Hydrogen bonding ligand functionality and catalytic selectivity in homogeneous hydrosilylation of enones with rhodium complexes

Journal of Molecular Catalysis A: Chemical

Volumn 222, Issue 1-2, 2004, Pages 59-73

  Rivera, Guillermina ^a   Crabtree, Robert H ^a  

^a YALE UNIVERSITY   (United States)

Author keywords

Carbene; Hydrosilylation; Molecular recognition; Rhodium catalyst; Salt effect

Indexed keywords

CATALYTIC SELECTIVITY; LIGANDS EFFECT; MOLECULAR RECOGNITION;

CATALYST ACTIVITY; CATALYSTS; CHEMICAL COMPOUNDS; ETHERS; HYDROGEN BONDS; MOLECULAR DYNAMICS; REDUCTION;

RHODIUM COMPOUNDS;

CARBENE; KETONE DERIVATIVE; RHODIUM COMPLEX;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; COMPLEX FORMATION; HYDROGEN BOND; HYDROSILYLATION; MOLECULAR RECOGNITION; REACTION ANALYSIS;

EID: 5144234841     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.molcata.2004.08.006     Document Type: Article

References (29)

1. C. Walsh Enzyme Reaction Mechanisms 1979 Freeman San Francisco
2. B. Cornils W. Herrmann Applied Homogeneous Catalysis with Organometallic Compounds: A Comprehensive Handbook 2002 Wiley-VCH Weinheim
3. B.R. James, Homogeneous Hydrogenation, Wiley New York, 1973.
4. J.M. Lehn Angew. Chem. Int. Ed. 29 1990 1304
5. J.H. Koh, A.O. Larsen, P.S. White, and M.R. Gagné Organometallics 21 2002 7
6. N.M. Brunkan, and M.R. Gagné J. Am. Chem. Soc. 122 2000 6217
7. V. Jubian, R.P. Dixon, and A.D. Hamilton J. Am. Chem. Soc. 114 1992 1120
8. C. Gibson, and J. Rebek Org. Lett. 4 2002 1887
9. K. Kavallieratos, and R.H. Crabtree Chem. Comm. 1999 2109 2110
10. M.M. Mader, and P.A. Bartlett Chem. Rev. 97 1997 1281
11. M. Akke Curr. Opin. Struct. Biol. 12 2002 642
12. K. Mikami, T. Korenaga, M. Terada, T. Ohkuma, T. Pham, and R. Noyori Angew. Chem. Int. Ed. 38 1999 495
13. GJH Buisman, L.A. vanderVeen, A. Klootwijk, W.G.J. deLange, P.C.J. Kamer, P.W.N.M. vanLeeuwen, and D. Vogt Organometallics 16 1997 2929
14. J. Balsells, J.M. Betancort, and P.J. Walsh Angew. Chem. Int. Ed. 39 2000 3428
15. T.J. Davis, J. Balsells, P.J. Carroll, and P.J. Walsh Org. Lett. 3 2001 2161 2164
16. W.P. Chen, and J.L. Xiao Tetrahedron Lett. 42 2001 8737
17. J.J. Becker, P.S. White, and M.R. Gagné J. Am. Chem. Soc. 123 2001 9478
18. W.A. Herrmann Angew. Chem. Int. Ed. 41 2002 1291
19. A.R. Chianese, X. Li, M.C. Janzen, J.W. Faller, and R.H. Crabtree Organometallics 22 8 2003 1663 1667
20. K.J. Harlow, A.F. Hill, and T. Welton Synthesis 1996 697 698
21. X.-L. Luo, and R.H. Crabtree J. Am. Chem. Soc. 111 1989 2527 2535
22. A. Loupy, and B. Tchoubar Salt effects in organic and organometallic chemistry 1992 VCH
23. G. Giordano, and R.H. Crabtree Inorg. Synth. 19 1979 218 220
24. K.J. Harlow, A.F. Hill, and T. Welton Synthesis 1996 697
25. H.M.J. Wang, and I.J.B. Lin Organometallics 17 1998 972
26. L.J. Prints, D.N. Reinhoudt, and P. Timmerman Angew. Chem. Int. Ed. 40 2001 2382 2426
27. P.M. Pinko Angew. Chem. Int. Ed. 43 2004 262 264
28. I. Ojima, and T. Kogure Organometallics 1 1982 1390 1399
29. G.Z. Zheng, and T.H. Chan Organometallics 14 1995 70 79