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Volumn 690, Issue 24-25, 2005, Pages 6143-6155

Development of 7-membered N-heterocyclic carbene ligands for transition metals

Author keywords

N heterocyclic carbene; Palladium; X ray structure

Indexed keywords

CHARACTERIZATION; COMPLEXATION; CRYSTAL STRUCTURE; PALLADIUM; SYNTHESIS (CHEMICAL); TRANSITION METALS;

EID: 27744440484     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2005.08.022     Document Type: Article
Times cited : (89)

References (82)
  • 7
    • 4143051292 scopus 로고    scopus 로고
    • For a leading reference to the direct use of carbenes as catalysts, see: D. Enders, and T. Balensiefer Acc. Chem. Res. 37 2004 534
    • (2004) Acc. Chem. Res. , vol.37 , pp. 534
    • Enders, D.1    Balensiefer, T.2
  • 29
    • 27744476038 scopus 로고    scopus 로고
    • note
    • 2-Ad), 273346 (11), 272585 (12), 272586 (13), 273348 (14), and 273347 (15). Copies of this information may be obtained free of charge from: The Director, CCDC, 12 Union Road, Cambridge, CB2 1EZ, UK, fax. (int code) +44 1223 336 033 or email: deposit@ccdc.cam.ac.uk or http://www.ccdc.cam.ac.uk.
  • 35
    • 0037049952 scopus 로고    scopus 로고
    • Ag(I)-NHC complexes have found widespread utility as carbene transfer agents for a variety of transition metals. See the following as leading examples. Transfer to Pd: Ref. [17] and D.J. Nielsen, K.J. Cavell, B.W. Skelton, and A.H. White Inorg. Chim. Acta 327 2002 116
    • (2002) Inorg. Chim. Acta , vol.327 , pp. 116
    • Nielsen, D.J.1    Cavell, K.J.2    Skelton, B.W.3    White, A.H.4
  • 63
    • 27744486309 scopus 로고    scopus 로고
    • note
    • The NHC ligand in complex 15 was disordered in the solid state, and only the Pd and non-NHC ligands were refined anisotropically. The structure obtained defines the connectivity, but bond lengths and angles of the NHC ligand are not reliably obtained from this crystal structure and are therefore not included in Table 1.
  • 69
    • 50549207291 scopus 로고
    • For a further description on Möbius Aromaticity, see Ref. [19] and the following: E. Heilbronner Tetrahedron Lett. 5 1964 1923
    • (1964) Tetrahedron Lett. , vol.5 , pp. 1923
    • Heilbronner, E.1
  • 75
    • 27744508410 scopus 로고    scopus 로고
    • Bruker-AXS. (2000-2003) sadabs V.2.05
    • (2000) Sadabs V.2.05


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.