133, Issue 24, 2011, Pages 9572-9579

  Wang, Xiaochen ^a   Weigl, Carolin ^a   Doyle, Michael P ^a  

^a Bldg 142   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

1 ,3-DIPOLARCYCLOADDITION; BROAD APPLICATION; CARBONYL-ENE REACTIONS; CARBOXYLATE LIGANDS; DIASTEREOMERIC; DIFFERENT SOLVENTS; DIRHODIUM; HETERO-DIELS-ALDER; LEWIS ACID-CATALYZED REACTIONS; NITRONES; REACTION SELECTIVITY; RELATIVE IMPORTANCE; UNSATURATED ALDEHYDES;

ALDEHYDES; CARBOXYLATION; CATALYSIS; CYCLOADDITION; DICHLOROMETHANE; ENANTIOSELECTIVITY; HALOCARBONS; LIGANDS; ORGANIC COMPOUNDS; ORGANIC SOLVENTS; REACTION RATES; RHODIUM; SOLVENTS; TOLUENE;

ASSOCIATION REACTIONS;

DICHLOROMETHANE; DIRHODIUM CARBOXAMIDATE DERIVATIVE; LEWIS ACID; RHODIUM DERIVATIVE; TOLUENE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHIRALITY; CYCLOADDITION; DIELS ALDER REACTION; ENANTIOSELECTIVITY; STEREOCHEMISTRY; SYNTHESIS;

CATALYSIS; LEWIS ACIDS; MODELS, MOLECULAR; MOLECULAR CONFORMATION; ORGANOMETALLIC COMPOUNDS; RHODIUM; SOLVENTS; STEREOISOMERISM; SUBSTRATE SPECIFICITY;

EID: 79959187553     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja202676a     Document Type: Article

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