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Volumn 48, Issue 4, 2009, Pages 815-819

Discrete supramolecular donor-acceptor complexes

Author keywords

Charge transfer; Density functional calculations; Host guest systems; Photochemistry; Pi interactions

Indexed keywords

CHARGE TRANSFER; FLOW INTERACTIONS; MASS TRANSFER; PHOTOEXCITATION;

EID: 58249121805     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200803984     Document Type: Article
Times cited : (98)

References (53)
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    • 60: 1669.991); see Figure S1 in the Supporting Information.
    • 60: 1669.991); see Figure S1 in the Supporting Information.
  • 34
    • 58249102145 scopus 로고    scopus 로고
    • Rate constants of about 1012 s-1 for intracomplex deactivation were estimated by fluorescence quenching
    • -1 for intracomplex deactivation were estimated by fluorescence quenching.
  • 37
    • 58249123344 scopus 로고    scopus 로고
    • -1.
    • -1.
  • 42
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    • Association binding energies are calculated as the difference between the total energy of the complex and the sum of the total energies of the receptor and C60
    • 60.
  • 47
    • 58249109417 scopus 로고    scopus 로고
    • Observed in chorobenzene at 429 nm, and calculated at 420 nm (f = 0.49). The LUMO for both MTW and PTW lies on the diester unit, and the lowest energy HOMO,HOMO-1→LUMO transitions have almost no intensity (f < 0.01).
    • Observed in chorobenzene at 429 nm, and calculated at 420 nm (f = 0.49). The LUMO for both MTW and PTW lies on the diester unit, and the lowest energy HOMO,HOMO-1→LUMO transitions have almost no intensity (f < 0.01).
  • 48
    • 58249102919 scopus 로고    scopus 로고
    • See the Supporting Information for a detailed description of the nature of the excited electronic states
    • See the Supporting Information for a detailed description of the nature of the excited electronic states.
  • 50
    • 58249102147 scopus 로고    scopus 로고
    • An additional band appears at 980 nm because of the singlet-singlet transition of free, uncomplexed C60
    • 60.
  • 53
    • 58249098468 scopus 로고    scopus 로고
    • •+ has lifetimes of 3.9 ps for PTW and 3.5 ps for MTW.
    • •+ has lifetimes of 3.9 ps for PTW and 3.5 ps for MTW.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.