Neutral transition metal hydrides as acids in hydrogen bonding and proton transfer: Media polarity and specific solvation effects

Journal of the American Chemical Society

Volumn 132, Issue 32, 2010, Pages 11234-11246

  Levina, Vladislava A ^a   Filippov, Oleg A ^a   Gutsul, Evgenii I ^a   Belkova, Natalia V ^a   Epstein, Lina M ^a   Lledos, Agusti ^b   Shubina, Elena S ^a  

^a A N NESMEYANOV INSTITUTE OF ORGANOELEMENT COMPOUNDS   (Russian Federation)

^b UNIVERSITAT AUTÒNOMA DE BARCELONA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

FREQUENCY CALCULATIONS; HYDROGEN BONDINGS; HYDROGEN-BOND FORMATION; HYDROGEN-BONDED COMPLEXES; ION PAIRS; IR SPECTROSCOPY; ORGANIC BASIS; PHOSPHINE OXIDE; POLARIZABLE CONTINUUM MODEL; PROTON TRANSFER REACTIONS; REACTION STEPS; SOLVENT EFFECTS; SPECIFIC SOLVATION; THERMODYNAMIC PARAMETER; TRANSITION METAL HYDRIDES; VARIABLE TEMPERATURE; WEAK INTERACTIONS;

CONTINUUM MECHANICS; HEXANE; HYDRIDES; HYDROGEN; HYDROGEN BONDS; HYDROPHILICITY; INFRARED SPECTROSCOPY; MOLYBDENUM OXIDE; PHOSPHORUS COMPOUNDS; PROTON TRANSFER; SOLVATION; TRANSITION METAL COMPOUNDS; TRANSITION METALS;

COMPLEXATION;

AMINE; HEXANE; PHOSPHINE OXIDE DERIVATIVE; PYRIDINE; TRANSITION ELEMENT;

ARTICLE; CALCULATION; COMPLEX FORMATION; DENSITY FUNCTIONAL THEORY; ELECTRON TRANSPORT; HYDROGEN BOND; INFRARED SPECTROSCOPY; PROTON TRANSPORT; SOLVATION; SPECTROSCOPY; THERMODYNAMICS;

ELECTRONS; GASES; HEXANES; HYDROGEN BONDING; HYDROGEN-ION CONCENTRATION; MODELS, MOLECULAR; MOLECULAR CONFORMATION; PROTONS; QUANTUM THEORY; SOLVENTS; SPECTRUM ANALYSIS; THERMODYNAMICS; TRANSITION ELEMENTS;

EID: 77955589562     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja103862r     Document Type: Article

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