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In fact a small residual emission intensity, ca. 10% of that of the model is observed. On the basis of its unquenched lifetime 5 ns, this emission is attributed to an impurity of free PMI
-
In fact a small residual emission (intensity, ca. 10% of that of the model) is observed. On the basis of its unquenched lifetime (5 ns), this emission is attributed to an impurity of free PMI.
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With the appropriate parameters see the Supporting Information, the solvent contribution to the reorganizational energy is estimated to be about 0.6 eV in dichloromethane
-
With the appropriate parameters (see the Supporting Information), the solvent contribution to the reorganizational energy is estimated to be about 0.6 eV in dichloromethane.
-
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63
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77955449109
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The energy of the charge-separated state in diethyl ether can be estimated by using Equation 1 using appropriate effective ionic radii, see the Supporting Information to be ca. 1.96 eV
-
The energy of the charge-separated state in diethyl ether can be estimated by using Equation (1) (using appropriate effective ionic radii, see the Supporting Information) to be ca. 1.96 eV.
-
-
-
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64
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77955452709
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-
Note that a decrease in solvent polarity does not only increase the energy of the charge-separated state, but it also decreases the reorganizational energy of the processes. In the inverted region, the two factors act synergistically to reduce the rates, whereas in the normal regime partial compensation between the two effects should be expected
-
Note that a decrease in solvent polarity does not only increase the energy of the charge-separated state, but it also decreases the reorganizational energy of the processes. In the inverted region, the two factors act synergistically to reduce the rates, whereas in the normal regime partial compensation between the two effects should be expected.
-
-
-
-
65
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77955442743
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-
The energy of the charge-separated state in toluene can be estimated by using Equation 1 using appropriate effective ionic radii, see the Supporting Information to be ca. 2.29 eV
-
The energy of the charge-separated state in toluene can be estimated by using Equation (1) (using appropriate effective ionic radii, see the Supporting Information) to be ca. 2.29 eV.
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8, 35, 38-40, 67 on dyads in which fullerene is a photoexcited electron acceptor and exTTF is the electron donor. For these systems, with an intrinsically larger driving force 0.7 eV, using the experimental two-electron value, the problem of the effective one-electron oxidation potential of exTTF is evidently much less critical than here
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[8, 35, 38-40, 67] on dyads in which fullerene is a photoexcited electron acceptor and exTTF is the electron donor. For these systems, with an intrinsically larger driving force (0.7 eV, using the experimental two-electron value), the problem of the effective one-electron oxidation potential of exTTF is evidently much less critical than here.
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