Determination of tocopherols and tocotrienols in vegetable oils by nanoliquid chromatography with ultraviolet-visible detection using a silica monolithic column

Journal of Agricultural and Food Chemistry

Volumn 58, Issue 2, 2010, Pages 757-761

  Cerretani, Lorenzo ^a   Lerma García, María Jesús ^b   Herrero Martínez, José Manuel ^b   Gallina Toschi, Tullia ^a   Simó Alfonso, Ernesto Franciscó ^b  

^a UNIVERSITY OF BOLOGNA   (Italy)

^b UNIVERSITY OF VALENCIA   (Spain)

Author keywords

Botanical origin; Nano lc; Silica monolithic columns; Tocopherols; Tocotrienols; Vegetable oils

Indexed keywords

ALPHA TOCOTRIENOL; TOCOPHEROL; VEGETABLE OIL;

ARTICLE; EVALUATION; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; INSTRUMENTATION; METHODOLOGY; ULTRAVIOLET SPECTROPHOTOMETRY;

CHROMATOGRAPHY, HIGH PRESSURE LIQUID; PLANT OILS; SPECTROPHOTOMETRY, ULTRAVIOLET; TOCOPHEROLS; TOCOTRIENOLS;

EID: 74849085855     PISSN: 00218561     EISSN: None     Source Type: Journal    
DOI: 10.1021/jf9031537     Document Type: Article

References (46)

1. Blekas, G.; Tsimidou, M.; Bouskou, D. Contribution of α-tocopherol to olive oil stability. Food Chem. 1995, 52, 289-294.
2. Manzi, P.; Panfili, G.; Esti, M.; Pizzoferrato, L. Natural antioxidants in the unsaponifiable fraction of virgin, olive oils from different cultivars. J. Sci. Food Agric. 1998, 77, 115-120. (Pubitemid 28226650)
3. Braunrath, R.; Isnardy, B.; Solar, S.; Elmadfa, I. Influence of α-, γ-, and δ-tocopherol on the radiation induced formation of peroxides in rapeseed oil triacylglycerols. Food Chem. 2009, 117, 349-351.
4. Panfili, G.; Fratianni, A.; Irano, M. Normal phase high-performance liquid chromatography method for the determination of tocopherols and tocotrienols in cereals. J. Agric. Food Chem. 2003, 57, 3940-3944.
5. Solomon, N. W. Plant sources of vitamin A and human nutrition; Red palm oil does the job. Nutr. Rev. 1998, 56, 309-311.
6. Lee, H. J.; Ju, J.; Paul, S.; So, J. Y.; DeCastro, A.; Smolarek, A.; Lee, M. J.; Yang, C. S.; Newmark, H. L.; Suh, N. Mixed tocopherols prevent mammary tumorigenesis by inhibiting estrogen action and activating PPAR-γ. Clin. Cancer Res. 2009, 15, 4242-4249.
7. Gester, H. Anticarcinogenic effect of common carotenoids. Int. J. Vitam. Nutr. Res. 1993, 63, 93-121.
8. Choo, Y. M.; Yapa, S. C.; Ooi, C. K.; Ma, A. N.; Goh, S. H.; Ong, A. S. H. Recovered oil from palm-pressed fiber: A good source of natural carotenoids, vitamin E, and sterols. J. Am. Oil Chem. Soc. 1996, 73, 599-602.
9. Watson, R. R.; Preedy, V. R. Tocotrienols: Vitamin E beyond Tocopherols; The American Oil Chemisfs Society (AOCS): Urbana, IL, 2009.
10. Tasioula-Margari, M.; Okogeri, O. Simultaneous determination of phenolic compounds and tocopherols in virgin olive oil using HPLC and UV detection. Food Chem 2001, 74, 377-383. (Pubitemid 32757210)
11. Gimeno, E.; Calero, E.; Castellote, A. I.; Lamuela-Raventos, R. M.; De La Torre, M. C.; López-Sabater, M. C. Simultaneous determination of a-tocopherol and β-carotene in olive oil. by reversed-phase high-performance liquid chromatography. J. Chromatogr. A 2000, 881, 255-259. (Pubitemid 30332209)
12. Rovellini, P.; Azzolini, M.; Cortesi, N. Tocoferoli e tocotrienoli in oli e grassi vegetali mediante HPLC. Riv Ital. Sost. Grasse 1997, 74, 1-5.
13. Dionisi, F.; Prodolliet, J.; Tagliaferri, E. Assessment of olive oil adulteration by reversed-phase high-performance liquid chromatography/ amperometric detection of tocopherols and tocotrienols. J. Am. Oil Chem. Soc. 1995, 72, 1505-1511.
14. Mariani, C.; Bellan, G.; Morchio, G.; Pellegrino, A. I componenti minori liberi ed esterificati dell'olio di oliva e dell'olio di nocciola: Loro possibile utilizzo nella individuazione di commistioni. Nota 1. Riv. Ital. Sost. Grasse 1999, 76, 59-67.
15. Manandhar, P. P.; Nagao, A.; Yamazaki, M. Determination of content of linseed oil in edible soybean oil J. Jpn. Oil Chem. Soc. 1986, 35, 725-732.
16. Melchert, H. U.; Pollock, D.; Pabel, E.; Ruback, K.; Stan, H. J. Determination of tocopherols, tocopherolquinones and tocopherolhydroquinones by gas chromatography-mass spectrometry and preseparation with lipophilic gel chromatography, J. Chromatogr. A. 2002, 976, 215-220.
17. Abidi, S. L. Chromatographic analysis of tocol-derived lipid antioxidants. J. Chromatogr. A 2000, 881, 197-216.
18. Cunha, S. C.; Amaral, J. S.; Fernandes, J. O.; Oliveira, M. B. P. P. Quantification of tocopherols and tocotrienols in Portuguese olive oils using HPLC with, three different detection systems. J. Agric. Food Chem. 2006, 54, 3351-3356.
19. Sikorska, E.; Gliszczynska-Świgλlo, A.; Khmelinskii, I.; Sikorski, M. Synchronous fluorescence spectroscopy of edible vegetable oils. Quantification of tocopherols. J. Agric. Food Chem. 2005, 53, 6988-6994. (Pubitemid 41375304)
20. Gruszka, J.; Kruk, J. RP-LC for determination of plastochromanol, tocotrienols and tocopherols in plant oils Chromatographia 2007, 66, 909-913. (Pubitemid 350211958)
21. Abidi, S. L.; Mounts, T. L. Reversed-phase high-performance liquid chromatographic separations of tocopherols, J. Chromatogr. A 1997, 782, 25-32. (Pubitemid 27470763)
22. Silva, S. D.; Rosa, N. F.; Ferreira, A. E.; Boas, L. V.; Bronze, M. R. Rapid determination of a-tocopherol in vegetable oils by fourier transform infrared spectroscopy, Food Anal. Method 2009, 2, 120-127.
23. Aturki, Z.; D'Orazio, G.; Fanali, S. Rapid assay of vitamin E in vegetable oils by reversed-phase capillary electrochromatography. Electrophoresis 2005, 26, 798-803. (Pubitemid 40424911)
24. Lerma-Garcia, M. J.; Simó-Alfonso, E. F.; Ramis-Ramos, G.; Herrero-Martínez, J. M. Determination of tocopherols in vegetable oils by CEC using methacrylate ester-based monolithic columns. Electrophoresis 2007, 28, 4128-4135. (Pubitemid 350187320)
25. Hernández-Borges, J. M.; Aturki, Z.; Rocco, A.; Fanali, S. Recent applications in nanoliquid chromatography. J. Sep. Sci. 2007, 30, 1589-1610.
26. Luque de Castro, M. D.; Gámiz-Gracia, L. Miniaturisation: A welldefined trend in separation and preconcentration techniques, Anal. Chim, Acta 1997, 351, 23-40.
27. Chassaigne, H.; Norgaard, J. V.; Van Hengel, A. J. Proteomicsbased approach, to detect and identify major allergens in processed peanuts by capillary LC-Q-TOF (MS/MS). J. Agric. Food Chem. 2007, 55, 4461-4473.
28. Weber, D.; Raymond, P.; Ben-Rejeb, S.; Lau, B. Development of a liquid chromatography-tandem mass spectrometry method using capillary liquid chromatography and nanoelectrospray ionizationquadrupole time-of-flight hybrid mass spectrometer for the detection of milk allergens. J. Agric. Food Chem. 2006, 54, 1604-1610.
29. D'Orazio, G.; Cifuentes, A.; Fanali, S. Chiral nano-liquid chromatography-mass spectrometry applied to amino acids analysis for orange juice profiling, Food Chem. 2008, 108, 1114-1121.
30. Hernández-Borges, J.; D'Orazio, G.; Aturki, Z.; Fanali, S. Nanoliquid chromatography analysis of dansylated biogenic amines in wines, J. Chromatogr. A 2007, 1147, 192-199. (Pubitemid 46476797)
31. Fanali, S.; Aturki, Z.; D'Orazio, G.; Raggi, M. A.; Quaglia, M. G.; Sabbioni, C.; Rocco, A. Use of nano-liquid chromatography for the analysis of glycyrrhizin and glycyrrhetic acid in licorice roots and candies. J. Sep. Sci. 2005, 25, 982-986. (Pubitemid 40909103)
32. Rocco, A.; Fanali, S. Analysis of phytosterols in extra-virgin olive oil by nano-liquid chromatography. J. Chromatogr. A 2009, 1216, 7173-7178
33. Fanali, S.; Camera, E.; Chankvetadze, B.; D'Orazio, G.; Quaglia, M. G. Separation of tocopherols by nano-liquid chromatography. J. Pharm. Biomed. 2004, 35, 331-337.
34. Vissers, J. P. C.; Claessens, H. A.; Cramers, C. A. Microcolumn, liquid chromatography: instrumentation, detection and applications, J. Chromatogr. A. 1997, 779, 1-28. (Pubitemid 27401993)
35. Saito, Y.; Jinno, K.; Greibrokk, T. Capillary columns in liquid chromatography: Between, conventional columns and microchips. J. Sep. Sci. 2004, 27, 1379-1390.
36. Swart, R.; Kraak, J. C.; Poppe, H. Recent progress in open tubular liquid chromatography. Trends Anal. Chem. 1997, 16, 332-342. (Pubitemid 27342014)
37. Legido-Quigley, C.; Marlin, N. D.; Melin, V.; Manz, A.; Smith, N. W. Advances in capillary electrochromatography and micro-high performance liquid chromatography monolithic columns for separation science, Electrophoresis 2003, 24, 917-944.
38. Svec, F.; Tennikova, T. B.; Deyl, Z. Monolithic Materials: Preparation, Properties and Applications; Journal of Chromatography Library, 67; Elsevier: Amsterdam, The Netherlands, 2003.
39. Núñez, O.; Nakanishi, K.; Tanaka, N. Preparation of monolithic silica columns for high-performance liquid chromatography. J. Chromatogr. A 2008, 1191, 231-252.
40. Urbánek, L.; Solichová, D.; Melichar, B.; Dvorak, J.; Svobodová, I.; Solich, P. Optimization and validation of a high performance liquid chromatography method for the simultaneous determination of vitamins A and E in human serum using monolithic column, and diode-array detection. Anal. Chim. Acta 2006, 573-574, 267-272. (Pubitemid 44066934)
41. Waseem, A.; Rishi, L.; Yaqoob, M.; Nabi, A. Flow-injection determination of retinol and tocopherol in pharmaceuticals with acidic potassium permanganate chemiluminescence. Anal Sci 2009, 25, 407-412.
42. Jee, M. Oils and Fat Authentication; Blackwell Publishing, CRC Press: Boca Raton, FL, 2002.
43. Gunstone, F. D. TiTulo. Vegetable Oils in Food Technology: Composition, Properties and Uses; Blackwell Publishing, CRC Press: Boca Raton, FL, 2002.
44. Abidi, S. L.; Rennick, K. A. Capillary electrochromatographic evaluation of vitamin E-active oil constituents: Tocopherols and tocotrienols. J. Chromatogr. A. 2001, 913, 379-386.
45. Abidi, S. L.; Thiam, S.; Warner, I. M. Elution behavior of unsaponifiable lipids with various capillary electrochromatographic stationary phases, J. Chromatogr. A 2002, 949, 195-207.
46. Abidi, S. L. Reversed-phase retention characteristics of tocotrienol antioxidants. J. Chromatogr. A. 1999, 844, 67-75.