Highly exo-selective and enantioselective cycloaddition reactions of nitrones catalyzed by a chiral binaphthyldiimine-Ni(II) complex

Organic Letters

Volumn 7, Issue 7, 2005, Pages 1431-1434

  Suga, Hiroyuki ^a   Nakajima, Takuya ^a   Itoh, Kengo ^a   Kakehi, Akikazu ^a  

^a SHINSHU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

BENZYLIDENE DERIVATIVE; IMINE; LEWIS ACID; NAPHTHYL GROUP; NICKEL COMPLEX; NITRONE DERIVATIVE; THIAZOLIDINE DERIVATIVE;

ARTICLE; CATALYSIS; CATALYST; CHIRALITY; CYCLOADDITION; ENANTIOSELECTIVITY;

EID: 17444374300     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol050397h     Document Type: Article

References (34)

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31. For the reaction of 1d, decreasing the catalyst loading to 1 or 2 mol % (rt for 112 h) resulted in lower yields (36% and 50%, respectively) and enantioselectivity (62%ee and 83% ee, respectively), but with high exo-selectivity (95:5 and 97:3, respectively).
32. 2 for 160 h, 0% yield. Reaction of 1a with 2d: reflux in toluene for 20 h, 0% yield.
33. 10
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