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Another useful method of analysis, the correlation of log k to the electronic parameter χ, has been developed by Giering and co-workers (see, for example: Bartholomew, J.; Fernandez, A. L.; Lorsbach, B. A.; Wilson, M. R.; Prock, A.; Giering, W. P. Organometallics 1996, 15, 295). In our case, this analysis did not yield much insight beyond the Hammett analysis.
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2 values for these fits ranged from 0.9999 to 0.82; however, similar trends were observed between fits of varying qualities
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2 values for these fits ranged from 0.9999 to 0.82; however, similar trends were observed between fits of varying qualities.
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Another interpretation could be that charges develop in the ground state of the starting materials, but this seems unlikely
-
Another interpretation could be that charges develop in the ground state of the starting materials, but this seems unlikely.
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3543110521
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All calculations were performed using the teXsan crystallographic software package of Molecular Structure Corp.
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All calculations were performed using the teXsan crystallographic software package of Molecular Structure Corp.
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