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The melting temperatures as a function of the particle radius are calculated from In T0/TM, 2/ρsL, ρs/ρl1/31/r, *{σl(1, ρs/ρl, σsl[1 -δ/rs*(ρs/ ρl)1/3]-1} where σsl is the solid-liquid interfacial tension, σl is the surface tension of the liquid, δ is the liquid-layer thickness, rs* is the radius of the particle at the melting point assuming that the particle is in the solid form, σs and σl are the solid and liquid densities, respectively, and L is the latent heat of fusion. The parameters (σsl, σl, σs, σl L) correspond to the experimental values of bulk gold 38. while δ and σ
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22 fitting their experimental data.
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